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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the monthly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Hysteresis; reflective roof coating; optimizing energy balance of nearly zero energy buildings; more

Ben Welter - Monday, August 31, 2020

From Journal of Molecular Liquids:

The research progress on phase change hysteresis affecting the thermal characteristics of PCMs: A review

From Journal of Building Engineering:

Thermal behavior of a phase change material in a building roof with and without reflective coating in a warm humid zone

From Renewable Energy:

A comprehensive study on thermal storage characteristics of nano-CeO2 embedded phase change material and its influence on the performance of evacuated tube solar water heater

From Sustainable Cities and Society:

Numerical analysis of phase change materials for optimizing the energy balance of a nearly zero energy building

From Journal of Energy Storage:

Multi-objective optimization of cooling and heating loads in residential buildings integrated with phase change materials using the artificial neural network and genetic algorithm
Assessing corrosive behaviour of commercial phase change materials in the 21–25 ºC temperature range
Exergy and economic analyses of nanoparticle-enriched phase change material in an air heat exchanger for cooling of residential buildings
Experimental and numerical investigation on enhancing heat transfer performance of a phase change thermal storage tank
The effect of ultraviolet coating on containment and fire hazards of phase change materials impregnated wood structure

From Energy Conversion and Management:

Application of granular materials for void space reduction within packed bed thermal energy storage system filled with macro-encapsulated phase change materials

From Chemical Engineering Journal:

Simultaneous solar-thermal energy harvesting and storage via shape stabilized salt hydrate phase change material

From Solar Energy:

Characterization and cooling effect of a novel cement-based composite phase change material
Effect of polymer-derived silicon carbonitride on thermal performances of polyethylene glycol based composite phase change materials

From Case Studies in Thermal Engineering:

Effect of porosity and pore density of copper foam on thermal performance of the paraffin-copper foam composite Phase-Change Material

From Renewable and Sustainable Energy Reviews:

A critical assessment on synergistic improvement in PCM based thermal batteries

From Journal of Energy Resources Technology:

Experimental Analysis of Salt Hydrate Latent Heat Thermal Energy Storage System With Porous Aluminum Fabric and Salt Hydrate as Phase Change Material With Enhanced Stability and Supercooling

From Energy Sources:

Experimental study on thermal management and performance improvement of solar PV panel cooling using form stable phase change material
Experimental investigation of thermal performance of indirect mode solar dryer with phase change material for banana slices

From Aalto University:

Experimental design and investigation on a thermal energy storage system using phase change materials [thesis]

From Journal of Applied Physics:

Development of eco-sustainable plasters with thermal energy storage capability

From Chemical Engineering Transactions:

Thermal Performance of Phase Change Material Wallboard with Typical Structure: Artificial Controlled Condition Experimental Investigation

From Materials Research Express:

Fabrication of thermal energy storage wood based on graphene aerogel encapsulated polyethylene glycol as phase change material
Preparation and characterization of acrylic resin encapsulated n-dodecanol microcapsule phase change material

From ACS Sustainable Chemical Engineering:

Synthesis and Characterization of Fatty Acid Amides from Commercial Vegetable Oils and Primary Alkyl Amines for Phase Change Material Applications

From Carbohydrate Polymers:

Fibrous form-stable phase change materials with high thermal conductivity fabricated by interfacial polyelectrolyte complex spinning

From Materials Today: Proceedings:

Effect of various phase change materials (paraffin wax/hydrogenated vegetable oil) packed in a fabricated shell and tube type heat exchanger

From Solar Energy Materials and Solar Cells:

Composite phase change materials with heat transfer self-enhancement for thermal energy storage
Novel network structural PEG/PAA/SiO2 composite phase change materials with strong shape stability for storing thermal energy

From International Journal of Refrigeration:

Improving the performance of household refrigerating appliances through the integration of phase change materials in the context of the new global refrigerator standard IEC 62552:2015

From Advances in Colloid and Interface Science:

Nanoencapsulation of phase change materials (PCMs) and their applications in various fields for energy storage and management

