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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Patent application: Battery pack containing phase change material

Ben Welter - Thursday, February 14, 2019

U.S. patent application 20190051955 (applicant Consortium de Recherche BRP / Universite de Sherbrooke, Canada):

"A battery pack for a vehicle is presented. The battery pack comprises a plurality of bricks, each brick of the plurality of bricks comprising a phase change material block, a side of the phase change material block defining a plurality of channels, and a plurality of battery cells, each battery cell being disposed at least in part in the phase change material block; and at least one connector for electrically connecting a first one of the plurality of bricks to a second one of the plurality of bricks, the at least one connector being disposed at least partially in one of the plurality of channels."

http://www.freepatentsonline.com/20190051955.pdf

Research roundup: Self-luminous wood composite; palmitic acid/mullite composite; corrosion sensitivity of metal alloys; more

Ben Welter - Tuesday, February 12, 2019

From Energy Storage Materials:

Self-luminous wood composite for both thermal and light energy storage

From International Journal of Refrigeration:

The thermal performances of a refrigerator incorporating a Phase Change Material

From Renewable Energy:

Enhanced thermal conductivity of palmitic acid/mullite phase change composite with graphite powder for thermal energy storage
An experimental study on the corrosion sensitivity of metal alloys for usage in PCM thermal energy storages

From Energy Conversion and Management:

Sorption thermal energy storage: Hybrid coating/granules adsorber design and hybrid TCM/PCM operation
Novel hybrid microencapsulated phase change materials incorporated wallboard for year-long year energy storage in buildings

From Thermochimica Acta:

Experimental Investigation on Thermal Properties of Sodium Acetate Trihydrate based Phase Change Materials for Thermal Energy Storage
The preparation of AgI/Au/foam-Cu as a framework of composite for water-based cool storage phase-change material with low supercooling

From Energy and Buildings:

Nano-encapsulation of phase change materials: from design to thermal performance, simulations and toxicological assessment
Investigation of phase change materials integrated with fin-tube baseboard convector for space heating

From Journal of Energy Storage:

Nano-enhancement of phase change material in a shell and multi-PCM-tube heat exchanger

From Applied Energy:

Numerical investigation of phase change material thermal storage for space cooling

From Journal of Materials Chemistry A:

Vertically aligned carbon fibers as supporting scaffolds for phase change composites with anisotropic thermal-conductivity and good shape-stability

Research roundup: Thermal conductivity; decarbonization potential of compact heat storage; liquid desiccant cooling systems; more

Ben Welter - Wednesday, February 06, 2019

From Energy:

Effects of thermal conductivity and density on phase change materials-based thermal energy storage systems

From Renewable Energy:

Melting process investigation of phase change materials in a shell and tube heat exchanger enhanced with heat pipe

From Applied Thermal Engineering:

Compact latent heat storage decarbonisation potential for domestic hot water and space heating applications in the UK
Numerical and experimental study of phase-change temperature controller containing graded cellular material fabricated by additive manufacturing
A novel composite phase change material with paraffin wax in tailings porous ceramics
Characterisation and evaluation of a new phase change enhanced working solution for liquid desiccant cooling systems
Thermal properties enhancement and application of a novel sodium acetate trihydrate-formamide/expanded graphite shape-stabilized composite phase change material for electric radiant floor heating

From Environmental Research:

Latent heat storage biocomposites of phase change material-biochar as feasible eco-friendly building materials

From Colloids and Surfaces A:

A facile microencapsulation of phase change materials within silicone-based shells by using glass capillary devices

From Microporous and Mesoporous Materials:

Phase change in modified metal organic frameworks MIL-101(Cr): Mechanism on highly improved energy storage performance

From Applied Energy:

Role of porous metal foam on the heat transfer enhancement for a thermal energy storage tube
Energy saving performance assessment and lessons learned from the operation of an active phase change materials system in a multi-storey building in Melbourne

From Building and Environment:

Comparative analysis of the PCM application according to the building type as retrofit system

From Construction and Building Materials:

Evaluation of the potential use of form-stable phase change materials to improve the freeze-thaw resistance of concrete

From Results in Physics:

Application Research of Nano-storage Materials in Cold Chain Logistics of E-commerce Fresh Agricultural Products

From Journal of Energy Storage:

Using PCM as energy storage material in water tanks: Theoretical and experimental investigation

Research roundup: Micro environmental control system; alkali nitrate salts; sodium thiosulfate pentahydrate; more

Ben Welter - Tuesday, January 22, 2019

From Journal of Thermal Science and Engineering :

Phase Change Material Freezing in an Energy Storage Module for a Micro Environmental Control System
Phase Change Material Melting in an Energy Storage Module for a Micro Environmental Control System

From Renewable Energy:

Form-stable oxalic acid dihydrate/glycolic acid-based composite PCMs for thermal energy storage
Molecular simulation of the structure and physical properties of alkali nitrate salts for thermal energy storage

From Applied Energy:

Effect of inclination on the thermal response of composite phase change materials for thermal energy storage

From Solar Energy Materials and Solar Cells:

