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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Micro environmental control system; alkali nitrate salts; sodium thiosulfate pentahydrate; more

Ben Welter - Tuesday, January 22, 2019

From Journal of Thermal Science and Engineering :

Phase Change Material Freezing in an Energy Storage Module for a Micro Environmental Control System
Phase Change Material Melting in an Energy Storage Module for a Micro Environmental Control System

From Renewable Energy:

Form-stable oxalic acid dihydrate/glycolic acid-based composite PCMs for thermal energy storage
Molecular simulation of the structure and physical properties of alkali nitrate salts for thermal energy storage

From Applied Energy:

Effect of inclination on the thermal response of composite phase change materials for thermal energy storage

From Solar Energy Materials and Solar Cells:

Characterization and thermal performance of microencapsulated sodium thiosulfate pentahydrate as phase change material for thermal energy storage
Fabrication and applications of dual-responsive microencapsulated phase change material with enhanced solar energy-storage and solar photocatalytic effectiveness

From Energy:

Numerical investigations of optimal phase change material incorporated into ventilated walls

From Polymer Degradation and Stability:

EG-based coatings for flame retardance of shape stabilized phase change materials

From Construction and Building Materials:

Freeze-thaw performance of phase change material (PCM) incorporated pavement subgrade soil

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Patent application: Radiative cooling with solar spectrum reflection

Ben Welter - Tuesday, January 22, 2019

U.S. patent application 20190017758 (applicant Board of Trustees of Stanford University, Stanford, Calif.):

"Aspects of the present disclosure are directed toward radiative cooling with solar spectrum reflection. In certain more specific embodiments, a structure facilitates far-field radiation at particular wavelengths while blocking radiation at solar wavelengths. Additionally, aspects of the present disclosure allow for twenty-four hour cooling of buildings and similar structures, and for cooling through a heat exchange to other liquid, gases, or solids. ... The heat exchange interface may further interface with phase-change materials either directly or indirectly to allow for thermal storage driven by the radiative properties of the plurality of different materials."

http://www.freepatentsonline.com/20190017758.pdf

Research roundup: Solar storage tank; concentric PCM module; supercooling degree improvement; more

Ben Welter - Monday, January 21, 2019

From Journal of Thermal Science:

Energy Storage Performance of a PCM in the Solar Storage Tank

From International Journal of Applied Engineering Research:

Numerical assessment of suitability of phase-change materials in a concentric PCM-module for thermal storage applications [pdf]

From International Journal of Energy Research:

Experimental measurements and numerical computation of nanofluid and microencapsulated phase change material in porous material

From IOP Conference Series: Materials Science and Engineering:

Nano-enhanced phase change material effects on the supercooling degree improvement: A review

From Renewable Energy:

Potential of ventilation systems with thermal energy storage using PCMs applied to air conditioned buildings

From Journal of Mechanical Engineering and Technology:

Thermal performance analysis of nano enhanced paraffin wax and myristic acid

From Solar Energy:

Synthesis and characterization of microencapsulated phase change materials with comb-like acrylic co-polymer shell as thermal energy storage materials
Sensible and latent heat energy storage systems for concentrated solar power plants, exergy efficiency comparison

From Solar Energy Materials and Solar Cells:

Thermal energy storage characteristics of myristic acid-palmitic eutectic mixtures encapsulated in PMMA shell

From Thermal Science and Engineering Progress:

Parametric analysis and optimization of an underfloor solar assisted heating system with phase change materials

From International Journal of Heat and Mass Transfer:

The improved enthalpy-transforming based lattice Boltzmann model for solid-liquid phase change

From Applied Energy:

Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell

From AIP Conference Proceedings:

Preparation and characterization of nanoparticle blended polymers for thermal energy storage applications

PCM with enhanced thermal properties developed for rail/truck container

Ben Welter - Saturday, January 12, 2019

Professor Yulong DingYulong Ding, the University of Birmingham professor who directed the development of a rail/truck shipping container designed to keep perishables cold without a power supply, says his team developed an organic phase change material with enhanced thermal properties for the project. The PCM is designed to keep the temperature inside the container between 5 and 12˚ C for up to 120 hours. Ding, director of the university's Center for Energy Storage, provided additional detail on the project in an interview this week.

Q: Describe your organization's role in the project.