From Building and Environment:

Space heating performance of novel ventilated mortar blocks integrated with phase change material for floor heating

From Energy:

A promising form-stable phase change material composed of C/SiO2 aerogel and palmitic acid with large latent heat as short-term thermal insulation

From Journal of Cleaner Production:

Enhanced thermal storage capacity of paraffin/diatomite composite using oleophobic modification

From International Conference on Renewable Energies for Developing Countries:

Storage efficiency of paraffin-LDPE-MWCNT phase change material for industrial building applications

PCM briefing: Ice Energy files for bankruptcy; Viking Cold has opening for thermal engineer

Ben Welter - Monday, February 10, 2020

Ice Energy, the Santa Barbara, Calif., company that made and distributed ice-based thermal energy storage systems, has filed for bankruptcy. The company's Ice Bear system makes ice at night when demand for electricity is low and capacity is abundant. During the day, the stored ice is used to provide cooling. Details of the Chapter 7 bankruptcy, filed in December, are sparse. The company's website is no longer active. Over the years, Ice Energy had won several major energy storage and distribution contracts with utilities, and had begun marketing a smaller version of the Ice Bear system aimed at retail customers. 

Viking Cold Solutions has an opening for a chemical/thermal engineer in Houston. The engineer will "conduct research in Thermal Science, Storage/Heat Transfer and Phase Change Materials (PCM) for low temperature applications (<10⁰C)."

Axiom Exergy has secured more than $1 million in orders for the Axiom Cloud, a software platform that helps manage energy consumption in supermarkets and cold storage facilities that use the company's PCM-powered thermal storage systems.

• The 2020 Advancements in Thermal Management conference, to be held Aug. 6-7 in Denver, has issued a call for presentations. Topics include thermal materials, thermal modeling and characterization and measurement of thermal materials. Abstracts are due Feb. 12.

EnergyNest will install a large thermal energy storage battery at a Senftenbacher brick factory in Austria. The system will temporarily store excess energy in the form of hot air from a tunnel furnace. The stored heat be converted to steam and later reused in production.

Devan Chemicals, the Belgium-based developer of finishing technologies for textiles, introduced its Tones of Cool Bio technology at the Heimtextil trade show in Frankfurt, Germany, last month. The technology "stimulates the textile to dissipate redundant heat from the body and to instantly reduce the body temperature," the company says. The phase change materials "are derived from sustainable, natural sources.

Registration is open for the 23rd Microencapsulation Industrial Convention to be held June 8-11 in Rotterdam, Netherlands.

Research roundup: Carbonized waste tires; cetyl palmitate/nickel foam; hydrated salt corrosion assessment; more

Ben Welter - Tuesday, January 14, 2020

From Waste Management:

Evaluation of carbonized waste tire for development of novel shape stabilized composite phase change material for thermal energy storage

From Journal of Energy Storage:

Development of polyurethane foam incorporating phase change material for thermal energy storage
Facile synthesis and thermal performance of cetyl palmitate/nickel foam composite phase change materials for thermal energy storage
Optimal sizing design and operation of electrical and thermal energy storage systems in smart buildings

From Energy Conversion and Management:

Numerical investigation of the effects of the nano-enhanced phase change materials on the thermal and electrical performance of hybrid PV/thermal systems
Thermal storage and thermal management properties of a novel ventilated mortar block integrated with phase change material for floor heating: an experimental study

From Applied Energy:

Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage

From Renewable Energy:

Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems
Experimental study on latent thermal energy storage system with gradient porosity copper foam for mid-temperature solar energy application
Selection of a phase change material and its thickness for application in walls of buildings for solar-assisted steam curing of precast concrete
Experimental assessment of Phase Change Material (PCM) embedded bricks for passive conditioning in buildings

From Applied Thermal Engineering:

Analysis of energy retrofit system using latent heat storage materials applied to residential buildings considering climate impacts
Experimental and numerical simulation of phase change process for paraffin/expanded graphite/ethylene-vinyl acetate ternary composite
An experimental investigation on the evaporation of polystyrene encapsulated phase change composite material based nanofluids

