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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Form-stable stearic acid PCM; spent diatomite from palm oil bleaching process; anisotrophic graphene aerogels; more

Ben Welter - Tuesday, October 30, 2018

From Journal of Thermal Analysis and Calorimetry:

Preparation and characterization of novel form stable phase change materials based on stearic acid

From Construction and Building Materials:

Thermal performance enhancement of organic phase change materials using spent diatomite from the palm oil bleaching process as support

From Journal of Facade Design and Engineering:

Modelling Envelope Components Integrating Phase Change Materials (PCMs) with Whole-Building Energy Simulation Tools: A State of the Art [pdf]

From Renewable Energy:

Two side serpentine flow based photovoltaic-thermal-phase change materials (PVT-PCM) system: Energy, exergy and economic analysis

From Advanced Functional Materials:

Thermally Conductive Phase Change Composites Featuring Anisotropic Graphene Aerogels for Real‐Time and Fast‐Charging Solar‐Thermal Energy Conversion

From Indoor and Built Environment:

The year-round thermal performance of a new ventilated Trombe wall integrated with phase change materials in the hot summer and cold winter region of China

From Energy:

Solar thermal energy storage based on sodium acetate trihydrate phase change hydrogels with excellent light-to-thermal conversion performance

From Advances in Material Science and Engineering:

Shape Stability of Polyethylene Glycol/Acetylene Black Phase Change Composites for Latent Heat Storage [pdf]

From Solar Energy:

Energy performance comparison of concentrated photovoltaic – Phase change material thermal (CPV-PCM/T) system with flat plate collector (FPC)

From Cogent Engineering:

Evaluation of a concrete-graphite hybrid mixture for low-cost thermal energy storage material

PCM briefing: 'Array' radiator featured at Dutch Design Week; DLR's Sundharam among speakers at green tech conference

Ben Welter - Monday, October 29, 2018

Array radiator

• What happens when designers and scientists collaborate on new materials? Ten teams set out to answer that question over a six-month period. The results were on display at Dutch Design Week 2018 earlier this month. A metallic radiator filled with phase change materials and nanowires was one of 10 projects featured in the "What Matter_s" exhibition in Eindhoven. The "Array" radiator, the work of furniture designer Amy Wang, architect Tim Söderström and two nanotechnologists, Professor Magnus Borgström and Dr. Vilgailè Dagytè, is designed to absorb and disperse heat in reaction to changing ambient temperatures.

Prem Sundharam, global sustainability leader for DLR Group, will be among the speakers at this week's California Green Technology Schools and Community College Conference in Pasadena. "Looking forward to discussing about Zero-Net Energy Buildings, California's Duck-Curve and the application of Phase Change Materials (PCM) as an effective solution," he wrote on LinkedIn last week. "Bonus: Also sharing how to integrate innovative energy technology (PCM) into school curriculum and have students be active participants in this cutting-edge research!"  

EnergyNest thermal battery EnergyNest of Norway is partnering with the Italian utility Enel to analyze the potential for integrating industrial-scale thermal batteries into Enel’s thermal power plants. EnergyNest's battery, right, consists of steel cassettes with pipes encased in Heatcrete, a special type of concrete developed in partnership with HeidelbergCement.

• New from QY Research: "Global (United States, European Union and China) Salt Hydrate Market Research Report 2018-2025"

• As the solar industry has grown, the market has been flooded with cheaply made Chinese panels. The panels are wearing out in as little as five years, the Verge reports, and recycling isn’t economically viable right now. “It’s going to be a major problem,” said Mary Hutzler, a senior fellow at the Institute for Energy Research.  

Vertellus, the specialty chemicals company based in Indianapolis, has named John Van Hulle its new chief executive officer. He previously served as president of global color and additives for Ohio-based PolyOne, and CEO of Wisconsin-based chemical supplier ChemDesign

PureTemp LLC is moving its Minnesota administrative office from Plymouth to Minneapolis, effective Oct. 31. The new address: 4232 Park Glen Road, Minneapolis, MN 55416.

• SolarReserve has been selected to receive a $2 million award from the U.S. Department of Energy's Solar Energy Technologies Office to advance concentrating concentrating solar power research and development. SolarReserve's CSP technology uses molten salt as a heat transfer fluid and thermal energy storage medium. 

