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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Thermoelectric generator system; solar chimney; novel thermal management system for lithium-ion battery pack; more

Ben Welter - Friday, May 18, 2018

From Energy:

Protection and Thermal Management of Thermoelectric Generator System Using Phase Change Materials: An Experimental Investigation
Performance analysis of a novel thermal management system with composite phase change material for a lithium-ion battery pack

From Solar Energy:

Efficient energy storage technologies for photovoltaic systems
The experimental appraisement of the effect of energy storage on the performance of solar chimney using phase change material

From Applied Thermal Engineering:

Improving thermal management of electronic apparatus with paraffin (PA)/expanded graphite (EG)/graphene (GN) composite material
Experimental exploration of incorporating form-stable hydrate salt phase change materials into cement mortar for thermal energy storage

From Thermal Science and Engineering Progress:

Role of Metallic Foam in Heat Storage in the Presence of Nanofluid and MicroEncapsulated Phase Change Material

From International Journal of Heat and Mass Transfer:

Numerical investigation of thermal and optical performance of window units filled with nanoparticle enhanced PCM

From Applied Energy:

Cost estimation and sensitivity analysis of a latent thermal energy storage system for supplementary cooling of air cooled condensers
Influence of design on performance of a latent heat storage system at high temperatures

From Energy Conversion and Management:

Preparation and investigation of distinct and shape stable paraffin/SiO2 composite PCM nanospheres

From Energy and Buildings:

Parametric Analysis of Using PCM Walls for Heating Loads Reduction

Patent application: Electric vehicle powered by capacitive energy storage modules

Ben Welter - Wednesday, May 16, 2018

U.S. patent application 20180126857 (applicant: Capacitor Sciences Inc., Menlo Park, Calif.):

"The invention relates to a capacitor based energy storage module and an electric vehicle using the same. For providing an electric vehicle which can meet the requirements of long distance running and rapid acceleration at the same time, the electric vehicle of present invention comprising: An electric control unit controlling all operations of the electric vehicle; An energy storage unit having one or more energy devices based on meta-capacitor which provides needed electric energy of the electric vehicle; A DC-DC converter receiving control signal from said electric control unit to convert the energy from said energy storage unit then provide to motor; A motor converting the electric energy into mechanical energy to drive the wheels; Wheels are driven by the motor to make the electric vehicle run. ... [The] capacitive energy storage module may include a cooling mechanism in thermal contact with the capacitive energy storage device and/or the DC-voltage converter. Such a cooling mechanism may be, e.g., a passive cooling mechanism, an active cooling system using air, water, ethylene glycol as a coolant; phase-change material, or any combination thereof."

http://www.freepatentsonline.com/20180126857.pdf

Patent application: Method and system for battery protection

Ben Welter - Wednesday, May 16, 2018

Milwaukee battery pack patent drawingU.S. patent application 20180131036 (applicant Milwaukee Electric Tool Corp., Brookfield, Wis.):

"The present invention provides a system and method for battery protection. In one construction and in some aspects, the invention provides a system and method for monitoring the temperature of a battery. In another construction and in some aspects, the invention provides a system and method for transferring heat within a battery pack. In another construction and in some aspects, the invention provides a system and method for transferring heat within a battery pack via a phase change material [300]."

http://www.freepatentsonline.com/20180131036.pdf

PCM keeps Embry-Riddle’s EcoCAR entry running cool

Ben Welter - Monday, April 30, 2018

Batteries used in hybrid and electric cars work hard and run hot. Traditional cooling systems use an array of pumps, heat exchangers, cooling fans and hoses to manage that heat. Florida’s Embry-Riddle Aeronautical University needed something lighter and simpler for its entry in the Department of Energy’s EcoCAR 3 competition.

The solution: an aluminum cooling plate filled with biobased phase change material.

A team of mechanical engineering students at the school designed and built the plate under the direction of Sandra Boetcher, associate professor of mechanical engineering.

