Phase Change Matters RSS


The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.




Research roundup: Silicon carbide for battery thermal management; Stefan moving boundary models; alkali nitrate/nitrite salts; more

Ben Welter - Tuesday, July 24, 2018

From Renewable Energy:

Using Renewables Coupled with Thermal Energy Storage to Reduce Natural Gas Consumption in Higher Temperature Commercial/Industrial Applications

From Solar Energy:

Development of a solar thermal storage cum cooking device using salt hydrate

From Applied Energy:

One-step fabrication of fatty acids/nano copper/polyester shape-stable composite phase change material for thermal energy management and storage
Palmitic acid/polyvinyl butyral/expanded graphite composites as form-stable phase change materials for solar thermal energy storage

From Chinese Journal of Chemical Engineering:

Preparation and phase change performance of Na2HPO4·12H2O@poly(lactic acid) capsules for thermal energy storage

From Applied Thermal Engineering:

Thermal performance of sodium acetate trihydrate based composite phase change material for thermal energy storage
Performance improvement and energy consumption reduction in refrigeration systems using phase change material (PCM)
A thermal conductive composite phase change material with enhanced volume resistivity by introducing silicon carbide for battery thermal management
Numerical and Experimental study on the performance of a new two -layered high-temperature packed-bed thermal energy storage system with changed-diameter macro-encapsulation capsule

From Colloids and Surfaces A: Physicochemical and Engineering Aspects:

Green Nano-encapsulation Technique for Preparation of Phase Change Nanofibers Mats with Core-Sheath Structure
From International Journal of Thermal Sciences:

Analytical and numerical analysis of PCM solidification inside a rectangular finned container with time-dependent boundary condition

From Construction and Building Materials:

Elaboration and properties of a composite bio-based PCM for an application in building envelopes

From International Journal of Heat and Mass Transfer:

Lorentz forces effect on NEPCM heat transfer during solidification in a porous energy storage system
A translucent honeycomb solar collector and thermal storage module for building façades

PCM briefing: Brookins confirmed as Alexium CEO; palmitic acid, stearic acid on U.S. tariff list

Ben Welter - Monday, July 16, 2018

Dr. Robert BrookinsAlexium International has appointed Dr. Robert Brookins, right, as chief executive officer and managing director of the company. Brookins, formerly executive vice president of research and development, was appointed interim CEO in May, replacing Dirk Van Hyning, who resigned for personal reasons. Alexium, based in Greer, S.C., and Perth, Australia, makes flame-retardant and PCM-enhanced fabric treatments.

Palmitic acid, stearic acid and their salts and esters are on a list of more than 6,000 items on which the United States may impose additional import tariffs in its escalating trade war with China.

Two top executives at Wilmar International have stepped down after Greenpeace published a report linking the world's largest palm oil trading company to a supplier accused of deforestation.

Active Energy Systems, a clean-tech startup in Tennessee, is developing an electro-thermal energy storage system that will use waste heat generated by data centers, industrial complexes, institutions and power plants to store and distribute energy more efficiently and cheaply than systems using conventional batteries. "Using power from the grid at off-peak times," Venture Nashville Connections reports, "the process transforms water into ice -- spraying it through an oil layer, which allows the water to freeze but not stick to a submerged heat exchanger. Instead, it forms pellets resembling Dippin' Dots ice cream, [co-founder Mitch] Ishmael said. Then the cycle operates in reverse, using waste heat to melt the ice and generate electricity back to the grid."

• New from Research Mentor:" Global Phase Change Material (PCM) Market will be Worth USD 770.1 Million by 2023"

• New from Questale: "Global Eutectic Phase Change Material Market Research Report 2018"

• "What are some new trends in solar energy research and development in 2018?" a Quora member asked recently. Three answers were posted. The one provided by Yogi Goswami, director of the University of South Florida's Clean Energy Research Center, got more than 120 "upvotes" and was picked up by Forbes magazine. Goswami discussed the strengths and weaknesses of two competing technologies: photovoltaics and concentrating solar power. He expressed confidence that CSP will eventually become commercially competitive because it has two big advantages over PV: "It uses the same thermal power conversion as the conventional thermal power (fossil fuel or nuclear based) and can therefore be integrated with the existing power infra-structure easily" and it "uses thermal energy storage which is about one-tenth the cost of battery storage."

Research roundup: Novel graphite-PCM composite sphere; sunlight-driven energy conversion; PCM-rich concrete overlay; more

Ben Welter - Tuesday, July 10, 2018

From Applied Thermal Engineering:

A Novel Graphite-PCM Composite Sphere With Enhanced Thermo-Physical Properties
Fatty acids based eutectic phase change system for thermal energy storage applications

From Applied Energy:

Mathematical modeling and sensitivity analysis of solar photovoltaic panel integrated with phase change material
Compact liquid cooling strategy with phase change materials for Li-ion batteries optimized using response surface methodology
Multi-parameter optimization design of thermoelectric harvester based on phase change material for space generation

From Solar Energy:

Experimental study on the performance of a novel solar water heating system with and without PCM
Latent thermal energy storage for solar process heat applications at medium-high temperatures – A review
Carbon based material included-shaped stabilized phase change materials for sunlight-driven energy conversion and storage: An extensive review

From Construction and Building Materials:

Application of a PCM-rich concrete overlay to control thermal induced curling stresses in concrete pavements

From Energy Conversion and Management:

Energy investigation of glazed windows containing Nano-PCM in different seasons
Transforming a passive house into a net-zero energy house: a case study in the Pacific Northwest of the U.S.

Research roundup: Humidity control material; solar water heaters; nanomaterials; flow-through wall elements; more

Ben Welter - Monday, July 09, 2018

From Energy and Buildings:

A Review on Enhancement of Phase Change Materials - A Nanomaterials Perspective
Phase change humidity control material and its impact on building energy consumption

From Solar Energy:

Optimization of melting and solidification processes of PCM: Application to integrated collector storage solar water heaters

From Applied Thermal Engineering:

Experimental Investigation on the Heat Transfer Enhancement in a Novel Latent Heat Thermal Storage Equipment
Recent advancements on thermal management and evaluation for data centers
Heat Transfer Characteristics of an Expanded Graphite/Paraffin PCM-Heat Exchanger used in an Instantaneous Heat Pump Water Heater

From Thermal Science and Engineering Progress:

Numerical simulation of the melting of a NePCM due to a heated thin plate with different positions in a square enclosure

From Journal of Building Engineering:

Numerical study of flow-through wall elements with phase–change materials

From Journal of Energy Storage:

Exploratory investigation of a new thermal energy storage system with different phase change materials having distinct melting temperatures

From Renewable Energy:

Optimization assessment of the energy performance of a BIPV/T-PCM system using Genetic Algorithms

From Sustainable Cities and Society:

Coupled cooling method and application of latent heat thermal energy storage combined with pre-cooling of envelope: Temperature control using phase-change chair

PCM briefing: Cash infusion for Ice Energy; ASHRAE's new energy audit standard now available

Ben Welter - Monday, July 02, 2018

Ice Energy, make of the Ice Bear and other ice-based energy storage systems, is getting an infusion of cash from a private equity manager. The California startup will receive $40 million from Argo Infrastructure Partners to finance the delivery of its residential and commercial thermal storage contracts.

• "Chemistry for the Non-Chemist," a four-part online course offered by Chemical Watch, promises "a solid introduction to chemistry." The cost: $450.  

ASHRAE Standard 211 is now available for download. The standard "establishes consistent practices for conducting and reporting energy audits for commercial buildings. The standard defines the procedures required to perform Energy Audit Levels 1, 2, and 3; provides a common scope of work for these audit levels for use by building owners and others; c. establishes consistent methodology and minimum rigor of analysis required; and establishes minimum reporting requirements for the results of energy audits." 

Purchase College of New York will get a free replacement for its aging central heating plant, thanks to a collaborative thermal energy storage project from the New York Power Authority and Brenmiller Energy. The R&D project will investigate sensible thermal energy storage as a way to increase the efficiency of a standard combined heat and power system. The new system could save State University of New York $100,000 a year.

Fifty-four academic papers were presented at PCM 2018, the 12th IIR International Conference on Phase Change Materials and Slurries for Refrigeration and Air Conditioning, held in Orford, Canada, last month. "Investigations on the stability of metallic cans for PCM macro-encapsulation," "Investigation of compatibility of organic and inorganic PCMs with the materials of containers" and "Life cycle assessment phase changes of materials, component and system concept" are among the papers posted on the International Institute of Refrigeration website. 

John Lerch, vice president of sales and marketing at thermal energy storage company Axiom Exergy, writes about "5 things utilities should consider for energy storage." 

Wilmar International said it has ceased sourcing from palm oil suppliers allegedly associated with Gama, a company that was accused by Greenpeace of causing deforestation in Indonesia. 

• The Roundtable on Sustainable Palm Oil and Canadian supply chain consultancy Ulula are collaborating to introduce a mobile phone app to report potential workers’ incidents and abuses on palm oil plantations. 

