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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Radiant floor heating system; mitigation of supercooling; hot water stratification; more

Ben Welter - Friday, March 08, 2019

From Energies:

Analysis of Thermal Performance and Energy Saving Potential by PCM Radiant Floor Heating System based on Wet Construction Method and Hot Water

From Applied Energy:

Supercooling of phase-change materials and the techniques used to mitigate the phenomenon

From Polymer Chemistry:

Encapsulating an organic phase change material within emulsion-templated poly(urethane urea)s

From AIP Advances:

Thermal expansion effects on the one-dimensional liquid-solid phase transition in high temperature phase change materials

From Journal of Materials Chemistry A:

A thermal energy storage composite with sensing function and its thermal conductivity and thermal effusivity enhancement

From Materials Science and Engineering:

Experimental Measurements of Hot Water Stratification in a Heat Storage Tank

From Thermochimica Acta:

Modification of physical and thermal characteristics of stearic acid as a phase change materials using TiO2-nanoparticles

From Energy and Buildings:

Thermal and Structural Performance of Geopolymer Concrete Containing Phase Change Material Encapsulated in Expanded Clay
An experimental study on applying organic PCMs to gypsum-cement board for improving thermal performance of buildings in different climates

From International Journal of Biological Macromolecules:

Sodium alginate/feather keratin-g-allyloxy polyethylene glycol composite phase change fiber

From Construction and Building Materials:

Thermal properties of lightweight concrete incorporating high contents of phase change materials

From Progress in Organic Coatings:

Fabrication and characterization of microencapsulated n-heptadecane with graphene/starch composite shell for thermal energy storage

From Sustainable Energy and Fuels:

A thermal energy storage prototype using sodium magnesium hydride

From Thermal Science and Engineering Progress:

Experimental investigation of the thermal performance of a helical coil latent heat thermal energy storage for solar energy applications

From International Journal of Sports Physiology and Performance:

Exploring the Efficacy of a Safe Cryotherapy Alternative: Physiological Temperature Changes from Cold Water Immersion vs Prolonged Phase Change Material Cooling

From Applied Sciences:

A Form Stable Composite Phase Change Material for Thermal Energy Storage Applications over 700° C

PCM briefing: Energy Storage Europe includes sessions on thermal storage; C-Therm offers webinar on thermal performance of textiles

Ben Welter - Monday, March 04, 2019

• The Energy Storage Europe conference and trade fair, set for March 12-14 in Dusseldorf, Germany, includes a number of sessions on thermal energy storage: "Heat Storage - an essential contribution to energy transition," Oliver Baudson, TSK Flagsol Engineering GmbH; "Advanced Thermal Energy Storage Concepts," Dr. Robert Pitz-Paal, DLR Institute of Solar Research; "High Temperature Storage," Doron Brenmiller, Brenmiller Energy; "Material and Component Development for Thermal Energy Storage," Christoph Rathgeber, ZAE Bayern; and "Thermal Energy Storage for Cost-Effective Energy Management & CO2 Mitigation," Dr. Dan Bauer, German Aerospace Center - DLR e.V.

• The deadline for submitting paper proposals for next fall's Advanced Building Skins conference in Bern, Switzerland, is March 10. The list of topics includes thermal performance of phase change materials.

• Thermal battery maker Sunamp Ltd.'s collaboration with the University of Edinburgh’s School of Chemistry won the "Powerful Partnership" award at the Scottish Knowledge Exchange Awards 2019 last month. The organizations began work on the development of new phase change materials in 2010. 

• Croda International Plc has been recognized for its commitment to "a deforestation-free supply chain." Croda earned an A- in that category in CDP's climate change report for 2018, up from a B the previous year. The specialty chemical company says it has a special focus on palm oil and is committed to supplying RSPO-certified palm oil derivatives. 

• Thermal instrumentation maker C-Therm Technologies Ltd. is hosting a free webinar this week, "Quantifying Thermal Performance of Textiles (Warm Feel / Cool Touch)." The webinar, aimed at "anyone working in the product performance testing of textiles and fabrics where temperature regulation is an important function," will be held at 1 p.m. EST Wednesday.

