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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Acrylic PCM microcapsules; paraffin-water nanoemulsion; two-tank molten salt TES; more

Ben Welter - Wednesday, February 14, 2018

Non-linear system identification of a latent heat thermal energy storage system [Applied Thermal Engineering]

Tailoring of bifunctional microencapsulated phase change materials with CdS/SiO2 double-layered shell for solar photocatalysis and solar thermal energy storage [Applied Thermal Engineering]

Preparation of acrylic PCM microcapsules with dual responsivity to temperature and magnetic field changes [European Polymer Journal]

Paraffin wax–water nanoemulsion: A superior thermal energy storage medium providing higher rate of thermal energy storage per unit heat exchanger volume than water and paraffin wax [Energy Conversion and Management]

Preparation and characterization of stearic acid/polyurethane composites as dual phase change material for thermal energy storage [Journal of Thermal Analysis and Calorimetry]

Efficiency analyses of high temperature thermal energy storage systems of rocks only and rock-PCM capsule combination [Solar Energy]

Thermal performance analysis of PCM wallboards for building application based on numerical simulation [Solar Energy]

Thermal energy storage in district heating: Centralised storage vs. storage in thermal inertia of buildings [Energy Conversion and Management]

Two-tank molten salts thermal energy storage system for solar power plants at pilot plant scale: lessons learnt and recommendations for its design, start-up and operation [Renewable Energy]

PCM briefing: Croda merger talks reported; RAL PCM members to meet March 1

Ben Welter - Monday, February 12, 2018

• British specialty chemicals maker Croda International Plc has held unsuccessful talks with Ashland Global Holdings Inc. about a possible merger, a source familiar with the matter told Reuters last week.

Croda recently redesigned the CrodaTherm website, www.crodatherm.com. The new site offers improved navigation and searchability, a wider range of potential PCM applications and profiles of the CrodaTherm technical team. Visitors can register to log in and download datasheets and order samples. "We are excited to launch this new website, making it even easier for our customers to find us and the products they need," said Graeme Tweddle, global managing director for energy technologies at Croda.

• Members of the RAL Quality Association PCM, a European-based organization established in 2004 to develop standards for the phase change material industry, will meet in Düsseldorf, Germany, on March 1. On the agenda: Quality and testing specifications; improvements to the association's website; member content on the BUILD UP Web portal; promotion of PCMs in the European Union, Germany, Netherlands and the United States; and registration of RAL quality marks.   

Sonoco ThermoSafe is accepting registrations for the company's first Leading Minds Seminar, to be held June 6-7 in Philadelphia. Co-hosted by ELPRO, the seminar is a chance for pharmaceutical manufacturers, supply chain partners and government representatives to discuss temperature-assurance packaging and data monitoring in a collaborative environment. Day two includes a visit to ThermoSafe's design and testing lab in Montgomeryville, Penn.

Sonoco is No. 90 on Barron's inaugural list of "The 100 Most Sustainable Companies." 

• A "measurement and verification study" of a Viking Cold Solutions TES system installed in a 320-square-foot walk-in freezer at a supermarket in Fremont, Calif., showed an 18 percent net reduction in energy consumption.   

• The deadline is Monday, Feb. 12, to submit a concept paper for ARPA-E's OPEN 2018 competition. Up to $100 million is available for new projects that "transform the way we generate, store and use energy."

DLR Group, which part of a public-private collaboration working to develop PCM-based cooling and heating methods for Agua Fria Canyon View High School, has been named one of Arizona's "40 Companies to Watch" in 2018 by AZRE magazine. 

• Entries are being accepted for Bio-Based World News' 2018 Innovation Awards. The four categories are product of the year, chemical innovation of the year, best use of alternative feedstocks and industry story of the year. The entry deadline is Feb. 23. Winners will be honored March 20 at the World Bio Markets conference in Amsterdam. 