Patent application: Thermal energy storage systems

Ben Welter - Monday, October 29, 2018

PCES TES patent drawing

U.S. patent application 20180283800 (applicant Phase Change Energy Solutions Inc., Asheboro, N.C.):

"In one aspect, thermal energy storage systems are described herein. In some embodiments, a thermal energy storage system comprises a thermal energy storage system comprising a container and a heat exchange apparatus disposed within the container. The heat exchange apparatus comprises a tank, a manifold at least partially disposed within the tank, and a phase change material disposed within the tank and in thermal contact with the manifold."

http://www.freepatentsonline.com/20180283800.pdf

Research roundup: Synthesis of n-butyl palmitate; graphite as heat-transfer enhancer in high-temperature inorganic PCM; more

Ben Welter - Thursday, October 25, 2018

From Journal of Thermal Analysis and Calorimetry:

Synthesis and characterization of the n-butyl palmitate as an organic phase change material

From Renewable Energy:

Encapsulation of high-temperature inorganic phase change materials using graphite as heat transfer enhancer

From Synthesis, Technology and Applications of Carbon Nanomaterials:

Activated Carbon for Shape-Stabilized Phase Change Material

From Applied Energy:

Thermal conductivity enhancement of phase change materials with 3D porous diamond foam for thermal energy storage

From Energy and Technology Journal:

Enhancement of Thermal Storage Properties of Phase Change Material by Using Metallic Swarf [pdf]

From ACS Sustainable Chemistry & Engineering:

Fabrication and Characterization of Flame-Retardant Nanoencapsulated n-Octadecane with Melamine–Formaldehyde Shell for Thermal Energy Storage

From Energy Storage Materials:

Polyurethane-Based Flexible and Conductive Phase Change Composites for Energy Conversion and Storage

From Materials Today:

Research roundup: Solar fish dryer; oscillating heat pipe; small-scale refrigeration system; more

Ben Welter - Monday, October 22, 2018

From Applied Thermal Engineering:

Experiments on comparative performance of water thermocline storage tank with and without encapsulated paraffin wax packed bed
Experimental study and performance prediction of the PCM-antifreeze solar thermal system under cold weather conditions
Improving System Performance of a Personal Conditioning System integrated with Thermal Storage

From Energy:

A methodological concept for phase change material selection based on multi-criteria decision making (MCDM): A case study

From Journal of Energy Storage:

Experimental analysis of solar fish dryer using phase change material

From International Journal of Heat and Mass Transfer:

Experimental investigation on thermal performance of phase change material coupled with three-dimensional oscillating heat pipe (PCM/3D-OHP) for thermal management application

From Sustainable Cities and Society:

Experimental investigation on melting and solidification behaviour of erythritol in a vertical double spiral coil thermal energy storage system

From Journal of Thermal Analysis and Calorimetry:

Investigation of energy and exergy performance on a small-scale refrigeration system with PCMs inserted between coil and wall of the evaporator cabin

From Journal of Applied Physics:

Optimizing the design of composite phase change materials for high thermal power density

From Energy Procedia:

The technical and economic feasibility of utilizing phase change materials for thermal storage in district heating networks

PCM briefing: Traction battery for electric vehicles; Ember mug available in Apple stores

Ben Welter - Friday, October 19, 2018

• The Fraunhofer Institute for Structural Durability and System Reliability in Darmstadt, Germany, has developed a traction battery that can use thermal energy as a heat source in electric vehicles. A new type of fiber-reinforced composite sandwich housing protects the battery from temperature fluctuations. The phase change material composite system is designed to precondition the battery at low outside temperatures and reduce heat generation during rapid charging. The system was developed as part of the European Union's Optimized Energy Management and Use project. "We've developed material, structural and process technologies that can guarantee drivers a more reliable and uniform range for their battery-powered vehicles," said Felix Weidmann, project manager at Fraunhofer LBF.

Airec AB of Sweden has joined the EU Horizon 2020 project SWS-Heating. The project's goal is to develop seasonal thermal storage of solar energy. The energy will be stored in phase change materials. Airec will develop heat exchangers for the project. 

A process for extracting a biodegradable polymer from crustaceans is among the winners of this year's Green Chemistry Challenge Awards. The awards were formerly known as the Presidential Green Chemistry Challenge Awards. The American Chemical Society’s Green Chemistry Institute has collaborated with the U.S. Environmental Protection Agency to manage the awards since their inception in 1995. The EPA dropped out this year, citing long-term certainty about the program’s financial situation.  

Ember temperature-control tumblerEmber Technologies' temperature-control mugs are now available in Apple stores and on apple.com. The travel version right, uses phase change material to bring hot beverages down to a drinkable temperature. Earlier this year, Nordstrom began selling the mugs online and in Nordstrom popup stores.