Research roundup: PCM wallboard; cement mortars; electric load shifting; red-mud geopolymer composite; more

Ben Welter - Wednesday, February 27, 2019

From Renewable Energy:

Phase Change Material Wallboard (PCMW) melting temperature optimisation for passive indoor temperature control

From Cement and Concrete Research:

Multiphysics analysis of effects of encapsulated phase change materials (PCMs) in cement mortars

From Journal of Molecular Liquids:

Preparation and characterization of sodium sulfate pentahydrate/sodium pyrophosphate composite phase change energy storage materials

From Energy and Buildings:

Performance of heat pump integrated phase change material thermal storage for electric load shifting in building demand side management
Indoor thermal comfort assessment using PCM based storage system integrated with ceiling fan ventilation: Experimental design and response surface approach

From International Journal of Photoenergy:

Experimental Study on the Performance of a Phase Change Slurry-Based Heat Pipe Solar Photovoltaic/Thermal Cogeneration System

From Solar Energy:

Effects of sodium nitrate concentration on thermophysical properties of solar salts and on the thermal energy storage cost
Red-mud geopolymer composite encapsulated phase change material for thermal comfort in built-sector [pdf]

From Energies:

A Novel Encapsulation Method for Phase Change Materials with a AgBr Shell as a Thermal Energy Storage Material

From Advanced Composites and Hybrid Materials:

Latent heat and thermal conductivity enhancements in polyethylene glycol/polyethylene glycol-grafted graphene oxide composites

From International Journal of Refrigeration:

Preparation and performance of form-stable TBAB hydrate/SiO2 composite PCM for cold energy storage

From Solar Energy Materials and Solar Cells:

Delignified wood/capric acid-palmitic acid mixture stable-form phase change material for thermal storage
Molten salt corrosion mechanisms of nitrate based thermal energy storage materials for concentrated solar power plants: A review

From Buildings:

Thermal Performance of Hollow-Core Slab Ventilation System with Macro-Encapsulated Phase-Change Materials in Supply Air Duct

From International Journal of Heat and Mass Transfer:

Heat transfer performance of the finned nano-enhanced phase change material system under the inclination influence

From Journal of the Electrochemical Society:

Effect of High Temperature Circumstance on Lithium-Ion Battery and the Application of Phase Change Material

From Energy:

High-temperature PCM-based thermal energy storage for industrial furnaces installed in energy-intensive industries

PCM mats helped lift Virginia Tech to first place in Solar Decathlon

Ben Welter - Monday, February 18, 2019

FutureHAUS, front elevation

The Virginia Tech team that won first place in the 2018 Solar Decathlon Middle East credits a good share of its success to the deft use of phase change material donated by Insolcorp LLC of New London, N.C.

FutureHAUS, the lone U.S. entry, topped 13 other finalists and more than 60 total entrants in the competition organized by the U.S. Department of Energy and the United Arab Emirates’ Dubai Electricity & Water Authority. Australia's University of Wollongong finished second. The finals took place in November in the desert heat of Dubai.

Insolcorp donated 400 square feet of two types of Infinite R PCM mats. Both are salt hydrates, one with a melt point of 21 degrees Celsius, the other a melt point of 22 degrees C. The phase change material acts as a thermal battery, absorbing and releasing thermal energy as it solidifies and melts.

The Virginia Tech team deployed the mats in the plenum of its 900-square-foot solar-powered house. The PCM allowed the team to take advantage of a rule that limited the use of solar energy to 8kw at any one time, with one exception: Unlimited use of solar energy for air conditioning was allowed during daily inspection periods to assure visitor comfort. The PCM mats, solidified during those periods, helped keep the house comfortable at other times. That helped the FutureHAUS achieve the highest score in net energy use, a key metric in the competition.

Joseph Wheeler, AIA"Every team struggled with the 8kw limit," said Joseph Wheeler, right, lead faculty on FutureHAUS and co-director of Virginia Tech's Center for Design Research. "Typically, during peak energy, you would be generating lots and lots of power, which you could easily charge your batteries with, which you could easily run all your tasks, and you could feed the grid, and build up quite a bit of surplus so that you would remain energy positive throughout the two weeks of competition.

"But, since they limited inverter use at any one time to 8kw, it really put a limit to what our energy budget was. We saw phase change as batteries. A massive ton of batteries. ... It's more of a strategy for a competition than it is for a realized situation. But in a realized situation, we know the value of the PCM. Heat energy, cost of power being cheaper at night than during the day where you can charge your systems and load shift. Practically, PCMs make a lot of sense. And we wanted to have the PCMs in this house for practical reasons, not just for competition reasons. ...

"In simple terms, we eased the demand for the HVAC every afternoon. It was the hottest time of the day and it was also the time when we were getting less power from the solar panels because the sun was moving down. It was a critical time because we knew that once the sun went down, we had to survive on battery. And we had a limit. They limited every house to 15kw of battery."

FutureHAUS, kitchenThe FutureHAUS team finished in the top three in eight of the competition's 10 categories: first place in Architecture, House Functioning and Sustainable Transportation; second place in Sustainability and Innovation; and third place in Engineering/Construction, Energy Efficiency and Comfort Conditions.