The school’s EcoCAR entry required that the plate use a PCM with a peak melting point of 45 degrees Celsius (113 degrees F). To achieve that temperature, the team selected two commercially available PCMs – PureTemp 37 and PureTemp 48 – and mixed them together.

Embry-Riddle cold plateBoetcher explains the photo at right:

“That’s the inside of the plate before we sealed the aluminum lid on it. On the inside is a copper tube. At the time we put this in the car, we were under a strict deadline and did not have time to redo the bending of the copper tube. The copper tube feeds a cold ethylene-glycol/water mixture as backup for when the PCM has completely melted and needs to resolidify while the car is driving.

“I was concerned that the copper tube didn’t provide enough coverage of the area, but that cold plate has been in the car for the past 2.5 years and it works great. Actually, the back-up pump that runs the ethylene-glycol/water through the copper tube rarely even turns on which means that under our test-driving conditions, the cold plate is acting 100 percent passive. The terrible part of the PCM is that it loves to leak. We feel that there has been some leaking.”

The plate is lighter and simpler than a water-cooled system. “It doesn’t take any energy to run,” said Patrick Currier, an associate professor who advises the EcoCAR team. “We’re not wasting power cooling things. This is a totally passive system, so unless it leaks, it can’t fail.”

Embry-Riddle filed for a U.S. patent on the device in 2015.

“The diagrams in the patent are similar to what we have in the EcoCAR right now, although the geometry is a little different,” Boetcher said. “The research we are conducting is still on-going. The applications we envision could be anything that requires PCM – battery cooling, building technologies, etc.”

Embry-Riddle is one of 16 North American universities challenged to redesign a 2016 Chevrolet Camaro into a hybrid-electric car to reduce environmental impact, while maintaining the “muscle and performance” the car is known for. 

The teams have had four years to develop their entries. The cars will be put to the test in a variety of events in Arizona and California in May. Winners will be chosen in 40-plus categories at an awards ceremony in Hollywood on May 22, with more than $100,000 in prize money at stake.

Embry-Riddle EcoCAR entry

https://news.erau.edu/headlines/shape-shifters-lightweight-technology-keeps-batteries-cool-supporting-eco-vehicles

Research roundup: Fabrication of shape-stable composite PCMs; battery thermal management; segmented heat storage; more

Ben Welter - Wednesday, April 18, 2018

Fabrication of shape-stable composite phase change materials based on lauric acid and graphene/graphene oxide complex aerogels for enhancement of thermal energy storage and electrical conduction [Thermochimica Acta]

Performance analysis of PCM based thermal energy storage system containing nanoparticles [International Research Journal of Engineering and Technology]

Cold temperature performance of phase change material based battery thermal management systems [Energy Reports]

Design and functionality of a segmented heat-storage prototype utilizing stable supercooling of sodium acetate trihydrate in a solar heating system [Applied Energy]

Macro-encapsulation and characterization of chloride based inorganic phase change materials for high temperature thermal energy storage systems [Applied Energy]

Parametric analysis of a residential building with phase change material (PCM)-enhanced drywall, precooling, and variable electric rates in a hot and dry climate [Applied Energy]

Fabrication of high thermal conductive shape-stabilized polyethylene glycol/silica phase change composite by two-step sol gel method [Composites Part A: Applied Science and Manufacturing]

Performance enhancement of cold thermal energy storage system using nanofluid phase change materials: A review [International Communications in Heat and Mass Transfer]

Development of form stable Poly(methyl methacrylate) (PMMA) coated thermal phase change material for solar water heater applications [IOP Conference Series: Earth and Environmental Science]

Patent application: Battery pack with PCM

Ben Welter - Monday, April 02, 2018

U.S. patent application 20180090728 (applicant LG Chem Ltd., Seoul, South Korea):

"A battery pack according to the present invention comprises a battery cell and a battery case accommodating the battery cell, wherein the battery case comprises an inner case accommodating the battery cell, an outer case disposed outside the inner case, and a cooling member between the inner and outer cases to indirectly cool the battery cell by using cool air generated by cooling the inner and outer cases."