From Solar Energy Materials and Solar Cells:

Lightweight mesoporous carbon fibers with interconnected graphitic walls for supports of form-stable phase change materials with enhanced thermal conductivity

From Energies:

The Effects of Fin Parameters on the Solidification of PCMs in a Fin-Enhanced Thermal Energy Storage System

From Journal of Materials Science:

Graphene aerogel-based phase changing composites for thermal energy storage systems

From Journal of Mechanical Science and Technology:

A study on development of the thermal storage type plate heat exchanger including PCM layer

From Journal of Power Sources:

Delayed liquid cooling strategy with phase change material to achieve high temperature uniformity of Li-ion battery under high-rate discharge

From Scientific Reports:

Modification of asphalt mixtures for cold regions using microencapsulated phase change materials

From ASES National Solar Conference:

A Study on the Thermal Energy Storage System Using Multiple PCMs [pdf]

From Molecules:

Assessment of Thermal Performance of Textile Materials Modified with PCM Microcapsules Using Combination of DSC and Infrared Thermography Methods

From Energy and Buildings:

Experimental study on thermal performance of a mobilized thermal energy storage system: A case study of hydrated salt latent heat storage

From Chemical Engineering Journal:

Shape-stabilized hydrated salt/paraffin composite phase change materials for advanced thermal energy storage and management

From International Journal of Heat and Mass Transfer:

A conjugate heat transfer model for unconstrained melting of macroencapsulated phase change materials subjected to external convection

PCM briefing: Acumen invests in Promethean Power Systems; Viking Cold wins Cleanie award

Ben Welter - Monday, October 14, 2019

• Social venture capital investor Acumen has invested an undisclosed amount in Promethean Power Systems Inc., which makes PCM-based refrigeration systems for cold-storage and milk chilling applications in off-grid and partially electrified areas of developing countries. Jiten Ghelani, chief executive of Promethean, which is based in Boston, Mass., and Pune, India, said the investment would help the company accelerate the adoption of its products across India and other markets, and also expand its cooling-as-a-service offerings. 

Air New Zealand pillow• Two new consumer products featuring temperature-control fabrics from Outlast Technologies hit the market recently: A pillow designed to improve the quality of sleep for passengers on Air New Zealand's long-haul flights and a Calloway pullover designed to keep golfers cool in warm weather and warm in cold weather

Viking Cold Solutions of Houston, Texas, won a Platinum Cleanie Award last month for a PCM-based storage and demand management project in Massachusetts. The Cleanie Awards, presented at this year's North America Smart Energy Week in Salt Lake City, Utah, recognize companies and individuals shaping the clean-tech and renewable energy industries. The Viking Cold project involved the installation and commissioning of TES systems to store refrigeration energy and facilitate 1.3 MW of energy demand reduction across eight customer facilities, including the Greater Boston Food Bank.

Sonoco ThermoSafe of Arlington Heights, Ill., has introduced a new temperature-controlled box rental service. "The new Orion r product line is based on the existing ChillTech product," said Ben VanderPlas, manager of engineering and product management at Sonoco. "We’ve made changes to make the product more reusable (added EPP) and have increased the VIP insulation. The PCMs remain the same, using paraffin-based materials. ChillTech was developed by Laminar Medica in the UK prior to their acquisition and integration into the ThermoSafe business. Solutions will exist for 2-8, 15-25 and frozen temperatures."

Sonoco ThermoSafe has posted an opening for a Senior Account Manager Europe, to be based in Netherlands.

Microtek Laboratories Inc. of Dayton, Ohio, has introduced a new line of PCM-equipped pouches and panels for use in temperature-controlled shipping.

Research roundup: Microencapsulated coconut oil; mixed alkanes microcapsules; low-hydration heat cement slurry; more

Ben Welter - Tuesday, August 27, 2019

From Cellulose:

Microencapsulated organic coconut oil as a natural phase change material for thermo-regulating cellulosic fabrics

From Journal of Physics: Conference Series:

Numerical and experimental investigation of melting process in spherical PCM capsule used for low-temperature thermal energy storage systems

From Energy:

Synthesis and characterization of mixed alkanes microcapsules with phase change temperature below ice point for cryogenic thermal energy storage
Preparation of Low Hydration Heat Cement Slurry with Micro-encapsulated Thermal Control Material

From Applied Thermal Engineering:

A Three-Dimensional Numerical Investigation of a Novel Shallow Bore Ground Heat Exchanger Integrated with Phase Change Material

From Polymer Science:

Preparation of Phase Change Microcapsules with Inorganic/Polymer Hybrid Shell Through a “Two-Step” Reaction

From Solar Energy:

Improved thermal energy storage for nearly zero energy buildings with PCM integration

From Thermal Science and Engineering Progress:

A theoretical and experimental study of a TBAB salt hydrate based cold thermal energy storage in an air conditioning system

From Journal of Energy Storage:

A Review of Phase Change Materials for the Thermal Management and Isothermalisation of Lithium-Ion Cells

From Energy Conversion and Management:

Experimental performance evaluation of a novel designed phase change material integrated manifold heat pipe evacuated tube solar collector system

From Renewable and Sustainable Energy Reviews:

Corrosion mechanisms in molten salt thermal energy storage for concentrating solar power

Croda began work on new microencapsulated PCM four years ago

Ben Welter - Friday, July 26, 2019

UK-based Croda International recently announced the launch of a microencapsulated form of biobased phase change material developed at the company's PCM technical center in Netherlands. The new material is designed to be used to control temperatures in bedding, mattresses, automotive interiors, clothing and other applications.

Jerome Gonthier and Martin ButtersThe development was led by Marco Auerbach and Jerome Gonthier, working with colleagues who have expertise in microencapsulation and acrylic polymer. Martin Butters, a specialist in PCM applications and business development, also supported the project.

Gonthier and Butters provided details on the new material in an email interview.

Q: What prompted the decision to develop this technology?

A: "Having established a range of high-quality bio-based PCMs, market demand led us to explore the microencapsulation of these PCMs. Microencapsulation converts the PCM into particles that are offered to the market in two forms, powder and water-based dispersion. Microencapsulated PCMs are often advantageous for use in composite materials such as coatings, fibers and other matrices where PCM leakage needs to be avoided."

Q: How long did it take to complete the project?

A: "Overall the project ran for about four years leading to the launch of the first products in 2018."

Q: Did the team surmount any unexpected challenges, technical or otherwise?

A: "The challenges were mainly those we expected – achieving microcapsules with good durability, very low levels of free wax and overcoming sub-cooling (reduction in crystallisation temperature due to microencapsulation)."

Q: When did Croda officially launch the technology commercially?

SEM photo of CrodaTherm ME29P (powder grade) A: "The first products, CrodaTherm ME 29D (50% dispersion) and CrodaTherm ME 29P (powder), which are 29º C melting point products, were launched in Q4 2018. 32º C versions will be added to the range shortly and we expect the range to be further extended with other operating temperatures in due course."

Q: Does Croda manufacture fibers and textiles with the microencapsulated PCM? Or does it manufacture the MPCM and sell it to fiber and textile manufacturers?

A: "Croda does not produce fibers or textiles, instead we specialize in offering PCMs that are developed and manufactured in-house, for use in such applications (and many more)."

Q: What specs can you share on the MPCM, such as composition, peak melt point and latent heat storage capacity?

A: "We microencapsulate CrodaTherm bio-based PCMs with an acrylic-type shell. For CrodaTherm ME 29D and ME 29P, peak melting temperature is 29ºC and latent heat is typically about 180 J/g."

Q: Does the MPCM have any properties, such as latent heat storage capacity or ease of manufacture, that sets it apart from competing products?

A: "We use internally produced bio-based PCM, rather than paraffin waxes sourced externally from the market, meaning we have full control over quality and the products have high bio-based content and excellent thermal properties."