Research roundup: Natural convection heat transfer; simulation of hysteresis effects; PCM in roofs; more

Ben Welter - Wednesday, June 20, 2018

From Energy Conversion and Management:

Effect of using nanoparticles on the performance of thermal energy storage of phase change material coupled with air-conditioning unit
Numerical study on the effect of non-uniform magnetic fields on melting and solidification characteristics of NEPCMs in an annulus enclosure
Solidification behavior of binary eutectic phase change material in a vertical finned thermal storage system dispersed with graphene nano-plates

From International Communications in Heat and Mass Transfer:

A method to evaluate natural convection heat transfer in microencapsulated phase change material (MPCM) slurry: An experimental study
Dynamic of plumes and scaling during the melting of a Phase Change Material heated from below

From Applied Thermal Engineering:

Experimental investigation of the thermal performance of heat pipe assisted phase change material for battery thermal management system
Low-temperature macro-encapsulated phase change material based thermal energy storage system without air void space design

From Energy and Buildings:

Modeling and experimental validation of an algorithm for simulation of hysteresis effects in phase change materials for building components
Thermal performance and numerical simulation of geopolymer concrete containing different types of thermoregulating materials for passive building applications

From Solar Energy:

How to enhance thermal energy storage effect of PCM in roofs with varying solar reflectance: Experimental and numerical assessment of a new roof system for passive cooling in different climate conditions

From Energy:

A facile approach to synthesize microencapsulated phase change materials embedded with silver nanoparticle for both thermal energy storage and antimicrobial purpose

From Reference Module in Materials Science and Materials Engineering:

Materials, Design and Development of Latent Heat Storage Systems for Medium and Large-Scale Applications: Issues and Challenges

From Physica A: Statistical Mechanics and its Applications:

Melting process in porous media around two hot cylinders: Numerical study using the lattice Boltzmann method

From Solar Energy Materials and Solar Cells:

Synthesis and characterization of chain-extended and branched polyurethane copolymers as form stable phase change materials for solar thermal conversion storage

From Construction and Building Materials:

Investigation of different materials for macroencapsulation of salt hydrate phase change materials for building purposes

From Journal of Energy Storage:

CFD thermal energy storage enhancement of PCM filling a cylindrical cavity equipped with submerged heating sources
Performance analysis of industrial PCM heat storage lab prototype

Research roundup: Heat transfer enhancement of PCMs; CuO/palmitic acid composite; cooking applications; more

Ben Welter - Tuesday, June 12, 2018

From Materials Today: Proceedings:

Investigation of thermal performance by applying a solar chimney with PCM towards the natural ventilation of model house under Climate of Thailand
Study of Solar– PCM Walls for domestic hot water production under the tropical climate of Thailand
Improved Performance of Composite Phase Change Material for Thermal Energy Storage
Experimental investigation on freezing/melting characteristics of two different phase change materials
Review on Heat Transfer Enhancement of Phase Change Materials (PCMs)
Experimental Investigation of Improved Thermal Characteristics of Al2O3/Barium Hydroxide Octa Hydrate as Phase Change Materials (PCMs)
Improved Thermal Energy Storage Behavior of CuO/Palmitic acid Composite as Phase Change Material

From Applied Thermal Engineering:

An Experimental Investigation of the Melting Process of a Bio-based Nano-PCM filled Vertical Cylindrical Thermal Energy Storage System

From International Journal of Heat and Mass Transfer:

Experimental investigation of the effects of mass fraction and temperature on the viscosity of microencapsulated PCM slurry

From Journal of the Brazilian Society of Mechanical Sciences and Engineering:

Rapid thermal cycling of three phase change materials (PCMs) for cooking applications

From 3rd Thermal and Fluids Engineering Conference:

Use of Wood/Phase Change Material Composite in the Building Envelope for Building Thermal Control and Energy Savings

Research roundup: N-octadecane/polystyrene/expanded graphite composites; decorative wood-based panels for thermal energy storage; more

Ben Welter - Monday, June 11, 2018

From Energy:

Experimental investigation on n–octadecane/polystyrene/expanded graphite composites as form–stable thermal energy storage materials

From Green Energy and Environment:

Thermal characterization of bio-based phase changing materials in decorative wood-based panels for thermal energy storage

From Chemical Engineering Science:

Melt-Front Propagation and Velocity Profiles in Packed Beds of Phase-Change Materials Measured by Magnetic Resonance Imaging

From Thermal Science and Engineering Progress:

Employment of Finned PCM Container in a Household Refrigerator as a Cold Thermal Energy Storage System

From Energy Conversion and Management:

Melting and solidification of PCM embedded in porous metal foam in horizontal multi-tube heat storage system
Evaluation of paraffin infiltrated in various porous silica matrices as shape-stabilized phase change materials for thermal energy storage

From Construction and Building Materials:

Potential applications of phase change materials to mitigate freeze-thaw deteriorations in concrete pavement
A practical ranking system for evaluation of industry viable phase change materials for use in concrete
Experimental and numerical study of thermal performance of the PCM wall with solar radiation
Utilizing blast furnace slags (BFS) to prepare high-temperature composite phase change materials (C-PCMs) 

From International Journal of Thermophysics:

Behavior of a PCM at Varying Heating Rates: Experimental and Theoretical Study with an Aim at Temperature Moderation in Radionuclide Concrete Encasements

PCM briefing: Ecozen Solutions wins Ashden Award; Fraunhofer researchers among winners in Imagine Chemistry challenge

Ben Welter - Monday, June 11, 2018

Ecozen cold storage unit

Ecozen Solutions of India, which makes portable solar cold rooms for use on small farms, is one of six international winners in the 2018 Ashden Awards competition. The Ecofrost system's thermal storage unit can store power for more than 36 hours in case of cloudy or rainy weather. The organizations will be honored at a ceremony at the Royal Geographical Society in London on Thursday, June 14. 