http://www.freepatentsonline.com/20180090728.pdf

Research roundup: Personal cooling device; China's cold chain; prismatic lithium ion batteries; more

Ben Welter - Friday, March 16, 2018

"Preparation and Characterization of Modified Porous Wood Flour/Lauric-Myristic Acid Eutectic Mixture as a Form-Stable Phase Change Material" [Energy & Fuels]

A novel phase based cooling system for prismatic lithium ion batteries [Institut International du Froid]

Optimization of solar photovoltaic system integrated with phase change material [Solar Energy]

A novel heat transfer enhancement technique for performance improvements in encapsulated latent heat storage system [Solar Energy]

Experimental and numerical investigation of a solar collector/storage system with composite phase change materials [Solar Energy]

Enhanced thermal conductivity of phase change material nanocomposites based on MnO2 nanowires and nanotubes for energy storage [Solar Energy Materials and Solar Cells]

Enhancing the Thermosiphon-Driven Discharge of a Latent Heat Thermal Storage System used in a Personal Cooling Device [International Journal of Refrigeration]

An Overview of Current Status of Cold Chain in China [International Journal of Refrigeration]

Applications of Thermal Analysis to the Study of Phase-Change Materials [Handbook of Thermal Analysis and Calorimetry]

Thermo-physical characteristics, mechanical performance and long-term stability of high temperature latent heat storages based on paraffin-polymer compounds [Thermochimica Acta]

High thermal conductive paraffin/calcium carbonate phase change microcapsules based composites with different carbon network [Applied Energy]

Research roundup: Biomass carbon aerogels from succulents; novel hybrid cooling for lithium-ion batteries; calcium carbonate, graphene oxide shell; more

Ben Welter - Thursday, March 08, 2018

Leakage-proof Phase Change Composites Supported by Biomass Carbon Aerogels from Succulents [Green Chemistry]

Experimental Investigation of a Novel Hybrid Cooling Method for Lithium-ion Batteries [Applied Thermal Engineering]

Modified phase change microcapsules with calcium carbonate and graphene oxide shell for enhanced energy storage and leakage prevention [Sustainable Chemistry & Engineering]

A Novel Thermal Energy Storage System in Smart Building Based on Phase Change Material [IEEE Transactions on Smart Grid]

Study of Material Compatibility for a Thermal Energy Storage System with Phase Change Material [Energies]

Is a self-sufficient building energy efficient? Lesson learned from a case study in Mediterranean climate [Applied Energy]

Research roundup: Thermal protective clothing; nanosilica-enhanced PCM; active-passive ventilation wall; more

Ben Welter - Wednesday, February 28, 2018

Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing [Applied Energy]

Micro encapsulated & form-stable phase change materials for high temperature thermal energy storage [Applied Energy]

Thermal performance of an active-passive ventilation wall with phase change material in solar greenhouses [Applied Energy]

A novel nanosilica-enhanced phase change material with anti-leakage and anti-volume-changes properties for battery thermal management [Energy Conversion and Management]

Synthetic Comb-Like Phase-Change Material Poly(Acrylonitrile-co-Lauric Acid) Copolymer for Low Temperature Energy Management [Materials Science Forum]

Fundamental incorporation of the density change during melting of a confined phase change material [Journal of Applied Physics]

Preliminary investigation of thermal behaviour of PCM based latent heat thermal energy storage [E3S Web of Conferences]

Patent application: Battery pack containing phase change material

Ben Welter - Thursday, February 22, 2018

U.S. patent application 20180053977 (University of Sherbrooke Research Consortium, Sherbrooke, Quebec):

"A battery pack for a vehicle is presented. The battery pack comprises a plurality of bricks, each brick of the plurality of bricks comprising a phase change material block, a side of the phase change material block defining a plurality of channels, and a plurality of battery cells, each battery cell being disposed at least in part in the phase change material block; and at least one connector for electrically connecting a first one of the plurality of bricks to a second one of the plurality of bricks, the at least one connector being disposed at least partially in one of the plurality of channels."

http://www.freepatentsonline.com/20180053977.pdf