Characterization and thermal performance of microencapsulated sodium thiosulfate pentahydrate as phase change material for thermal energy storage
Fabrication and applications of dual-responsive microencapsulated phase change material with enhanced solar energy-storage and solar photocatalytic effectiveness

From Energy:

Numerical investigations of optimal phase change material incorporated into ventilated walls

From Polymer Degradation and Stability:

EG-based coatings for flame retardance of shape stabilized phase change materials

From Construction and Building Materials:

Freeze-thaw performance of phase change material (PCM) incorporated pavement subgrade soil

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Patent application: Radiative cooling with solar spectrum reflection

Ben Welter - Tuesday, January 22, 2019

U.S. patent application 20190017758 (applicant Board of Trustees of Stanford University, Stanford, Calif.):

"Aspects of the present disclosure are directed toward radiative cooling with solar spectrum reflection. In certain more specific embodiments, a structure facilitates far-field radiation at particular wavelengths while blocking radiation at solar wavelengths. Additionally, aspects of the present disclosure allow for twenty-four hour cooling of buildings and similar structures, and for cooling through a heat exchange to other liquid, gases, or solids. ... The heat exchange interface may further interface with phase-change materials either directly or indirectly to allow for thermal storage driven by the radiative properties of the plurality of different materials."

http://www.freepatentsonline.com/20190017758.pdf

Research roundup: Solar storage tank; concentric PCM module; supercooling degree improvement; more

Ben Welter - Monday, January 21, 2019

From Journal of Thermal Science:

Energy Storage Performance of a PCM in the Solar Storage Tank

From International Journal of Applied Engineering Research:

Numerical assessment of suitability of phase-change materials in a concentric PCM-module for thermal storage applications [pdf]

From International Journal of Energy Research:

Experimental measurements and numerical computation of nanofluid and microencapsulated phase change material in porous material

From IOP Conference Series: Materials Science and Engineering:

Nano-enhanced phase change material effects on the supercooling degree improvement: A review

From Renewable Energy:

Potential of ventilation systems with thermal energy storage using PCMs applied to air conditioned buildings

From Journal of Mechanical Engineering and Technology:

Thermal performance analysis of nano enhanced paraffin wax and myristic acid

From Solar Energy:

Synthesis and characterization of microencapsulated phase change materials with comb-like acrylic co-polymer shell as thermal energy storage materials
Sensible and latent heat energy storage systems for concentrated solar power plants, exergy efficiency comparison

From Solar Energy Materials and Solar Cells:

Thermal energy storage characteristics of myristic acid-palmitic eutectic mixtures encapsulated in PMMA shell

From Thermal Science and Engineering Progress:

Parametric analysis and optimization of an underfloor solar assisted heating system with phase change materials

From International Journal of Heat and Mass Transfer:

The improved enthalpy-transforming based lattice Boltzmann model for solid-liquid phase change

From Applied Energy:

Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell

From AIP Conference Proceedings:

Preparation and characterization of nanoparticle blended polymers for thermal energy storage applications

PCM with enhanced thermal properties developed for rail/truck container

Ben Welter - Saturday, January 12, 2019

Professor Yulong DingYulong Ding, the University of Birmingham professor who directed the development of a rail/truck shipping container designed to keep perishables cold without a power supply, says his team developed an organic phase change material with enhanced thermal properties for the project. The PCM is designed to keep the temperature inside the container between 5 and 12˚ C for up to 120 hours. Ding, director of the university's Center for Energy Storage, provided additional detail on the project in an interview this week.

Q: Describe your organization's role in the project.

A: It was funded by CRRC Shijiazhuang, a Chinese railway equipment manufacturer, and the project was collaborative. Our work at Birmingham included PCM materials development and fabrication, cold storage device design and testing, cold charging method and design. Work began in October 2017.

Q: What role did CRRC Shijiazhuang play?

A: CRRC was the project sponsor. Their work included manufacture and test of the device and cold charge device, installation of cold storage devices into large container, data-logging and IT, real application demonstration and testing (35,000 km combined road and railway testing across a wide climate zones).

Q: Can you briefly describe the testing methods and results?

A: I believe two standard containers were used, goods include all sorts of vegetables, flowers and fruits. Energy saving data have not been processed for the real tests but we do have testing data from labs, which is around 20 percent.

Q: Describe the PCM used in the application.

A: We used organic based PCM reformulated for enhanced thermal properties. Melting temperatures can be turned between -4 and 4 degree C, and the thermal storage capacity is >~200 kJ/kg.

Q: How big are the rail containers, typically, and how much PCM is used in each container?

A: We used the standard container for road transportation, which can be used for rail use. I prefer not to say the amount of PCM used, which may need approval from our sponsor.

Q: How is the PCM charged, and how long does it take to charge the PCM in a typical container?

A: We have a mobile charge device. The charging time is relatively short. The details will need our sponsor to approve before I can tell.

Q: In what material is the PCM contained (HDPE, film, metal)?

A: We used composite PCM contained in PCM storage device.

Q: How is the PCM deployed in the rail containers?

A: The PCM devices are installed inside the container.

Q: Does CRRC plan to manufacture the rail containers?