Axel Kraft and Martin Peters of Fraunhofer UMSICHT are among the winners of the 2018 AkzoNobel Imagine Chemistry challenge. Kraft and Peters will receive support from LuxResearch to further develop a catalytic process for making alcohols from more sustainable raw materials. Overall, 10 startups and researchers were chosen as winners from a group of 20 finalists at a three-day event held at Chalmers University in Gothenburg, Sweden.

A call for papers has been issued for the 10th International Conference on Indoor Air Quality, Ventilation and Energy Conservation in Buildings. Topics include ventilation strategies and measurement techniques; HVAC systems; smart technologies for zero-energy buildings; and design and energy modeling. Abstracts are due by Nov. 1. The conference will be held Sept. 5-7, 2019, in Bari, Italy.  

• Researchers at the Jülich Solar Tower test facility in Germany have reached a milestone in the development of a new receiver concept for solar tower power plants. During a test of the centrifugal receiver CentRec for the generation and storage of solar high temperature heat, an average particle temperature of 965 degrees Celsius has been measured at the receiver outlet. The bauxite particles used in the system are available at prices that enable cost-effective thermal storage. “The proof of the high operating temperature is an essential condition for the targeted commercialization of this new receiver concept,” said Dr. Reiner Buck, head of solar tower systems at the DLR Institute of Solar Research

• June 15 is the last day to get the early bird rate for this year's Advancements in Thermal Management Conference (Denver, Aug. 8-9). Topics include thermal materials, thermal imaging, thermal characterization, modeling, battery cooling and thermal simulation. Joe Kelly, senior materials scientist at Outlast Technologies, is among the speakers. His topic: "Enhancing Thermal Stability and Performance of Lithium-ion Batteries using Latent Heat Storage (LHS) Technology."

Phase change composite shows potential to double AC compressor efficiency

Ben Welter - Friday, June 01, 2018

Using a phase change composite material, researchers at the University of Illinois at Chicago have developed a novel thermal energy storage system that has the potential to downsize conventional air-conditioner compressors by 50 percent and double compressor efficiency during off- and mid-peak hours.

The research is described in a paper titled “Design and optimization of a hybrid air conditioning system with thermal energy storage using phase change composite,” recently accepted for publication in Energy Conversion and Management. One of the authors, Said Al-Hallaj, a research professor of chemical engineering at UI-Chicago and CEO of AllCell Technologies LLC, answered a few questions by e-mail.

Q: Who led the research team, and how long did the project take?

A: “It is an ongoing project since 2015 at the University of Illinois at Chicago, where I work as a Research Professor of Chemical Engineering, and part of the PhD thesis for my graduate student Ahmed Aljehani.”

Q: Who funded the project? 

A: “Ahmed has a scholarship from his government in Saudi Arabia and we get technical support from our industry partners NETenergy and AllCell Technologies LLC.”

Q: Who supplied the PCM?

A: “I believe it is n-tetradecane (C14H30) PCM that we bought from a distributor and not sure about actual source.”

28 slabs of phase change composite materialQ: What is its peak melting point? 

A: “4-6 degrees Celsius.”

Q: What is its thermal storage capacity?

A: “180 kJ/kg (78% PCM, 22% graphite).”

Q: Describe the benchtop PCC/TES system size, components and functionality.

A: “The actual 4 kWh PCC-TES structure is made of 28 slabs of PCC [right]. The whole PCC-TES structure is thermally insulated with building insulation materials. Each slab represents a graphite structure that has been soaked into n-tetradecane for at least 24 h until impregnated with n-tetradecane. The slabs are numbered from top to bottom; top being number 1. The second component is the copper tubes or the copper coils, which pass back and forth in between the 28 slabs. The copper tubes enter the PCC-TES structure from the top and exits from the bottom of the structure.”

Q: Is the concept intended mainly for commercial AC systems, or could it be adapted for residential use?

A: “It should work for both, but commercial AC applications are more economically beneficial due to rate structure and peak demand requirements.”

Q: What are the next steps in developing this concept?

A: “NETenergy, our technology commercialization partner, is partnering with National Renewable Energy Laboratory and a major OEM to build and test a full-scale prototype at NREL facilities in the next year or so.”