• Nantucket, Mass., has approved the installation of an Ice Bear thermal storage and air-conditioning unit in a building owned by the town. Last summer, Genbright won a $1.5 million grant from the state to install the units in more than 200 Nantucket homes, with the goal of reducing peak energy demand and staving off the need for a third undersea power cable for the island. But some residents voiced skepticism about the technology, prompting the town board to approve the test installation.

• Shippers have found that cocoa butter can be hard to contain on long ocean voyages. There have been reports of the material leaking out of containers as it changes phase, clogging bilges and generally making a mess. The Cargo Incident Notification System, established in 2011 to share information on all cargo-related incidents, has issued guidelines that recommend the material be shipped in refrigerated containers, particularly when passing through hot climate zones. 

Research roundup: Heat transfer model based on energy asymmetry; smart concretes; traction transient cooling; more

Ben Welter - Wednesday, February 07, 2018

A new heat transfer model of phase change material based on energy asymmetry [Applied Energy]

Multifunctional smart concretes with novel phase change materials: Mechanical and thermo-energy investigation [Applied Energy]

The melting of salt hydrate phase change material in an irregular metal foam for the application of traction transient cooling [Thermal Science and Engineering Progress]

Solar Energy Latent Thermal Storage by Phase Change Materials (PCMs) in a Honeycomb System [Thermal Science and Engineering Progress]

Fabrication and characterization of diethylene glycol hexadecyl ether-grafted graphene oxide as a form-stable phase change material [Thermochimica Acta]

One-dimensional model of a stratified thermal storage tank with supercritical coiled heat exchanger [Applied Thermal Engineering]

Using silicagel industrial wastes to synthesize polyethylene glycol/silica-hydroxyl form-stable phase change materials for thermal energy storage applications [Solar Energy Materials and Solar Cells]

Steam-PCM heat exchanger design and materials optimization by using Cr-Mo alloys [Solar Energy Materials and Solar Cells]

Sodium acetate trihydrate-chitin nanowhisker nanocomposites with enhanced phase change performance for thermal energy storage [Solar Energy Materials and Solar Cells]

Preparation and thermal properties of fatty acid/diatomite form-stable composite phase change material for thermal energy storage [Solar Energy Materials and Solar Cells]

Patent application: Encapsulation of thermal storage medium

Ben Welter - Tuesday, February 06, 2018

U.S. patent application 20180016482 (assignee University of South Florida, Tampa, Fla.): 

"In one embodiment, a method for depositing metal on a polymer surface, the method includes coating the polymer surface with a binding metal to render the polymer surface solvophillic and/or hydrophilic and depositing a further metal on the binding metal-coated polymer surface."

http://www.freepatentsonline.com/20180016482.pdf

Research roundup: Eutectic organic PCMs; diatomite/CNTs/PEG composites; cellulose insulation; more

Ben Welter - Tuesday, February 06, 2018

From Data in Brief:

Prediction of the Properties of Eutectic Organic Phase Change Materials

From Energy and Buildings:

Diatomite/CNTs/PEG composite PCMs with shape-stabilized and improved thermal conductivity: Preparation and thermal energy storage properties

From Solar Energy:

Thermal performance of phase change materials (PCM)-enhanced cellulose insulation in passive solar residential building walls

From Energy Procedia:

A Parametric Study about the Potential to Integrate Phase Change Material into Photovoltaic Panel
Investigations on thermal environment in residential buildings with PCM embedded in external wall
Passive Cooling Using Phase Change Material and Insulation for High-rise Office Building in Tropical Climate
A Study on Latent Heat Energy Storage Performance of Tetradecane
Erythritol-Vermiculite form-stable phase change materials for thermal energy storage

From Applied Thermal Engineering:

Modification of expanded graphite and its adsorption for hydrated salt to prepare composite PCMs

From Renewable Energy:

Experimental Investigation of Solar Chimney with Phase Change Material (PCM)
Effect of retrofitting a silver/water nanofluid-based photovoltaic/thermal (PV/T) system with a PCM-thermal battery for residential applications

From International Journal of Thermal Sciences:

Thermal charging performance of enhanced phase change material composites for thermal battery design

From Colloids and Surfaces A: Physicochemical and Engineering Aspects:

Preparation and characterization of high-temperature non-flowing SiO2/EG/paraffin composites by high-temperature refining

From Materials Today: Proceedings:

Experimental analysis of thermal energy storage by phase change material system for cooling and heating applications

From Materials & Design:

Thermal conductivity enhancement of phase change materials with form-stable carbon bonded carbon fiber network

From Sustainable Cities and Society:

Experimental study on thermal performance improvement of building envelopes by integrating with phase change material in an intermittently heated room

From International Journal of Refrigeration:

Phase-change thermal energy storage using spherical capsules: performance of a test plant

PCM briefing: va-Q-tec opens North American headquarters; Viking Cold Solutions begins Phoenix-area installation

Ben Welter - Friday, January 19, 2018

• PCM maker va-Q-tec AG officially opened its new North American headquarters in Langhorne, Penn., this week. Va-Q-tec will use the 20,000-square-foot facility to showcase new products and to manufacture its small temperature-control shipping containers. The location will also serve as a hub for the company's rental and repair operation. “The investment in this new facility is a testament to our commitment to grow the business and expand our footprint in North America," said CEO Dr. Joachim Kuhn.

Drones that deliver sterile mosquitoes in the fight against the Zika virus will be field tested in Latin America early this year. The system, developed by the Joint FAO/IAEA Division of Nuclear Techniques in Food and Agriculture's Insect Pest Control Laboratory, uses phase change material to keep the mosquitoes inactive during transportation. 

• New from Greentech Media: "The Next Five Years in Energy Storage According to 500 Energy Professionals"

• New from Global Info Research: "North America Advanced Phase Change Materials (PCM) Market by Manufacturers, Countries, Type and Application, Forecast to 2022"

• New from Technavio: "Global Advanced Phase Change Materials Market 2017-2021

Viking Cold Solutions has begun installing its PCM-based thermal energy storage system in a 10,000-square-foot freezer at the Bashas food distribution center in the Phoenix area. The system, which consists of salt-hydrate-filled panels suspended from warehouse ceilings, is designed to significantly reduce energy costs by shifting peak demand to nighttime hours.

• The cost of renewable energy is falling so fast that it should be a consistently cheaper source of electricity than fossil fuels by 2020, according to a new report from the International Renewable Energy Agency

Utility Dive takes a close look at Nantucket Island's "hybrid" plan to add energy storage, including thermal storage, to stave off expensive grid enhancements.

Patent application: Thermal energy storage apparatus with PCM

Ben Welter - Friday, January 19, 2018

Neothermal patent drawingU.S. patent application 20180017337 (applicant NeoThermal Energy Storage Inc., Timberlea, Canada):

"A thermal energy storage apparatus is disclosed. The apparatus includes a base and fluid flow plates which cooperate with the base to define a cavity; a phase change material contained within the cavity; an extendable extension spring [40] at least partially contained within the phase change material [14]; and end plates which cooperate with the fluid flow plates to define fluid flow channels. Inlet and outlet ports allow for the ingress and egress of a heat exchange fluid into the fluid flow channels. In operation, the extension of the extendable extension spring induces solidification of at least a portion of the phase change material from a supercooled liquid state to a solid state, releasing thermal energy, allowing for the transfer of thermal energy across the fluid flow plates from the phase change material to the heat exchange fluid."

http://www.freepatentsonline.com/20180017337.pdf

Research roundup: Review of latent heat storage systems; triple-glazed window with PCM; myristic acid; more

Ben Welter - Wednesday, January 17, 2018

Design of a Latent Thermal Energy Storage System From Constructal Approach [ASME 2017 International Mechanical Engineering Congress and Exposition]

Latent Heat Thermal Energy Storage Systems with Solid–Liquid Phase Change Materials: A Review [Advanced Engineering Materials]

Simulation Research on the Dynamic Thermal Performance of a Novel Triple-glazed Window Filled with PCM [Sustainable Cities and Society]

Charging and Discharging Period Analysis of Myristic Acid as Phase Change Material [pdf] [International Journal of Current Engineering and Technology]

Solid-liquid phase equilibria of stearic acid and dicarboxylic acids binary mixtures as low temperature thermal energy storage materials [Journal of Chemical Thermodynamics]

Comparative study on the solar still performance utilizing different PCM [Desalination]

Temperature stabilization using salt hydrate storage system to achieve thermal comfort in prefabricated wooden houses [Energy and Buildings]

Multiobjective optimization of a building envelope with the use of phase change materials (PCMs) in Mediterranean climates [International Journal of Energy Research]

Experimental research in the phase change materials based on paraffin and expanded perlite [Phase Transitions]

Enhanced Thermal Conductivity and Thermal Performance of Polyethylene Glycol (PEG)/Modified SiO2 Composite Phase Change Material [Science of Advanced Materials]

PCM briefing: Cleanergy to develop solar TES in Morocco; SpaceX has opening for a thermal engineer

Ben Welter - Friday, January 12, 2018

Cleanergy AB of Sweden and the Moroccan Agency for Sustainable Energy have agreed on a framework to jointly develop a thermal energy storage system using Cleanergy's Stirling-based solar electricity technology.

• Applications are being accepted for the World Materials Forum Startup Challenge. Companies with fewer than 50 employees are eligible for the competition, which recognizes technical or organizational breakthroughs in one of five categories, including materials composition, product design and 3D manufacturing. The winning company will receive a 50,000 euro award at the World Materials Forum in June in Nancy, France.

Grace Hsia, co-founder and CEO of Warmilu LLC, is among 14 entrepreneurs in the running for the $1 million top prize in the WeWork Creator Awards Global competition. The winner will be announced in New York City on Jan. 17.

• Prize money totaling 52,500 euros, financed by Germany's National Climate Initiative, is up for grabs in the German Refrigeration Prize 2018 competition, honoring innovations in air conditioning and refrigeration. The entry deadline is Jan. 31. Winners will be announced at the Berlin Energy Days conference in May.

SpaceX is seeking candidates for the position of thermal engineer.  

Pacific Gas & Electric will introduce a new electric time-of-use rate in April. The California utility says the optional rate will make energy use more efficient and minimize peak demand challenges. The peak pricing will be from 4 p.m. to 9 p.m.

Bain & Co. has analyzed how chemical companies can "demystify" the R&D process. Among the three common "failure modes" Bain identified: "strong team running in too many directions."

Buro Happold associate Mark Dowson will speak on the topic of "phase change materials for ultimate thermal efficiency" at the 2018 Materials for Architecture conference in London in April.

Research roundup: Composite PCM/concrete wall; thermal inertia in buildings; multilayer roof with two PCMs; more

Ben Welter - Thursday, January 04, 2018

Thermal impact study of a bio-based wall coupled with an inner PCM layer [Energy Procedia]

Numerical study of the thermal behavior of a novel Composite PCM/concrete wall [Energy Procedia]

Phase change materials for improving the building thermal inertia [Energy Procedia]

Thermal behavior in dynamic regime of a multilayer roof provided with two phase change materials in the case of a local conditioned [Energy Procedia]

Composite phase change materials with good reversible thermochromic ability in delignified wood substrate for thermal energy storage [Applied Energy]

D-mannitol for medium temperature thermal energy storage [Solar Energy Materials and Solar Cells]

Novel metal coated nanoencapsulated phase change materials with high thermal conductivity for thermal energy storage [Solar Energy Materials and Solar Cells]

State and state of charge estimation for a latent heat storage [Control Engineering Practice]

Microencapsulated n-alkane eutectics in polystyrene for solar thermal applications [Solar Energy]

Improving thermal properties of shape-stabilized phase change materials containing lauric acid and mesocellular foam silica by assessing thermodynamic properties of the non-melting layer [Thermochimica Acta]