A: I doubt they would make the container.

https://www.birmingham.ac.uk/news/latest/2018/12/scientists-develop-world-first-cold-storage-roadrail-container.aspx

Microtek sponsors Spanish entry in Solar Decathlon Europe 2019

Ben Welter - Saturday, January 12, 2019

A team representing the Polytechnic University of Valencia, Spain, plans to use phase change material in the energy-efficient home it is building for Solar Decathlon Europe 2019. Azalea, one of 16 teams selected for the competition, is made up of 30 students and professionals representing fields such as architecture and engineering. 

Microtek Laboratories of Dayton, Ohio, is providing Azalea with technical and financial support.

Tim Riazzi"We are proud to be a sponsor of the Polytechnic team and the Azalea Project," said Tim Riazzi, Microtek president. "As a company who practices and is concerned with environmental stewardship, we are excited about their efforts to create a sustainable ecological dwelling that will reduce our impact on the environment and reduce our energy consumption." 

Riazzi said Microtek provided Azalea with Micronal 28D (formerly Micronal 5528X).

"Instead of providing them with a final product," Riazzi said, "we have worked with the team and decided that it would be better to provide them our dried Micronal product so that they could use it in the specific areas that they needed. We can say that they are incorporating it into a variety of elements/components of their wall and floor design, but they have asked us not to divulge the exact use of it because the competition is active. ... We can say that we have provide them over 200 kg of material."

https://www.microteklabs.com/blog/azalea-project-solar-decathlon-europe

Research roundup: Hydrophobic lauric acid; paraffin in heat exchanger; EnergyPlus vs. IES; more

Ben Welter - Thursday, January 10, 2019

From Journal of Energy Storage:

Preparation of hydrophobic lauric acid/SiO2 shape-stabilized phase change materials for thermal energy storage

From Applied Thermal Engineering:

Development of paraffin wax as phase change material based latent heat storage in heat exchanger

From Renewable Energy:

Characterization and stability study of a form-stable erythritol/expanded graphite composite phase change material for thermal energy storage

From Journal of Building Engineering:

Comparison of EnergyPlus and IES to model a complex university building using three scenarios: Free-floating, ideal air load system, and detailed

From 4th International Conference on Renewable Energies for Developing Countries :

Phase Change Materials in a Domestic Solar Hot Water Storage Tank of the Lebanese Market
Numerical and experimental investigations of a PCM integrated solar chimney
Integrating a High Solar Combi-Plus System using PCM Storage in a Smart Network: KSA Case Study

From International Journal of Advanced Research In Applied Sciences, Engineering and Technology:

Solar Cooker with Heat Storage System: A Review [pdf]

From Energy and Buildings:


From Solar Energy Materials and Solar Cells:

Bio-based poly (lactic acid)/high-density polyethylene blends as shape-stabilized phase change material for thermal energy storage applications

From Construction and Building Materials:

Microstructure-guided numerical simulation to evaluate the influence of phase change materials (PCMs) on the freeze-thaw response of concrete pavements

From Energy Conversion and Management:

Thermal management of Li-ion battery pack with the application of flexible form-stable composite phase change materials
Experimental investigation on cylindrically macro-encapsulated latent heat storage for space heating applications

From International Communications in Heat and Mass Transfer:

Experimental investigation on using a novel phase change material (PCM) in micro structure photovoltaic cooling system
Experimental investigation on a novel composite heat pipe with phase change materials coated on the adiabatic section

From Journal of Cleaner Production:

PCM briefing: Sunamp among 'Scottish tech companies to watch' in 2019; C-Therm webinar on new thermal conductivity instrument

Ben Welter - Monday, January 07, 2019

Rail shipping container with PCM

• The University of Birmingham's Center for Energy Storage has teamed up with a Chinese railway equipment manufacturer to develop a shipping container that uses phase change materials to maintain a low temperature over several days without a power supply. "Once ‘charged’, PCM inside the container - which can be transferred from train to truck and vice versa - can keep the inside temperature between 5-12 ˚C for up to 120 hours," the university reports.

CNET's Scott Stein takes a close look at PowerStation, "a battery of sorts that can keep a low-power sensor running off the temperature differences in everyday weather conditions." The device, made by Matrix Industries of Menlo Park, Calif., stores heat in a substance the company calls "Luna Phase Change Material" and later releases the heat in the form of electricity.

Scottish Business Insider has named Sunamp Ltd. one of five Scottish tech companies to watch in 2019. "The £2.2m raised in its latest fundraising sets the company up for a Series A round in 2019 as it looks to expand its international footprint and further scale its operations," Insider writes. "Sunamp heat batteries have so far been installed in over a thousand homes across the UK." 

C-Therm managing director Adam Harris is hosting a webinar this week to introduce the company's new thermal conductivity instrument, the C-Therm Trident. Advance registration is required for the webinar, which will be held at 1 p.m. EST Thursday, Jan. 10.

• At a business summit in Wisconsin last month, Encapsys President Mary Goggans said the Appleton-based company offers internships to students at regional colleges, including the children of employees. “The interns see the jobs and technologies they are interested in right here in the area,” Goggans said. “They realize they don’t need to get a job outside of the region to have the career they are looking for.”