Q: Have textiles embedded with this MPCM undergone thermal effusivity testing or other tests that would confirm their effectiveness in managing temperatures in consumer products?

A: "Several tests have been carried out to confirm the performance of materials embedded with mPCM and further work will be carried out, including thermal effusivity."

Q: Will the technology be used in any products scheduled for release this year or next?

A: "A number of projects are underway for different applications, so we’ll have to wait and see!"

PCM briefing: PureTemp fabrics featured at Materio library; new round of funding for Ecozen Solutions

Ben Welter - Friday, July 26, 2019

PureTemp-enhanced fabrics were among the new materials presented at a gathering of architects, designers and journalists at the MatériO library in Paris this week. The materials library, which also has showrooms in Brussels, Seoul and Shanghai, lists thousands of "cutting edge" materials and technologies in its online database, including PureTemp's biobased PCM.

Southern Research opened the new Energy Storage Research Center on its engineering campus in Birmingham, Ala., this month. The center will work to speed the development of clean and sustainable energy storage technology, including thermal energy storage systems. 

Ecozen Solutions of India, which makes portable solar cold rooms for use on small farms, recently closed a Series A round of funding from investors including impact investment fund manager Caspian and Hivos-Triodos Fund, which is affiliated with Netherlands-based Triodos Bank. Omnivore Capital Management Advisors, which originally invested in Ecozen in 2015, also participated in the round, AgFunder News reports. The solar cold room's thermal storage unit can store power for more than 36 hours in case of cloudy or rainy weather. 

PCM briefing: Axiotherm wins 2 innovation awards; newly commissioned pilot power plant in Sweden uses SaltX TES

Ben Welter - Friday, July 05, 2019

ESDA-Axiotherm GmbH won two awards in this year's INNOspace Masters ideas competition. The competition, sponsored by the Space Administration of the German Aerospace Center, honors innovative ideas that address the challenges faced by the space industry. The winners were announced this week in Berlin. ESDA-Axiotherm won the overall prize for the development of a PCM polymer compound for the thermal stabilization of components and systems. The German company also won the OHB Challenge, which honors ready-to-use solutions.

Noor Abu Dhabi, the world’s largest single-site solar power project with an installed capacity of 1,177 MW, has been successfully commissioned. The project is a joint venture between the government of Abu Dhabi and a consortium comprising Marubeni Corp., Japan, and Jinko Solar Holding, China. Abu Dhabi says the project's 3.2 million solar  panels provide enough power for 90,000 people. 

• The Swedish power producer Vattenfall has commissioned an industrial-scale, 0.5 MW/10 MWh, pilot test facility at its Reuter power plant, employing thermal energy storage technology developed by SaltX of Sweden. The technology uses nano-coated salts to store thermal energy. 

Croda International Plc posted a product announcement on its LinkedIn page this week: "CrodaTherm can be incorporated into wearable and non-wearable textile fibres to improve temperature regulation." There's more information on crodatherm.com. According to the website, Croda has encapsulated its bio-based phase change material "in a durable acrylic polymer shell, so that when the bio-based core changes phase, the particle remains solid." I hope to have more details on the technology in time for next week's newsletter.

PCM briefing: Building Skins conference agenda; tough words for CALMAC and Axiom Exergy

Ben Welter - Saturday, May 25, 2019

• The agenda is set for the 14th International Conference on Advanced Building Skins, to be held Oct. 28-29 in Bern, Switzerland. The Japanese architect and Pritzker laureate Shigeru Ban will be the keynote speaker. Among the more than 150 speakers is Thomas Friedrich of Innogration GmbH, Germany, who will discuss "collection of thermal energy from the façade" and "decentralized PCM storage elements for saving thermal energy." The registration fee is 680 euros and includes the conference documentation as well as meals during both days. Participants who register by May 31 will receive a 20 percent discount.