Capstone Turbine Corp. and Argonne National Laboratory have received funding from U.S. Department of Energy to refine Argonne’s high-efficiency, fast-charging and fast-discharging thermal energy storage system for use in combined heat and power systems. The system, originally developed for use in concentrated solar power applications, will use phase change material to capture waste heat from industrial manufacturing processes. The goal is to integrate Argonne's technology into a Capstone C200 CHP system.

• New from Persistence Market Research"Global Market Study on Salt Hydrate: Pharmaceutical Industry to Remain Dominant Consumer Through 2026"

• New from QY Research: "Global Thermal Energy Storage Market Size, Status And Forecast 2025"

• New from Maia Research: "Inorganic PCMs Market Analysis, Market Size, Application, Analysis, Regional Outlook, Competitive Strategies And Forecasts, 2018 -2025"

• At the World Energy Engineering Congress in Charlotte, N.C., this week, Mark Richards of Phase Change Energy Solutions reports that the company demonstrated "a mini PhaseStor tank in action with 1/2 ton chiller and small heater (system hand made by Scott Queen) to charge and discharge the tank and includes on board DAQ system to show tank thermal performance." Richards presented at a panel discussion Friday, "Justifying HVAC Energy Savings in Buildings Using Phase Change Materials - A Debate with a Skeptical Engineer." Also presenting were Guy Frankenfield, energy division manager at DN Tanks Inc. ("Thermal Energy Storage - Uncovering the Value of Ice and Chilled Water TES Systems") and Ice Energy CEO Mike Hopkins ("Thermal Energy Storage in Package Units? Yes, it is Here").

Ice Cub is now available to California homeowners, builders

Ben Welter - Friday, October 12, 2018

The Ice Cub, Ice Energy's hybrid air-conditioning and thermal energy storage system, is now available for purchase by California homeowners and homebuilders.

The solar PV-compatible unit replaces a conventional 5-ton outdoor condensing unit and is designed to work seamlessly with home HVAC systems. The Ice Cub functions like a typical condensing unit, but it also makes ice to store up to four hours' worth of cooling.

"For homes with solar PV," Ice Energy says, "a full tank of ice can be made and stored during the day, using what would otherwise be surplus solar generation."

The Ice Cub retails for $15,000. But Ice Energy says two government incentives potentially reduce the cost of purchase and installation to below that of a conventional air conditioning system. The Ice Cub qualifies for California’s Self-Generation Incentive Program rebate and, for homes with solar PV, the federal Solar Investment Tax Credit. Ice Energy says the payback period for an Ice Cub installed in a California home with solar PV is less than one year.

The company, based in Southern California, says it is in the early stages of recruiting regional project partners such as homebuilders and HVAC installers.

“Conventional AC units in California have become increasingly expensive to operate as the state’s new time-of-use rates take effect,” said Joseph Draper, executive chairman of Ice Energy. “The Ice Cub, by contrast, reduces consumption of expensive electricity and can save homeowners as much as $1,500 a year on their utility bill. The smart, energy-efficient Ice Cub is a true consumer product with real potential to render conventional home AC units obsolete. We are very excited to make it available for immediate delivery to homeowners and builders here in California.”

https://www.solarpowerworldonline.com/2018/10/ice-energys-hybrid-air-conditioning-and-energy-storage-system-qualifies-for-itc-with-solar/

PCM briefing: Viking Cold Solutions to install system in Mexico; Pluss reaches distribution deal with Ferro-Plast of Italy

Ben Welter - Friday, October 12, 2018

Viking Cold Solutions of Houston, Texas, has reached a deal to install its PCM-based thermal energy storage system in one of Red de Frios' frozen food warehouses in Monterrey, Mexico. Viking systems are designed to reduce energy costs by shifting peak demand to nighttime hours.

• The German Aerospace Center, the Karlsruhe Institute of Technology and the University of Stuttgart have signed an agreement to build a research facility in Germany to develop an efficient, cost-effective and "virtually loss-less" heat-based electrical storage technology. At this week's signing ceremony in Stuttgart, Stanford University Professor Robert B. Laughlin, right, 1998 Nobel Laureate in Physics, explained why he thinks heat storage will play a key role in the energy landscape of the future.

• The Conductive Plastics conference in Vienna Nov. 6-7 will include sessions on "Challenging the boundaries in thermally conductive and electrically conductive polyamides," "Boron nitride filler materials for high-performance thermal management applications," "Mineral flame retardants and metal oxides as thermally conductive fillers," "Investigating the effect of material molecular orientation on thermal conductivity of polymeric products" and "Thermally conductive materials based on synthetic rubber."

• In a LinkedIn post, Pluss Advanced Technologies of India announced it has reached a deal with Ferro-Plast Srl of Italy to distribute Pluss products in Europe.