The FutureHAUS entry was a two-year university-wide effort. More than 100 Virginia Tech students helped design and build the structure, with help from faculty members in architecture, urban studies, science, engineering and other departments.

The house consists of 18 modular  "cartridges" built inside a Virginia Tech research facility. It was first assembled on campus in Blacksburg, Va., last summer. After testing, it was disassembled, shipped to Dubai and then reassembled at the competition site in just two days. It has since been shipped back to Blacksburg, where it will undergo testing to measure its various energy-saving components.

"We now have a system in place where we can collect data and can truly test the performance," Wheeler said. "We know the PCM worked for us during the competition because we did have some temperature sensors in the ceiling. And so we were able to prove that we were reaching the pre-state when those PCMs were being charged. But we really want to collect a lot more data and look at it in real-world situations."

PCM briefing: PureTemp joins RSPO; Reda's new PCM fabric on display in Milan

Ben Welter - Monday, February 18, 2019

PureTemp LLC has joined the Roundtable for Sustainable Palm Oil as an associate member. The nonprofit organization, which has more than 4,000 members worldwide, promotes the growth and use of sustainable oil palm products. In November, RSPO adopted stricter standards for certified sustainable palm oil, including a total ban on deforestation by its members.

Reda Group's new Active Phase temperature-control fabric was on display at the Milan fabric trade show earlier this month. The material uses phase change material to keep body temperature constant when ambient temperature fluctuates. Reda says the material features enhanced breathability and softness and is "easy to clean, even in water."

University of Maryland fabric•  University of Maryland researchers have created a temperature-control fabric that does not rely on phase change material. The fabric changes its insulating properties in response to the environment. In warm and humid conditions, the fabric allows radiant heat to pass through. When conditions become cooler and drier, the fabric reduces the heat that escapes. Two types of synthetic materials in the fabric — one that absorbs water and another other that repels it — are coated with carbon nanotubes. The fibers warp and relax in response to changing humidity, opening and closing pores in the fabric. 

• In interviews with Advanced Textiles Source, four entrepreneurs were asked: What do you wish you had known early on when you were first dealing with intellectual property law and patent issues? “Get feedback on why you need a patent,” said Jeremy Wall, founder and CEO of smart-clothing startup Lumenus. “Where else could you spend $20,000?” Said Matt Kolmes, CEO of VOLT Smart Yarns: “Even if you are on a tight budget, file that Provisional application immediately before you show your idea to anyone, or talk about it with anyone."

• The Marie Sklodowska-Curie Action program is seeking applicants for a one- to two-year research fellowship at the Oslo Metropolitan University. The European Union-funded fellowship will focus on the energy-performance aspects of phase change material in buildings. "In this collaboration," OsloMet says, "we intend to gain our understanding and explore about the micro-structural aspect to relate the macro-scale behavior at continuum level." The application deadline is March 7.

Patent application: Battery pack containing phase change material

Ben Welter - Thursday, February 14, 2019

U.S. patent application 20190051955 (applicant Consortium de Recherche BRP / Universite de Sherbrooke, Canada):

"A battery pack for a vehicle is presented. The battery pack comprises a plurality of bricks, each brick of the plurality of bricks comprising a phase change material block, a side of the phase change material block defining a plurality of channels, and a plurality of battery cells, each battery cell being disposed at least in part in the phase change material block; and at least one connector for electrically connecting a first one of the plurality of bricks to a second one of the plurality of bricks, the at least one connector being disposed at least partially in one of the plurality of channels."

http://www.freepatentsonline.com/20190051955.pdf

Research roundup: Self-luminous wood composite; palmitic acid/mullite composite; corrosion sensitivity of metal alloys; more

Ben Welter - Tuesday, February 12, 2019

From Energy Storage Materials:

Self-luminous wood composite for both thermal and light energy storage

From International Journal of Refrigeration:

The thermal performances of a refrigerator incorporating a Phase Change Material

From Renewable Energy:

Enhanced thermal conductivity of palmitic acid/mullite phase change composite with graphite powder for thermal energy storage
An experimental study on the corrosion sensitivity of metal alloys for usage in PCM thermal energy storages

From Energy Conversion and Management:

Sorption thermal energy storage: Hybrid coating/granules adsorber design and hybrid TCM/PCM operation
Novel hybrid microencapsulated phase change materials incorporated wallboard for year-long year energy storage in buildings

From Thermochimica Acta:

Experimental Investigation on Thermal Properties of Sodium Acetate Trihydrate based Phase Change Materials for Thermal Energy Storage
The preparation of AgI/Au/foam-Cu as a framework of composite for water-based cool storage phase-change material with low supercooling