Mike HopkinsIn a LinkedIn post, former Ice Energy CEO Mike Hopkins shared his take on two of the California company's competitors in distributed thermal energy storage. "Look at @CALMAC, a Portfolio of Trane - been in our industry forever, good product, but haven't been able to secure utility deals because their large bespoke systems make it too risky to commit to MWs in a location on a schedule," wrote Hopkins, who is now CEO at Bakken Midstream. "Relative newcomer [Axiom Exergy] came to market with their #refrigeration #battery. Good concept but not plug and play. Not surprising, they seem to have recast themselves as a #cloud based power management company."

• Speaking of CALMAC: CEO Mark McCracken will speak on "some of the myths surrounding ice-based TES" at an ASHRAE technical seminar on thermal energy storage in building design in Hong Kong June 13. 

FedEx Express has launched a temperature-controlled shipping solution in Japan, Korea and Singapore. The company says its Medpak VIºC packaging, first introduced in Europe, provides 96-hour temperature stability. The reusable thermal packaging features vacuum insulated panels and phase change material validated to International Safe Transit Association 7D standards.

CIC energiGUNE, a research center in Spain's Basque Country, has an opening for a researcher in its thermal energy storage area. The research will focus on the storage of heat through reversible chemical reactions "in a range of temperature few explored so far (120 - 250 °C)." The application deadline is Sept. 11, 2019.   

Barbara Pause of Textile Testing & Innovation will be among the speakers at this year's Advances in Thermal Management conference, to be held Aug. 7-8 in Denver, Colo. Her topic: "Measuring and Modeling the Thermal Performance of Products Equipped with Phase Change Materials." 

• Thermal energy storage startup NET Energy of Chicago is among 10 finalists for the University of Chicago’s 19th annual Edward L. Kaplan New Venture Challenge. Winners will be announced next week, with the top companies sharing $250,000 in cash, along with $250,000 worth of office space and professional services from program sponsors. 

Research roundup: High-conductivity nanomaterials; paper board packaging; battery thermal management; more

Ben Welter - Thursday, May 16, 2019

From Heat and Mass Transfer:

Experimental and numerical analysis of composite latent heat storage in cooling systems for power electronics

From Journal of Sol-Gel Science and Technology:

A robust, flexible superhydrophobic sheet fabricated by in situ growth of micro-nano-SiO2 particles from cured silicone rubber

From Journal of Thermal Analysis and Calorimetry:

High-conductivity nanomaterials for enhancing thermal performance of latent heat thermal energy storage systems

From Building Simulation:

Optimization and sensitivity analysis of design parameters for a ventilation system using phase change materials

From Journal of Packaging Technology and Research:

Thermal Analysis of Paper Board Packaging with Phase Change Material: A Numerical Study

From Energy Storage:

Thermal performance of battery thermal management system using composite matrix coupled with mini‐channel

From Phase Transitions:

A study on preparation and properties of carbon materials/myristic acid composite phase change thermal energy storage materials

From ACS Applied Materials & Interfaces:

Melamine Foam Supported Form-stable Phase Change Materials with Simultaneous Thermal Energy Storage and Shape Memory Property for Thermal Management of Electronic Devices

From International Conference on Thermal Engineering:

Performance Enhancement of Unitary and Packaged Air Conditioners With Phase Change Material
Performance Comparison of Different Phase Change Materials For Solar Cooking During off Sun Sunshine Hours
A Review on Enhancement of Thermophysical Properties of Paraffin Wax PCM With Nanomaterials
Nano-Enhanced PCMs for Low Temperature Thermal Energy Storage Systems and Passive Conditioning Applications

From Chemistry Select:

Designing Coconut Oil Encapsulated Poly(stearyl methacrylate‐co‐hydroxylethyl metacrylate) Based Microcapsule for Phase Change Materials

From Evolution in Polymer Technology Journal:

Enhancement of Thermo-Regulating Textile Materials Using Phase Change Material

From Materials Research Express:

Improved thermal characteristics of Ag nanoparticles dispersed myristic acid as composite for low temperature thermal energy storage

From Applied Energy:

On the performance of ground coupled seasonal thermal energy storage for heating and cooling: A Canadian context

From Solar Energy Materials and Solar Cells:

Thermal stability enhancement of d-mannitol for latent heat storage applications