• New from MarketResearch.biz: "Global Advanced Phase Change Material (PCM) Market Trends, Applications, Analysis, Growth, And Forecast: 2018 To 2027"

• New from Invant Research: "Global Advanced Phase Change Material (PCM) Market Study 2015-2025"

• New from Future Market Insights: "Salt Hydrate Market: Global Industry Analysis 2012 - 2016 and Opportunity Assessment; 2017 - 2027"

• New from Polaris Market Research: "Fatty Acid Esters Market, [By Product Type (Glycerol Monostearate, Medium Chain Trigylcerides, Isopropyl Esters (Myrsitate & Palmitate) and Others); By Application (Lubricants, Pharmaceuticals, Personal care & Cosmetics, Surfactants and Others); By Regions]: Market size & Forecast, 2018 – 2026"

Peli BioThermal has opened service centers in Basel and Berlin to support the company's line of Credo reusable temperature-control shippers.

• Nominations are being accepted for Metrohm USA's Young Chemist Award 2019. Entrants submit an abstract of their research for a chance to win a $10,000 cash prize and an all-expenses-paid trip to PITTCON 2019. The contest is limited to undergrad, grad, post-grad and doctoral students in the United States and Canada. Entrants must demonstrate novel research or a novel methodology using titration, ion chromatography, electrochemistry and/or spectroscopy. Applications are due by Dec. 31, 2018.

Sonoco ThermoSafe, a global provider of temperature assurance packaging in the life sciences sector, has an opening for a sales director, responsible for sales growth in North America.

• Sonoco ThermoSafe has posted the agenda for the next Leading Minds Seminar, to be held Nov. 6-7 in London. Co-hosted by ELPRO, the seminar is a chance for pharmaceutical manufacturers, supply chain partners and government representatives to discuss temperature-assurance packaging and data monitoring in a collaborative environment.

ASHRAE Learning Institute will offer 20 courses during the 2019 ASHRAE Winter Conference and AHR Expo. The conference will be held in Atlanta Jan. 12-16. Courses include "Advanced Designs for Net Zero Buildings," "Thermal Energy Storage Systems for Air Conditioning" and "Solar PV and Thermal System Analysis and Design."

Research roundup: Crude glycerol polyurethane composite foams; heat transfer analysis; Kalina cycle; more

Ben Welter - Wednesday, October 10, 2018

From Materials:

Thermal Energy Storage and Mechanical Performance of Crude Glycerol Polyurethane Composite Foams Containing Phase Change Materials and Expandable Graphite

From International Journal of Energy Research:

Review on heat transfer analysis in thermal energy storage using latent heat storage systems and phase change materials

From International Journal of Heat and Mass Transfer:

Recent developments in phase change materials for energy storage applications: A review

From Energy Conversion and Management:

Integrated power generation cycle (Kalina cycle) with auxiliary heater and PCM energy storage

From Minerals:

Mullite Stabilized Palmitic Acid as Phase Change Materials for Thermal Energy Storage

From Applied Thermal Engineering:

Microencapsulated phase change material (MEPCM) saturated in metal foam as an efficient hybrid PCM for passive thermal management: A numerical and experimental study
Inverse method to estimate air flow rate during free cooling using PCM-air heat exchanger

Research roundup: Ternary hydrated salt mixture; earth-air heat exchanger; shape-stabilized fly ash composite PCM; more

Ben Welter - Monday, October 01, 2018

From Energy Conversion and Management:

Two types of composite phase change panels containing a ternary hydrated salt mixture for use in building envelope and ventilation system
Research on cooling performance of phase change material-filled earth-air heat exchanger
An experimental investigation of the phase change process effects on the system performance for the evacuated tube solar collectors integrated with PCMs

From Solar Energy:

Carbon based material included-shaped stabilized phase change materials for sunlight-driven energy conversion and storage: An extensive review

From Applied Thermal Engineering:

Experimental Study of Water Solidification Phenomenon for Ice-on-Coil Thermal Energy Storage Application Utilizing Falling Film

From Powder Technology:

Preparation and thermal properties of stearic acid-benzamide eutectic mixture/expanded graphite composites as phase change materials for thermal energy storage

From International Communications in Heat and Mass Transfer:

Experimental and numerical study of melting of the phase change material tetracosane

From Particuology:

Effect of particle size on the thermal performance of NaNO3/SiO2/C composite phase-change materials

From Materials Chemistry and Physics:

Low-cost, shape-stabilized fly ash composite phase change material synthesized by using a facile process for building energy efficiency

From Construction and Building Materials:

Preparation and thermal properties of encapsulated ceramsite-supported phase change materials used in asphalt pavements

From Applied Energy: