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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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PCM briefing: $33M in funding for CSP thermal storage research; Walero undergarment put to the test in race simulator

Ben Welter - Friday, March 29, 2019

• The U.S. Department of Energy has announced $33 million in research funding to advance technologies that work toward achieving the department's 2030 cost target of 5 cents per kilowatt-hour for CSP-generated electricity with at least 12 hours of thermal energy storage. "This research," DOE writes, "includes new materials and technologies that significantly reduce the cost of manufacturing, enable new energy storage technologies, and develop solutions that enable a solar field to operate autonomously without any human input."

Jack MitchellWalero racewear, which uses Outlast phase change technology to regulate temperature in race and rally drivers, has been put to the test on reigning British GT4 champion Jack Mitchell in a temperature-controlled race simulator. The tests were directed by racing performance coach Dean Fouache. On the first day, Mitchell, right, wore standard Nomex underwear; on the second day, he wore Walero underwear. Three measurements were recorded every five minutes during the hourlong tests: body temperature, heart rate and weight loss. In all three areas, Walero showed measurable advantages over the Nomex. "Jack sweated around 40 percent less in the Walero underwear and his average heart rate was eight beats less over the course of the hour," Fouache told Autosport magazine. "So, all in all, relatively conclusive results - even though it is a small comparison test."

• New this month from Central West Publishing in Australia: "Phase Change Materials," edited by Vikas Mittal, an associate professor of chemical engineering at the Petroleum Institute in Abu Dhabi.

• The International Conference on Innovative Applied Energy in the United Kingdom earlier this month featured a number of experiments with phase change materials, including Auburn University's development of micro-encapsulated phase change materials that can be combined with many different media. Other PCM research included a bio-composite made with hemp lime concrete and a novel utilization of fly ash to encapsulate phase change materials.

James Joule• The 200th anniversary of the birth of physicist James Prescott Joule will be commemorated with the unveiling of a plaque in Sale, United Kingdom, in April. The English physicist and mathematician, who gave his name to the unit of energy, was born on Dec. 24, 1818, in Salford. He died in Sale in 1889.

• The deadline for submitting manuscripts for "Phase Change Materials of Buildings," a special issue of the journal Buildings, is Sunday, March 31. Dr. Morshed Alam of Australia's Swinburne University of Technology is the guest editor.

PCM briefing: Sonoco ThermoSafe partners with Cargolux; Axiom Exergy partners with Leap

Ben Welter - Friday, March 22, 2019

Amrit RobbinsAxiom Exergy has announced a partnership with Leap, a technology company that serves as an aggregator of flexible power loads in California. Axiom says the arrangement will unlock grid services revenue for its customers, including three Whole Foods Market facilities in Northern California.

Axiom's "Refrigeration Battery" system is designed to reduce a supermarket's peak power use by up to 40 percent and provide backup cooling during power outages. It uses the excess capacity of existing refrigeration systems to "store cooling" at night by freezing tanks of salt water.  

"Axiom Exergy is excited to announce that Whole Foods has connected three of their buildings to our platform, which will serve as our first Virtual Power Plant," Axiom CEO Amrit Robbins wrote in a LinkedIn post Friday. "Axiom’s platform will intelligently manage 340 kW of dispatchable load across these facilities in order to generate more value for Whole Foods and to help stabilize California’s electricity grid."

Sonoco ThermoSafe has announced a global partnership agreement with Cargolux for the leasing of the PharmaPort 360 temperature-controlled bulk shipping container. The agreement enables pharmaceutical shippers to lease PharmaPort 360 containers directly from the all-cargo airline based in Luxembourg.

• On LinkedIn this week, Ice Energy posted an update on its 5 MW contract with Riverside Public Utilities in California: "We are working to install 9 Ice Bear thermal #energystorage batteries and 13 rooftop units with Inland Mechanical Services Inc. at a car dealership in Riverside."

• A high-temperature thermal energy storage system inaugurated in Denmark this week stores heat in stones. The test system uses surplus wind power to generate hot air, which heats up small stones in an insulated container to 600 degrees. The stored heat is used to generate electricity when the wind doesn't blow. The system was developed by the energy company Seas-NVE, in collaboration with DTU Energy, Aarhus University Geoscience, Danish Energy, Energinet.dk and Rockwool.

Alexium International CEO Bob Brookins was among the presenters at the International Conference on Textile Coating and Laminating in Berlin earlier this month. His topic: "Advanced applications of phase change materials."