From Energy and Buildings:

Nano-encapsulation of phase change materials: from design to thermal performance, simulations and toxicological assessment
Investigation of phase change materials integrated with fin-tube baseboard convector for space heating

From Journal of Energy Storage:

Nano-enhancement of phase change material in a shell and multi-PCM-tube heat exchanger

From Applied Energy:

Numerical investigation of phase change material thermal storage for space cooling

From Journal of Materials Chemistry A:

Vertically aligned carbon fibers as supporting scaffolds for phase change composites with anisotropic thermal-conductivity and good shape-stability

Research roundup: Thermal conductivity; decarbonization potential of compact heat storage; liquid desiccant cooling systems; more

Ben Welter - Wednesday, February 06, 2019

From Energy:

Effects of thermal conductivity and density on phase change materials-based thermal energy storage systems

From Renewable Energy:

Melting process investigation of phase change materials in a shell and tube heat exchanger enhanced with heat pipe

From Applied Thermal Engineering:

Compact latent heat storage decarbonisation potential for domestic hot water and space heating applications in the UK
Numerical and experimental study of phase-change temperature controller containing graded cellular material fabricated by additive manufacturing
A novel composite phase change material with paraffin wax in tailings porous ceramics
Characterisation and evaluation of a new phase change enhanced working solution for liquid desiccant cooling systems
Thermal properties enhancement and application of a novel sodium acetate trihydrate-formamide/expanded graphite shape-stabilized composite phase change material for electric radiant floor heating

From Environmental Research:

Latent heat storage biocomposites of phase change material-biochar as feasible eco-friendly building materials

From Colloids and Surfaces A:

A facile microencapsulation of phase change materials within silicone-based shells by using glass capillary devices

From Microporous and Mesoporous Materials:

Phase change in modified metal organic frameworks MIL-101(Cr): Mechanism on highly improved energy storage performance

From Applied Energy:

Role of porous metal foam on the heat transfer enhancement for a thermal energy storage tube
Energy saving performance assessment and lessons learned from the operation of an active phase change materials system in a multi-storey building in Melbourne

From Building and Environment:

Comparative analysis of the PCM application according to the building type as retrofit system

From Construction and Building Materials:

Evaluation of the potential use of form-stable phase change materials to improve the freeze-thaw resistance of concrete

From Results in Physics:

Application Research of Nano-storage Materials in Cold Chain Logistics of E-commerce Fresh Agricultural Products

From Journal of Energy Storage:

Using PCM as energy storage material in water tanks: Theoretical and experimental investigation

Research roundup: Micro environmental control system; alkali nitrate salts; sodium thiosulfate pentahydrate; more

Ben Welter - Tuesday, January 22, 2019

From Journal of Thermal Science and Engineering :

Phase Change Material Freezing in an Energy Storage Module for a Micro Environmental Control System
Phase Change Material Melting in an Energy Storage Module for a Micro Environmental Control System

From Renewable Energy:

Form-stable oxalic acid dihydrate/glycolic acid-based composite PCMs for thermal energy storage
Molecular simulation of the structure and physical properties of alkali nitrate salts for thermal energy storage

From Applied Energy:

Effect of inclination on the thermal response of composite phase change materials for thermal energy storage

From Solar Energy Materials and Solar Cells:

Characterization and thermal performance of microencapsulated sodium thiosulfate pentahydrate as phase change material for thermal energy storage
Fabrication and applications of dual-responsive microencapsulated phase change material with enhanced solar energy-storage and solar photocatalytic effectiveness

From Energy:

Numerical investigations of optimal phase change material incorporated into ventilated walls

From Polymer Degradation and Stability:

EG-based coatings for flame retardance of shape stabilized phase change materials

From Construction and Building Materials:

Freeze-thaw performance of phase change material (PCM) incorporated pavement subgrade soil

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Patent application: Radiative cooling with solar spectrum reflection

Ben Welter - Tuesday, January 22, 2019

U.S. patent application 20190017758 (applicant Board of Trustees of Stanford University, Stanford, Calif.):

"Aspects of the present disclosure are directed toward radiative cooling with solar spectrum reflection. In certain more specific embodiments, a structure facilitates far-field radiation at particular wavelengths while blocking radiation at solar wavelengths. Additionally, aspects of the present disclosure allow for twenty-four hour cooling of buildings and similar structures, and for cooling through a heat exchange to other liquid, gases, or solids. ... The heat exchange interface may further interface with phase-change materials either directly or indirectly to allow for thermal storage driven by the radiative properties of the plurality of different materials."

http://www.freepatentsonline.com/20190017758.pdf