A: It was funded by CRRC Shijiazhuang, a Chinese railway equipment manufacturer, and the project was collaborative. Our work at Birmingham included PCM materials development and fabrication, cold storage device design and testing, cold charging method and design. Work began in October 2017.

Q: What role did CRRC Shijiazhuang play?

A: CRRC was the project sponsor. Their work included manufacture and test of the device and cold charge device, installation of cold storage devices into large container, data-logging and IT, real application demonstration and testing (35,000 km combined road and railway testing across a wide climate zones).

Q: Can you briefly describe the testing methods and results?

A: I believe two standard containers were used, goods include all sorts of vegetables, flowers and fruits. Energy saving data have not been processed for the real tests but we do have testing data from labs, which is around 20 percent.

Q: Describe the PCM used in the application.

A: We used organic based PCM reformulated for enhanced thermal properties. Melting temperatures can be turned between -4 and 4 degree C, and the thermal storage capacity is >~200 kJ/kg.

Q: How big are the rail containers, typically, and how much PCM is used in each container?

A: We used the standard container for road transportation, which can be used for rail use. I prefer not to say the amount of PCM used, which may need approval from our sponsor.

Q: How is the PCM charged, and how long does it take to charge the PCM in a typical container?

A: We have a mobile charge device. The charging time is relatively short. The details will need our sponsor to approve before I can tell.

Q: In what material is the PCM contained (HDPE, film, metal)?

A: We used composite PCM contained in PCM storage device.

Q: How is the PCM deployed in the rail containers?

A: The PCM devices are installed inside the container.

Q: Does CRRC plan to manufacture the rail containers?

A: I doubt they would make the container.

https://www.birmingham.ac.uk/news/latest/2018/12/scientists-develop-world-first-cold-storage-roadrail-container.aspx

Microtek sponsors Spanish entry in Solar Decathlon Europe 2019

Ben Welter - Saturday, January 12, 2019

A team representing the Polytechnic University of Valencia, Spain, plans to use phase change material in the energy-efficient home it is building for Solar Decathlon Europe 2019. Azalea, one of 16 teams selected for the competition, is made up of 30 students and professionals representing fields such as architecture and engineering. 

Microtek Laboratories of Dayton, Ohio, is providing Azalea with technical and financial support.

Tim Riazzi"We are proud to be a sponsor of the Polytechnic team and the Azalea Project," said Tim Riazzi, Microtek president. "As a company who practices and is concerned with environmental stewardship, we are excited about their efforts to create a sustainable ecological dwelling that will reduce our impact on the environment and reduce our energy consumption." 

Riazzi said Microtek provided Azalea with Micronal 28D (formerly Micronal 5528X).

"Instead of providing them with a final product," Riazzi said, "we have worked with the team and decided that it would be better to provide them our dried Micronal product so that they could use it in the specific areas that they needed. We can say that they are incorporating it into a variety of elements/components of their wall and floor design, but they have asked us not to divulge the exact use of it because the competition is active. ... We can say that we have provide them over 200 kg of material."

https://www.microteklabs.com/blog/azalea-project-solar-decathlon-europe

Research roundup: Hydrophobic lauric acid; paraffin in heat exchanger; EnergyPlus vs. IES; more

Ben Welter - Thursday, January 10, 2019

From Journal of Energy Storage:

Preparation of hydrophobic lauric acid/SiO2 shape-stabilized phase change materials for thermal energy storage

From Applied Thermal Engineering:

Development of paraffin wax as phase change material based latent heat storage in heat exchanger

From Renewable Energy:

Characterization and stability study of a form-stable erythritol/expanded graphite composite phase change material for thermal energy storage

From Journal of Building Engineering:

Comparison of EnergyPlus and IES to model a complex university building using three scenarios: Free-floating, ideal air load system, and detailed

From 4th International Conference on Renewable Energies for Developing Countries :

Phase Change Materials in a Domestic Solar Hot Water Storage Tank of the Lebanese Market
Numerical and experimental investigations of a PCM integrated solar chimney
Integrating a High Solar Combi-Plus System using PCM Storage in a Smart Network: KSA Case Study

From International Journal of Advanced Research In Applied Sciences, Engineering and Technology:

Solar Cooker with Heat Storage System: A Review [pdf]