• The German Aerospace Center (DLR) is investigating whether Germany’s coal plants can be refitted to serve as thermal energy storage sites. "The research body, which has a track record in concentrated solar power (CSP) development, is planning a pilot that will involve ripping out the boiler from an old coal plant and replacing it with a molten salt thermal storage tank that will be heated using excess renewable energy," Greentech Media reports. "If the concept works, then advocates say it could help safeguard coal generation jobs while giving Germany tens of gigawatts of storage capacity for renewable energy load-shifting on the German grid." DLR says it is preparing a commercial-scale pilot in association with an unnamed German utility.

PCM briefing: Energy Storage Europe includes sessions on thermal storage; C-Therm offers webinar on thermal performance of textiles

Ben Welter - Monday, March 04, 2019

• The Energy Storage Europe conference and trade fair, set for March 12-14 in Dusseldorf, Germany, includes a number of sessions on thermal energy storage: "Heat Storage - an essential contribution to energy transition," Oliver Baudson, TSK Flagsol Engineering GmbH; "Advanced Thermal Energy Storage Concepts," Dr. Robert Pitz-Paal, DLR Institute of Solar Research; "High Temperature Storage," Doron Brenmiller, Brenmiller Energy; "Material and Component Development for Thermal Energy Storage," Christoph Rathgeber, ZAE Bayern; and "Thermal Energy Storage for Cost-Effective Energy Management & CO2 Mitigation," Dr. Dan Bauer, German Aerospace Center - DLR e.V.

• The deadline for submitting paper proposals for next fall's Advanced Building Skins conference in Bern, Switzerland, is March 10. The list of topics includes thermal performance of phase change materials.

• Thermal battery maker Sunamp Ltd.'s collaboration with the University of Edinburgh’s School of Chemistry won the "Powerful Partnership" award at the Scottish Knowledge Exchange Awards 2019 last month. The organizations began work on the development of new phase change materials in 2010. 

• Croda International Plc has been recognized for its commitment to "a deforestation-free supply chain." Croda earned an A- in that category in CDP's climate change report for 2018, up from a B the previous year. The specialty chemical company says it has a special focus on palm oil and is committed to supplying RSPO-certified palm oil derivatives. 

• Thermal instrumentation maker C-Therm Technologies Ltd. is hosting a free webinar this week, "Quantifying Thermal Performance of Textiles (Warm Feel / Cool Touch)." The webinar, aimed at "anyone working in the product performance testing of textiles and fabrics where temperature regulation is an important function," will be held at 1 p.m. EST Wednesday.

Need a PCM coating on that coat? Ohio company has a solution

Ben Welter - Friday, March 01, 2019

Therma-SprayMCMENT Inc., an Ohio company that makes a PCM spray designed for use by consumers, launched a new website last month, teamapini.com, to market the product.

"We have been working on the Team Apini Therma-Spray product for a couple of years to give consumers a way to apply PCM technology to the clothing, bedding or other textile products they may already own," said Monte Magill, the company's senior vice president for PCM technologies. The coating is designed to absorb and release thermal energy to enhance thermal comfort.

"It is a water-based formulation containing microencapsulated PCMs and a heat curable binder material to affix the microPCMs to the various textile substrates," said Magill, who has worked in the PCM industry since the mid-1990s. "We do the final packaging in house but have the microPCMs and the binder formulation contract manufactured."

Therma-Spray-treated socks are also available on the site. The company has been selling Infinite R PCM products for the building and construction industry on its main site, mcmentinc.com, since 2016.

Magill says more retail products are in the pipeline: "Look for Team Apini thermal underwear, henleys, pillow cases and sheeting, a bunzy protector (seat cushion thermal protector for home, auto, camping, stadium, etc.), heating and cooling packs (for work, first responder and dietary applications) as well as an equestrian line we are working on now for both horse and rider (dressage focus)."

PCM briefing: PureTemp joins RSPO; Reda's new PCM fabric on display in Milan

Ben Welter - Monday, February 18, 2019

PureTemp LLC has joined the Roundtable for Sustainable Palm Oil as an associate member. The nonprofit organization, which has more than 4,000 members worldwide, promotes the growth and use of sustainable oil palm products. In November, RSPO adopted stricter standards for certified sustainable palm oil, including a total ban on deforestation by its members.

Reda Group's new Active Phase temperature-control fabric was on display at the Milan fabric trade show earlier this month. The material uses phase change material to keep body temperature constant when ambient temperature fluctuates. Reda says the material features enhanced breathability and softness and is "easy to clean, even in water."

