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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the monthly PCM newsletter. Or join the discussion on LinkedIn.




PCM briefing: Lineup set for TES forum in Duesseldorf; CIC Energigune joins European research network

Ben Welter - Friday, June 21, 2019

Christoph Rathgeber of ZAE Bayern and Michael Andretzky of the University of Duisburg-Essen are among the speakers at next week's Thermal Energy Storage Forum in Dusseldorf, Germany. The forum will focus on the use of thermal storage in industrial processes. Rathgeber's topic is "Economy of thermal energy storage." Andretzky's topic: "PCM in buffer tank for CHPs."

Crystallize bubble• Another frosty gem from Physics Today: "Bubbles freeze in a swirl of ice crystals"

Siemens Gamesa Renewable Energy has launched an electric thermal energy storage system designed to store large quantities of energy cost-effectively. The pilot plant in Hamburg can store up to 130 MWh of thermal energy for a week. It uses a steam turbine to convert stored energy into electricity. 

CIC Energigune, a thermal energy storage research center in Spain's Basque Country, has joined the ALISTORE-ERI network. The European network brings together 20 research centers and 12 companies engaged in advanced energy storage research.

Viking Cold Solutions of Houston has made Food Logistics' list of Top Green Providers 2019. Viking was honored in two categories, refrigeration and alternative fuels &  energy. The company says its PCM-based thermal storage system, designed for use in cold storage facilities, can reduce energy consumption by more than 25 percent.

Cryopak, a maker of insulated shipping containers, gel packs and phase change materials, says it is taking steps toward reducing its carbon footprint with the launch of a new line of shipping solutions. The company, based in Edison, N.J. says its R3 Service Program "minimizes the need for insulation materials, phase change solutions, bottles and their necessary disposal by handling the coordination of container delivery, reverse logistics and required refurbishment."

Sonoco ThermoSafe has an opening for a sales manager with "experience in strategic selling across Europe."

Research roundup: Form-stable PCM; polyethylene glycol/quartz composites; fuzzy clustering; more

Ben Welter - Tuesday, June 18, 2019

From Renewable Energy:

A N-octadecane/hierarchically Porous TiO2 Form-Stable PCM for Thermal Energy Storage

From International Journal of Energy Research:

Hybrid solar parabolic dish power plant and high‐temperature phase change material energy storage system

From Journal of Applied Polymer Science:

Thermal and dynamic mechanical properties of polyethylene glycol/quartz composites for phase change materials

From Journal of Cleaner Production:

Using fuzzy clustering and weighted cumulative probability distribution techniques for optimal design of phase change material thermal energy storage

From Construction and Building Materials:

Thermoregulation effect analysis of microencapsulated phase change thermoregulation agent for asphalt pavement

From Applied Energy:

Residential cooling using separated and coupled precooling and thermal energy storage strategies

Research roundup: Building-integrated PV with PCM; double skin facade; lab-scale thermal energy accumulator; more

Ben Welter - Friday, June 14, 2019

From Solar Energy:

Effectiveness of phase change materials for improving the resiliency of residential buildings to extreme thermal conditions

From Energy Conversion and Management:

Analysis and design of air ventilated building integrated photovoltaic (BIPV) system incorporating phase change materials
Experimental and numerical study on a novel hybrid battery thermal management system integrated forced-air convection and phase change material

From Applied Thermal Engineering:

Thermal Performance of Electrospun Core-Shell Phase Change Fibrous layers at Simulated Body Conditions

From Applied Engineering:

Phase change material blind system for double skin façade integration: System development and thermal performance evaluation

From Building and Environment:

Reduced-scale experiments on the thermal performance of phase change material wallboard in different climate conditions

From Renewable Energy:

Analysis of a laboratory scale thermal energy accumulator using two-phases heterogeneous paraffin wax-water mixtures

From Thermochimica Acta:

Nano-inclusion aided thermal conductivity enhancement in palmitic acid/di-methyl formamide phase change material for latent heat thermal energy storage

From Journal of Manufacturing Processes:

Experimental investigation of phase change materials fabricated using selective laser sintering additive manufacturing

From International Journal of Heat and Mass Transfer:

Cyclic characteristics of water thermocline storage tank with encapsulated PCM packed bed

From Journal of Building Engineering:

Thermal behaviour of wallboard incorporating a binary mixture as a phase change material

From Composites Part B: Engineering:

Effects of aging on asphalt binders modified with microencapsulated phase change material

From Chemistry Select:

Experimental Study of the Thermal Properties of Microencapsulated Palmitic Acid Composites with CuCO3 Shell as Thermal Energy Storage Materials

From Fire Safety Journal:

Fire resistance of light gauge steel framed wall systems lined with PCM-plasterboards

From ACS Applied Nano Materials:

Size-tunable Alumina-encapsulated Sn-based Phase Change Materials for Thermal Energy Storage

Have you ever seen a DSC quite like this?

Ben Welter - Friday, June 07, 2019

More than 120 years ago, German chemist Emil Fischer said his lab had developed a crystal that seemed to defy the laws of physics. The solid form of acetaldehyde phenylhydrazone kept melting at two different temperatures. One batch might melt at 65° C; another at 100° C. Physics Today explains how the mystery was eventually solved: 

DSC of mysterious crystal APH"Colleagues and rivals at the time told him he must have made a mistake. Fischer didn’t think so. As far as he could tell, the crystals that melted at such different points were identical. A few groups in Britain and France repeated his work and got the same baffling results. But as those scientists died off, the mystery was forgotten, stranded in obscure academic journals published in German and French more than a century ago.

"There it would probably have remained but for Terry Threlfall, an 84-year-old chemist at the University of Southampton, UK. Stumbling across Fischer’s 1896 paper in a library about a decade ago, Threlfall was intrigued enough to kick-start an international investigation of the mysterious crystal. Earlier this year in the journal Crystal Growth and Design, Threlfall and his colleagues published the solution: APH is the first recorded example of a solid that, when it melts, forms two structurally distinct liquids. Which liquid emerges comes down to contamination so subtle that it’s virtually undetectable."

Research roundup: Energy management of household refrigerator; borehole heat exchangers; more

Ben Welter - Thursday, June 06, 2019

From Energy:

Energy management of a household refrigerator using eutectic environmental friendly PCMs in a cascaded condition
Use of encapsulated phase change materials in lightweight building walls for annual thermal regulation
Screening of sugar alcohols and their binary eutectic mixtures as phase change materials for low-to-medium temperature thermal energy storage.

From Industrial and Engineering Chemistry Research:

Biodegradable Polymeric Solid Framework-based Organic Phase Change Materials for Thermal Energy Storage

From Renewable Energy:

Thermal Management and Uniform Temperature Regulation of Photovoltaic Modules Using Hybrid Phase Change Materials-Nanofluids System
Polyethylene glycol/silica (PEG@SiO2) composite inspired by the synthesis of mesoporous materials as shape-stabilized phase change material for energy storage

From International Journal of Energy Research:

Thermal buffering effect of a packaging design with microencapsulated phase change material
Laboratory investigation on the use of thermally enhanced phase change material to improve the performance of borehole heat exchangers for ground source heat pumps

From IOP Conference Series: Materials Science and Engineering:

Thermal properties of cool asphalt concrete containing phase change material

From International Journal of Advance Research and Innovation:

Experimental Investigation of Thermal energy storage with phase changing material [pdf]

From Thermal Science and Engineering Progress:

Experimental study on thermal storage and heat transfer performance of microencapsulated phase-change material slurry

From Journal of Molecular Liquids:

Thermal conductivity modification of n-octanoic acid-myristic acid composite phase change material

From International Journal of Refrigeration:

Experimental study of enhanced PCM exchangers applied in a thermal energy storage system for personal cooling

From Applied Thermal Engineering:

Development of paraffinic phase change material nanoemulsions for thermal energy storage and transport in low-temperature applications
Effect of micro encapsulated phase change material on the anti-dry-out ability of pulsating heat pipes

From Construction and Building Materials:

Integrating phase change materials in construction materials: Critical review

From Solar Energy Materials and Solar Cells:

Compatibility of vegetable oils with solid filler materials for thermocline thermal energy storage systems
Novel paraffin/ethylene propylene diene monomer phase change latex with excellent stability and low viscosity

From Applied Materials and Interfaces:

Natural Microtubule-Encapsulated Phase-Change Material with Simultaneously High Latent Heat Capacity and Enhanced Thermal Conductivity

From Applied Energy:

System performance and economic assessment of a thermal energy storage based air-conditioning unit for transport applications
Experimental investigation of a cementitious heat storage medium incorporating a solar salt/diatomite composite phase change material

PCM briefing: Building Skins conference agenda; tough words for CALMAC and Axiom Exergy

Ben Welter - Saturday, May 25, 2019

• The agenda is set for the 14th International Conference on Advanced Building Skins, to be held Oct. 28-29 in Bern, Switzerland. The Japanese architect and Pritzker laureate Shigeru Ban will be the keynote speaker. Among the more than 150 speakers is Thomas Friedrich of Innogration GmbH, Germany, who will discuss "collection of thermal energy from the façade" and "decentralized PCM storage elements for saving thermal energy." The registration fee is 680 euros and includes the conference documentation as well as meals during both days. Participants who register by May 31 will receive a 20 percent discount.

Mike HopkinsIn a LinkedIn post, former Ice Energy CEO Mike Hopkins shared his take on two of the California company's competitors in distributed thermal energy storage. "Look at @CALMAC, a Portfolio of Trane - been in our industry forever, good product, but haven't been able to secure utility deals because their large bespoke systems make it too risky to commit to MWs in a location on a schedule," wrote Hopkins, who is now CEO at Bakken Midstream. "Relative newcomer [Axiom Exergy] came to market with their #refrigeration #battery. Good concept but not plug and play. Not surprising, they seem to have recast themselves as a #cloud based power management company."

• Speaking of CALMAC: CEO Mark McCracken will speak on "some of the myths surrounding ice-based TES" at an ASHRAE technical seminar on thermal energy storage in building design in Hong Kong June 13. 

FedEx Express has launched a temperature-controlled shipping solution in Japan, Korea and Singapore. The company says its Medpak VIºC packaging, first introduced in Europe, provides 96-hour temperature stability. The reusable thermal packaging features vacuum insulated panels and phase change material validated to International Safe Transit Association 7D standards.

CIC energiGUNE, a research center in Spain's Basque Country, has an opening for a researcher in its thermal energy storage area. The research will focus on the storage of heat through reversible chemical reactions "in a range of temperature few explored so far (120 - 250 °C)." The application deadline is Sept. 11, 2019.   

Barbara Pause of Textile Testing & Innovation will be among the speakers at this year's Advances in Thermal Management conference, to be held Aug. 7-8 in Denver, Colo. Her topic: "Measuring and Modeling the Thermal Performance of Products Equipped with Phase Change Materials." 

• Thermal energy storage startup NET Energy of Chicago is among 10 finalists for the University of Chicago’s 19th annual Edward L. Kaplan New Venture Challenge. Winners will be announced next week, with the top companies sharing $250,000 in cash, along with $250,000 worth of office space and professional services from program sponsors. 

Research roundup: Night ventilation study; residential ice storage; fly ash and slag cement slurry; more

Ben Welter - Friday, May 24, 2019

From Building and Environment:

A parametric study of phase change material behaviour when used with night ventilation in different climatic zones

From Energy and Buildings:

Development and Evaluation of a Generalized Rule-Based Control Strategy for Residential Ice Storage Systems
Characterization of potassium carbonate salt hydrate for thermochemical energy storage in buildings

From International Journal of Energy Research:

Fly ash and slag cement slurry containing microencapsulated phase change materials

From Applied Energy:

Thermal response of annuli filled with metal foam for thermal energy storage: An experimental study
A scalable environmental thermal energy harvester based on solid/liquid phase-change materials

From International Journal of Hydrogen Energy:

Thermal management of metal hydride hydrogen storage reservoir using phase change materials

From Macromolecular Research:

Multiple Energy Harvesting Based on Reversed Temperature Difference Between Graphene Aerogel Filled Phase Change Materials

From Solar Energy:

Experimental studies on the effect of using phase change material in a salinity-gradient solar pond under a solar simulator

From Chemical Engineering Journal:

Thermal enhancement and shape stabilization of a phase-change energy-storage material via copper nanowire aerogel

From U.S. Office of Scientific and Technical Information:

Prototype Testing of Encapsulated Phase Change Material Thermal Energy Storage (EPCM-TES) for Concentrated Solar Power

From E3S Web of Conferences:

A PCM based cooling system for office buildings: a state of the art review

From Solar Energy Materials and Solar Cells:

Design of MtNS/SA microencapsulated phase change materials for enhancement of thermal energy storage performances: Effect of shell thickness

From Journal of Molecular Liquids:

Investigating the effects of hybrid nanoparticles on solid-liquid phase change process in a Y-shaped fin-assisted LHTESS by means of FEM

From Renewable and Sustainable Energy Reviews:

A review of microencapsulated and composite phase change materials: Alteration of strength and thermal properties of cement-based materials

Research roundup: High-conductivity nanomaterials; paper board packaging; battery thermal management; more

Ben Welter - Thursday, May 16, 2019

From Heat and Mass Transfer:

Experimental and numerical analysis of composite latent heat storage in cooling systems for power electronics

From Journal of Sol-Gel Science and Technology:

A robust, flexible superhydrophobic sheet fabricated by in situ growth of micro-nano-SiO2 particles from cured silicone rubber

From Journal of Thermal Analysis and Calorimetry:

High-conductivity nanomaterials for enhancing thermal performance of latent heat thermal energy storage systems

From Building Simulation:

Optimization and sensitivity analysis of design parameters for a ventilation system using phase change materials

From Journal of Packaging Technology and Research:

Thermal Analysis of Paper Board Packaging with Phase Change Material: A Numerical Study

From Energy Storage:

Thermal performance of battery thermal management system using composite matrix coupled with mini‐channel

From Phase Transitions:

A study on preparation and properties of carbon materials/myristic acid composite phase change thermal energy storage materials

From ACS Applied Materials & Interfaces:

Melamine Foam Supported Form-stable Phase Change Materials with Simultaneous Thermal Energy Storage and Shape Memory Property for Thermal Management of Electronic Devices

From International Conference on Thermal Engineering:

Performance Enhancement of Unitary and Packaged Air Conditioners With Phase Change Material
Performance Comparison of Different Phase Change Materials For Solar Cooking During off Sun Sunshine Hours
A Review on Enhancement of Thermophysical Properties of Paraffin Wax PCM With Nanomaterials
Nano-Enhanced PCMs for Low Temperature Thermal Energy Storage Systems and Passive Conditioning Applications

From Chemistry Select:

Designing Coconut Oil Encapsulated Poly(stearyl methacrylate‐co‐hydroxylethyl metacrylate) Based Microcapsule for Phase Change Materials

From Evolution in Polymer Technology Journal:

Enhancement of Thermo-Regulating Textile Materials Using Phase Change Material

From Materials Research Express:

Improved thermal characteristics of Ag nanoparticles dispersed myristic acid as composite for low temperature thermal energy storage

From Applied Energy:

On the performance of ground coupled seasonal thermal energy storage for heating and cooling: A Canadian context

From Solar Energy Materials and Solar Cells:

Thermal stability enhancement of d-mannitol for latent heat storage applications

Patent application: High-density latent heat storage device

Ben Welter - Friday, May 10, 2019

University of Texas patent drawing

U.S. patent application 20190137190 (applicant Board of Regents, University of Texas System, Austin, Texas):

"Latent heat storage devices are disclosed, such as latent heat storage devices comprising a phase change material encapsulated in sufficiently conductive tubes, wherein the tubes are arrayed in a hexagonal-packed pattern. The devices herein can be used, for example, in residential and/or commercial HVAC systems."

PCM briefing: Cold chain veteran joins Phase Change Energy Solutions; Outlast showcases new nylon filament yarn

Ben Welter - Friday, May 10, 2019

Bruce TruesdaleBruce Truesdale has joined Phase Change Energy Solutions of Asheboro, N.C., as director of business development - cold chain. He was formerly senior supply chain consultant at Verta Life Sciences and director of health care at Protek Pharma Worldwide. He declined an interview request, but his new job title suggests that PCES, whose product line now focuses on HVAC, building and thermal energy storage, has an interest in the temperature-controlled packaging market. Earlier this year, PCES announced an investment by Pegasus Capital Advisors, Emerald Technology Ventures and Third Prime, an early-stage venture fund and prior investor. The company said it would use the proceeds to fund the continued development of its thermal storage products and expand its operations globally.

Chalmers University of Technology of Sweden has an opening for a postdoctoral researcher in thermal energy storage for building applications. The research group Building Physics is working "to find out how novel TES with phase change materials (PCM) could complement the existing district heating and cooling networks and co-operate with other peak shaving techniques (water accumulator tanks, ground heat storage pumps, etc.) through smart thermal grids." The application deadline is June 9.

Outlast will showcase its new nylon filament yarn at the Techtextil trade show in Frankfurt, Germany, next week. "The PCMs optimized for this specific application," Outlast says, "are included directly inside the polyamide fibers." Potential applications include next-to-skin products such as undergarments, shapewear, sportswear and hosiery. The company says it now sources the majority of PCMs used in its products from renewable instead of synthetic raw materials.

PCM coolerA PCM coating designed to absorb heat from rockets is among the dozens of NASA spinoffs listed in the latest issue of Spinoff, an annual publication that has been documenting space agency spinoffs since 1976. In the early 2000s, Raj Kaul, a materials scientist at Marshall Space Flight Center, began researching a way to use PCM to keep the outside of spacecraft at a safe temperature. An entrepreneur eventually snapped up the patent for the coating Kaul developed and is working on a number of products based on the technology, including aircraft paint, pipe heat traps and an iceless cooler, shown at right. 

• The U.S. Department of Energy this week announced $89 million in funding for "innovative, advanced manufacturing research and development projects." "Innovations for the Manufacture of Advanced Materials," one of three areas to receive funding, includes phase change storage materials for heating and cooling applications. The department anticipates making up to 55 awards for up to three years. Concept papers are due on June 20.