From Energy and Buildings:


From Solar Energy Materials and Solar Cells:

Bio-based poly (lactic acid)/high-density polyethylene blends as shape-stabilized phase change material for thermal energy storage applications

From Construction and Building Materials:

Microstructure-guided numerical simulation to evaluate the influence of phase change materials (PCMs) on the freeze-thaw response of concrete pavements

From Energy Conversion and Management:

Thermal management of Li-ion battery pack with the application of flexible form-stable composite phase change materials
Experimental investigation on cylindrically macro-encapsulated latent heat storage for space heating applications

From International Communications in Heat and Mass Transfer:

Experimental investigation on using a novel phase change material (PCM) in micro structure photovoltaic cooling system
Experimental investigation on a novel composite heat pipe with phase change materials coated on the adiabatic section

From Journal of Cleaner Production:

PCM briefing: Sunamp among 'Scottish tech companies to watch' in 2019; C-Therm webinar on new thermal conductivity instrument

Ben Welter - Monday, January 07, 2019

Rail shipping container with PCM

• The University of Birmingham's Center for Energy Storage has teamed up with a Chinese railway equipment manufacturer to develop a shipping container that uses phase change materials to maintain a low temperature over several days without a power supply. "Once ‘charged’, PCM inside the container - which can be transferred from train to truck and vice versa - can keep the inside temperature between 5-12 ˚C for up to 120 hours," the university reports.

CNET's Scott Stein takes a close look at PowerStation, "a battery of sorts that can keep a low-power sensor running off the temperature differences in everyday weather conditions." The device, made by Matrix Industries of Menlo Park, Calif., stores heat in a substance the company calls "Luna Phase Change Material" and later releases the heat in the form of electricity.

Scottish Business Insider has named Sunamp Ltd. one of five Scottish tech companies to watch in 2019. "The £2.2m raised in its latest fundraising sets the company up for a Series A round in 2019 as it looks to expand its international footprint and further scale its operations," Insider writes. "Sunamp heat batteries have so far been installed in over a thousand homes across the UK." 

C-Therm managing director Adam Harris is hosting a webinar this week to introduce the company's new thermal conductivity instrument, the C-Therm Trident. Advance registration is required for the webinar, which will be held at 1 p.m. EST Thursday, Jan. 10.

• At a business summit in Wisconsin last month, Encapsys President Mary Goggans said the Appleton-based company offers internships to students at regional colleges, including the children of employees. “The interns see the jobs and technologies they are interested in right here in the area,” Goggans said. “They realize they don’t need to get a job outside of the region to have the career they are looking for.”

Research roundup: Thermally modulated fiber sorbents; metamaterial-based radiative cooling; stearic–capric acid/porous nanoceramics; more

Ben Welter - Friday, January 04, 2019

From Industrial & Engineering Chemistry Research:

Development of Phase-Change-Based Thermally Modulated Fiber Sorbents

From ChemistrySelect:

Preparation and Thermal Properties of 1‐Hexadecanol‐Palmitic Acid Eutectic Mixture/Activated Carbon Composite Phase Change Material for Thermal Energy Storage

From Energies:

Thermal Conductivity Enhancement of Phase Change Materials for Low-Temperature Thermal Energy Storage Applications [pdf]
Metamaterial-Based Radiative Cooling: Towards Energy-Free All-Day Cooling [pdf]

From Renewable and Sustainable Energy Reviews:

A review and evaluation of thermal insulation materials and methods for thermal energy storage systems

From Materials Letters:

Stearic–capric acid/porous nanoceramics as a novel form-stable composite phase change material (FSPCM) for thermal energy storage

From International Refrigeration and Air Conditioning Conference:

Analysis of TES with PCM (Solid/Liquid) Integrated in a Residential System
Experimental Study on Portable Air-Conditioning System with Enhanced PCM Condenser

Research roundup: Solidification/subcooling in spherical capsule; cement-based thermal storage; heat transfer in flexible container; more

Ben Welter - Friday, December 21, 2018

From International Journal of Refrigeration:

Experimental studies on solidification and subcooling characteristics of water-based phase change material (PCM) in a spherical encapsulation for cool thermal energy storage applications

From Construction and Building Materials:

Thermal energy storage characterization of cement-based systems containing microencapsulated-PCMs

From Renewable and Sustainable Energy Reviews:

Seasonal thermal energy storage system for cold climate zones: A review of recent developments

From Heat and Mass Transfer:

Analysis of heat transfer in latent heat thermal energy storage using a flexible PCM container

From Energy Conversion and Management:

Plate type heat exchanger for thermal energy storage and load shifting using phase change material

From Applied Thermal Engineering:

Experimental studies on the charging performance of single-tank single-medium thermal energy storage
Investigation of thermal energy storage properties of a microencapsulated phase change material using response surface experimental design methodology
Financial and energetic evaluation of solar-assisted heat pump underfloor heating systems with phase change materials

From IOP Conference Series: Materials Science and Engineering:

Thermal Performance Through the Use of Radiant Barrier and Phase Change Material in Concrete Flat Roofs

From Solar Energy Materials and Solar Cells:

Synthesis of novel form-stable composite phase change materials with modified graphene aerogel for solar energy conversion and storage

From International Journal of Heat and Mass Transfer:

Development of vacuum impregnation equipment and preparation of mass/uniform shape-stabilized phase change materials

PCM briefing: McGill joins Phase Change Energy Solutions as CEO; Croda is No. 3 on Britain's Most Admired Companies list

Ben Welter - Friday, December 21, 2018

Dennis McGillDennis McGill, operations advisor at Pegasus Capital Advisors, has joined Phase Change Energy Solutions as chief executive officer and chairman of the board. McGill, right, has more than 30 years of experience in senior financial and executive leadership roles. For the past three years, he has been the CEO and chairman of the board for ReCommunity Recycling of Charlotte, N.C. 

Malta Inc., a spinoff of Alphabet’s Moonshot Factory, has raised $26 million in Series A funding. The Massachusetts company is developing an electro-thermal energy storage system that stores energy in the form of the thermal differential between hot and cold storage media. 

Croda International, maker of phase change materials and other specialty chemicals, is No. 3 on Management Today's list of Britain's Most Admired Companies 2018. Diageo and McDonald's took the top two spots.

• From Andrew Chang, regional operations director at Ice Energy, on LinkedIn: "Today was a major milestone for Ice Energy. We commissioned our 100th Ice Bear in the SCE LCR program in #OrangeCounty! We are currently offsetting about 1.5MW for 4 hours every day in Orange County."

MIT researchers have developed a way to use light to trigger the storage and release of waste heat from car engines and other sources. "Once melted and activated by ultraviolet light, the [phase change] material stores the absorbed heat until a beam of visible light triggers solidification and heat release," Phys.org reports. "Key to that control are added molecules that respond to light by changing shape from one that impedes solidification to one that permits it."

Nebu Block T10• Via LinkedIn: "It might not look like it, but this is how VIPs help to store energy. Vacuum insulated panels, that is. ZAE Bayern cooperates with va-Q-tec, Nebuma GmbH, Verallia, and Lungmuß Feuerfest to make industrial high-temperature energy storages more efficient and less hard to find." Nebuma's 20-foot mobile container, shown at right, is designed to store about 16 MWh of heat at a temperature of 1,000 degrees Celsius.

Dr. Yixiang Gan of the University of Sydney is among 11 researchers to win fellowships from the Australia-India Strategic Research Fund for 2019. His focus: "Optimizing thermal energy storage with phase change materials: with applications to solar energy storage in Australia and India." 

• Registration is open for the 44th Stanford Geothermal Workshop, to be held Feb. 11-13 at Stanford University in California.

• Registration is open for Energy Storage Europe, "the leading international trade fair for energy storage," to be held March 12-14 in Dusseldorf, Germany. 

• The 14th Conference on Advanced Building Skins, to be held Oct. 28-29, 2019, in Bern, Switzerland, has issued a call for papers. The deadline for submissions is June 1. Registration for the conference is expected to open once the program is published in April. 

Pelican BioThermal has appointed Lynaye Reynolds as worldwide director of quality. She joined the company three years ago as the quality manager at its site in Leighton Buzzard in the United Kingdom.

1414 Degrees’ molten silicon biogas energy storage system will be installed at a wastewater treatment plant in South Australia. The $3.2 million (AUS) pilot project is a joint effort of 1414 Degrees and SA Water.