University of Maryland fabric•  University of Maryland researchers have created a temperature-control fabric that does not rely on phase change material. The fabric changes its insulating properties in response to the environment. In warm and humid conditions, the fabric allows radiant heat to pass through. When conditions become cooler and drier, the fabric reduces the heat that escapes. Two types of synthetic materials in the fabric — one that absorbs water and another other that repels it — are coated with carbon nanotubes. The fibers warp and relax in response to changing humidity, opening and closing pores in the fabric. 

• In interviews with Advanced Textiles Source, four entrepreneurs were asked: What do you wish you had known early on when you were first dealing with intellectual property law and patent issues? “Get feedback on why you need a patent,” said Jeremy Wall, founder and CEO of smart-clothing startup Lumenus. “Where else could you spend $20,000?” Said Matt Kolmes, CEO of VOLT Smart Yarns: “Even if you are on a tight budget, file that Provisional application immediately before you show your idea to anyone, or talk about it with anyone."

• The Marie Sklodowska-Curie Action program is seeking applicants for a one- to two-year research fellowship at the Oslo Metropolitan University. The European Union-funded fellowship will focus on the energy-performance aspects of phase change material in buildings. "In this collaboration," OsloMet says, "we intend to gain our understanding and explore about the micro-structural aspect to relate the macro-scale behavior at continuum level." The application deadline is March 7.

PureTemp introduces temperature-control fabric coating

Ben Welter - Wednesday, January 23, 2019

PureTemp LLC has developed a fabric coating engineered to provide an effective buffer against ambient temperature swings in consumer products such as apparel, footwear, bedding, safety, medical, workwear and industrial applications.

Scanning electron microscope image of PureTemp fabric coating Through a proprietary process, PureTemp's biobased phase change material is enclosed in spherical microcapsules and bound to the surface of the fabric. PCMs absorb, store and release thermal energy as they cycle between solid and liquid states. The PCM coating interacts continuously with the unique microclimate of the human body, storing and releasing energy to balance body temperature and increase comfort.

PureTemp honeycomb pattern coatings are available for knit, woven, interlock, circular knits, nonwoven, cotton, polyester and other blends. The photo above shows what PureTemp coated fabric looks like under a scanning electron microscope.

The Minnesota company began producing the world’s first 100 percent biobased PCMs in 2007. PureTemp PCMs, developed in three years of research sponsored by the U.S. Department of Agriculture, are used in a wide variety of temperature-control applications, from cooling vests and warming blankets to shipping containers and coffee mugs.

PureTemp's Dan Keller is directing the business initiative. For more information on PureTemp coated fabrics, contact him via inquiries@puretemp.com or visit https://www.puretemp.com/fabrics.

PCM briefing: New Outlast materials on display at Heimtextil; agenda set for Jan. 24 workshop at Nottingham

Ben Welter - Saturday, January 12, 2019

Outlast recycled polysterNew Outlast products based on recycled materials were on display at the Heimtextil show in Frankfurt, Germany, this week. "In the new Outlast products," the company said, "temperature-regulating technology is applied to base material (knitted fabric or nonwoven) which is produced from 100% recycled polyester textiles or PET bottles and therefore meets the Global Recycle Standard (GRS). Further products that use renewable materials for other components of the technology are planned to expand the portfolio in the near future."

Tempur-Pedic says the latest version of its Breeze mattress line features a new "PureCool+ breathable phase change technology [that] absorbs excess heat and recharges faster to help the sleeper feel cooler when falling asleep."

Eindhoven University of Technology is seeking candidates for a Ph.D. position in nanoporous materials for thermal energy storage

Chemical & Engineering News is seeking candidates for a six-month science-writing editorial fellowship for 2019.

• A proposal to use microencapsulated phase change material to help motor vehicles run smoothly in extreme cold has been honored by Azerbaijan's Ministry of Economy as the best youth startup project of the year. A team of chemical engineering students from Baku Higher Oil School developed the concept.

The agenda has been posted for the Workshop on Energy Efficient Buildings & Thermal Energy Storage Systems to be held Jan. 24 at the University of Nottingham in the United Kingdom. Topics include "Enhanced geothermal borehole heat exchangers with PCMs," "Innovative composite smart materials for heating, cooling and humidity control in buildings" and "Demonstration of the TESSe2b system in three demo sites." The free, all-day workshop is part of the European Union-supported project TESSe2b.

•  From LinkedIn: "Pluss Advanced Technologies Pvt. Ltd. is expanding its vendor development team for its PCM and polymers business. Candidates with prior experience in purchase or vendor management will be preferred, others will be considered too. Want to understand more about the opportunity? Please write to Ruchika Garg at jobs@pluss.co.in."  

• The world's first grid-scale pumped heat energy storage is now in operation at Newcastle University. "The system consists of two containers – a cold store and a hot store – filled with gravel and an inert gas," Utility Week reports. "They are connected via a reversible heat pump/engine. When surplus energy needs to be stored, gas is withdrawn from the cold store and compressed using an electrically-powered pump, thereby raising its temperature. The gas is injected into the hot store where the heat is transferred to the gravel. It is then withdrawn from the hot store, expanded to further lower its temperature and returned to the cold store. To recover the stored energy, the process is reversed."

Dominic Hyde, vice president of Credo on Demand at Pelican BioThermal, said the rental program increased its temperature-controlled container fleet size by 90 and increased revenue by 90 percent in 2018.

Research roundup: Thermally modulated fiber sorbents; metamaterial-based radiative cooling; stearic–capric acid/porous nanoceramics; more

Ben Welter - Friday, January 04, 2019

From Industrial & Engineering Chemistry Research:

Development of Phase-Change-Based Thermally Modulated Fiber Sorbents

From ChemistrySelect:

Preparation and Thermal Properties of 1‐Hexadecanol‐Palmitic Acid Eutectic Mixture/Activated Carbon Composite Phase Change Material for Thermal Energy Storage

From Energies:

Thermal Conductivity Enhancement of Phase Change Materials for Low-Temperature Thermal Energy Storage Applications [pdf]
Metamaterial-Based Radiative Cooling: Towards Energy-Free All-Day Cooling [pdf]

From Renewable and Sustainable Energy Reviews:

A review and evaluation of thermal insulation materials and methods for thermal energy storage systems

From Materials Letters:

Stearic–capric acid/porous nanoceramics as a novel form-stable composite phase change material (FSPCM) for thermal energy storage

From International Refrigeration and Air Conditioning Conference:

Analysis of TES with PCM (Solid/Liquid) Integrated in a Residential System
Experimental Study on Portable Air-Conditioning System with Enhanced PCM Condenser

Research roundup: Thermo-regulating bamboo fabric; PCM emulsions; nanoparticle-enhanced composite; more

Ben Welter - Friday, November 30, 2018

From Journal of Cleaner Production:

Autonomous greenhouse microclimate through hydroponic design and refurbished thermal energy by phase change material

From Journal of Energy Storage:

Development of heat accumulation unit based on heterogeneous structure of MF/PCM for cogeneration units

From Textile Research Journal:

Preparation and evaluation of thermo-regulating bamboo fabric treated by microencapsulated phase change materials

From International Journal of Clothing Science and Technology:

Development of thermo-regulating fabrics using PCM microcapsules with poly(methyl methacrylate-co-2-hydroxy ethyl methacrylate) shell and n-alkane core

From Canadian Society for Mechanical Engineering International Congress:

Preparation and Properties of Nanoparticle-enhanced Composite Phase Change Material with Ceramic Porous Media

From Solar Energy Materials and Solar Cells:

A comprehensive review on phase change material emulsions: Fabrication, characteristics, and heat transfer performance

From 59th Conference on Simulation and Modelling:

Convective Melting Modeling Approach for Phase Change Materials with Variable Boundary Heating

From Energy Conversion and Management:

Simultaneous energy storage and recovery in the triplex-tube heat exchanger with PCM, copper fins and Al2O3 nanoparticles

From International Journal of Energy Research:

Operation strategies guideline for packed bed thermal energy storage systems [pdf]

From Journal of Molecular Liquids:

Solidification process of hybrid nano-enhanced phase change material in a LHTESS with tree-like branching fin in the presence of thermal radiation

From Energy:

Experiment study on thermal performance of building integrated with double layers shape-stabilized phase change material wallboard

Patent application: Cables made of phase change material

Ben Welter - Thursday, November 29, 2018

U.S. patent application 20180334775 (applicant E.I. du Pont de Nemours and Co., Wilmington, Del.):

"A phase change material (PCM) is useful for thermal management in various applications such as automotive, building, packaging, garments, and footwear, and in devices such as wires and cables. The cable described herein comprises a core and a PCM layer surrounding the core. The PCM layer comprises a PCM composition, which in turn comprises a 1,3-propanediol fatty acid ester. The core consists of a yarn, strand or wire made of a natural or synthetic polymeric material or a metal."

http://www.freepatentsonline.com/20180334775.pdf