Phase Change Matters

From Journal of Molecular Liquids:

• The research progress on phase change hysteresis affecting the thermal characteristics of PCMs: A review

From Journal of Building Engineering:

• Thermal behavior of a phase change material in a building roof with and without reflective coating in a warm humid zone

From Renewable Energy:

• A comprehensive study on thermal storage characteristics of nano-CeO2 embedded phase change material and its influence on the performance of evacuated tube solar water heater

From Sustainable Cities and Society:

• Numerical analysis of phase change materials for optimizing the energy balance of a nearly zero energy building

From Journal of Energy Storage:

• Multi-objective optimization of cooling and heating loads in residential buildings integrated with phase change materials using the artificial neural network and genetic algorithm
• Assessing corrosive behaviour of commercial phase change materials in the 21–25 ºC temperature range
• Exergy and economic analyses of nanoparticle-enriched phase change material in an air heat exchanger for cooling of residential buildings
• Experimental and numerical investigation on enhancing heat transfer performance of a phase change thermal storage tank
• The effect of ultraviolet coating on containment and fire hazards of phase change materials impregnated wood structure

From Energy Conversion and Management:

• Application of granular materials for void space reduction within packed bed thermal energy storage system filled with macro-encapsulated phase change materials

From Chemical Engineering Journal:

• Simultaneous solar-thermal energy harvesting and storage via shape stabilized salt hydrate phase change material

From Solar Energy:

• Characterization and cooling effect of a novel cement-based composite phase change material
• Effect of polymer-derived silicon carbonitride on thermal performances of polyethylene glycol based composite phase change materials

From European Polymer Journal:

• Extremely fast synthesis of polythioether based phase change materials (PCMs) for thermal energy storage

From Journal of Building Engineering:

• Thermal behavior analysis of hollow bricks filled with phase-change material (PCM)

From Energies:

• FEM Applied to Building Physics: Modeling Solar Radiation and Heat Transfer of PCM Enhanced Test Cells

From Iranian Polymer Journal:

• Encapsulation of phase change materials with alginate modified by nanostructured sodium carbonate and silicate

From Energy & Fuels:

• Aluminium ammonium sulfate dodecahydrate with multiple additives as composite phase change materials for thermal energy storage

From Materials Today: Proceedings:

• Evaluation and reduction of temperature stresses in concrete pavement by using phase changing material
• Optimization of Heat Energy Based on Phase Change Materials used in Solar Collector using Taguchi Method
• Experimental and Theoretical Investigations on Thermal Conductivity of the Paraffin Wax using CuO Nanoparticles

From Journal of Energy Storage:

• Novel synthesis of silica coated palmitic acid nanocapsules for thermal energy storage
• Recent progress in phase change materials storage containers: Geometries, design considerations and heat transfer improvement methods
• Effect of phase separation and supercooling on the storage capacity in a commercial latent heat thermal energy storage: Experimental cycling of a salt hydrate PCM
• Energy efficiency optimization of the waste heat recovery system with embedded phase change materials in greenhouses: A thermo-economic-environmental study
• Characterization of innovative mortars with direct incorporation of phase change materials

From Applied Thermal Engineering:

• A trade study of a phase change system in a stratospheric airship based on a triple gasbag concept
• Experimental evaluation of structural insulated panels outfitted with phase change materials
• Lattice Boltzmann simulation of melting heat transfer in a composite phase change material

From Geothermics:

• Parametric modeling and simulation of low temperature energy storage for cold-climate multi-family residences using a geothermal heat pump system with integrated phase change material storage tank

From Energy:

• Multi-level uncertainty optimisation on phase change materials integrated renewable systems with hybrid ventilations and active cooling
• A novel solar thermal system combining with active phase-change material heat storage wall (STS-APHSW): Dynamic model, validation and thermal performance

From Advances in Energy Research:

• Theoretical Modeling of Phase Change Material-Based Space Heating Using Solar Energy

From Chemical Engineering Journal:

• High latent heat and recyclable form-stable phase change materials prepared via a facile self-template method

From Composites Part B: Engineering:

• In situ one-step construction of monolithic silica aerogel-based composite phase change materials for thermal protection

From Solar Energy:

• Effects of external insulation component on thermal performance of a Trombe wall with phase change materials

From Journal of Architectural Engineering:

• Experimental and Numerical Thermal Properties Investigation of Cement-Based Materials Modified with PCM for Building Construction Use

From Energy Conversion and Management:

• Experimental and numerical study on the thermal performance of ventilated roof composed with multiple phase change material (VR-MPCM)

From Construction and Building Materials:

• Multi-scale analysis on thermal properties of cement-based materials containing micro-encapsulated phase change materials

From Applied Energy:

• D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability
• Novel bio-based phase change materials with high enthalpy for thermal energy storage

From Materials Today Energy:

• A detailed review on heat transfer rate, supercooling, thermal stability and reliability of nanoparticle dispersed organic phase change material for low-temperature applications

From International Journal of Thermal Sciences:

• Experimental study and assessment of high-tech thermal energy storing radiant floor heating system with latent heat storage materials

From Advanced Powder Technology:

• Paraffin core-polymer shell micro-encapsulated phase change materials and expanded graphite particles as an enhanced energy storage medium in heat exchangers

From International Journal of Energy Research:

• Design of diatomite‐based hydrated salt composites with low supercooling degree and enhanced heat transfer for thermal energy storage

From Journal of Physical Chemistry B:

• Clusters in Liquid Fatty Acids: Structure and Role in Nucleation

From Construction and Building Materials:

• Development of thermal energy storage lightweight structural cementitious composites by means of macro-encapsulated PCM
• Preparation of microencapsulated phase change materials used graphene oxide to improve thermal stability and its incorporation in gypsum materials

From Journal of Power and Energy:

• Numerical modelling of phase change material melting process embedded in porous media: Effect of heat storage size

From Advanced Materials Interfaces:

• Phase Change Materials: Doubly Coated, Organic–Inorganic Paraffin Phase Change Materials: Zinc Oxide Coating of Hermetically Encapsulated Paraffins

From NASA Technical Reports Server:

• Utilization of Micro Tube Heat Exchanger for Next Generation Phase Change Material Heat Exchanger Development

From SN Applied Sciences:

• Encapsulation of paraffin wax by rigid cross-linked poly (styrene divinylbenzene-acrylic acid) and its thermal characterization

From Energy Conversion and Management:

• Transient performance of a Peltier super cooler under varied electric pulse conditions with phase change material

From Applied Thermal Engineering:

• Thermal optimization of a kirigami-patterned wearable lithium-ion battery based on a novel design of composite phase change material
• An experimental and theoretical study of the solidification process of phase change materials in a horizontal annular enclosure

From Journal of Energy Storage:

• Enhancement of the thermal energy storage capacity of a parabolic dish concentrated solar receiver using phase change materials

From Renewable Energy:

• Numerical simulation on the thermal performance of a PCM-containing ventilation system with a continuous change in inlet air temperature

From Energy Fuels:

• Graphene modified hydrate salt/UV-curable resin form-stable phase change materials: continuously adjustable phase change temperature and ultrafast solar-to-thermal conversion

From Journal of Industrial and Chemical Engineering:

• Thermal performance enhancement of a phase change material with expanded graphite via ultrasonication

From Chemistry Select:

• Microencapsulation of Stearic Acid into Strontium Titanate Shell by Sol‐Gel Approach for Thermal Energy Storage

From Materials:

• Phase Change Materials for Energy Efficiency in Buildings and Their Use in Mortars

From Applied Energy:

• Natural convection during melting in vertical finned tube latent thermal energy storage systems
• Year-round performance analysis of a photovoltaic panel coupled with phase change material

From Energy Procedia:

• A Review of the Performance of Buildings Integrated with Phase Change Material: Opportunities for Application in Cold Climate

From Journal of Applied Polymer Science:

• Encapsulation of polar phase change materials via multiemulsification and crosslinking method and its application in building

From Journal of Energy Storage:

• Thermal performance of shell and tube latent heat storage unit: Comparative assessment of horizontal and vertical orientation
• Experimental investigation of phase change in a multitube heat exchanger

From Chemistry Select:

• Preparation and Thermal Properties of Stearic Acid/n‐Octadecane Binary Eutectic Mixture as Phase Change Materials for Energy Storage

From Journal of Materials Research:

• Synthesis of novel shape-stabilized phase change materials with high latent heat and low supercooling degree for thermal energy storage

From Science of Advanced Materials:

• Fabrication and Performance of Polyurethane/Polyurea Microencapsulated Phase Change Materials with Isophorone Diisocyanate via Interfacial Polymerization
• Design and Analysis of Battery Box Based on Graphite-Phase Change Material and Air Cooling

From Experimental Techniques:

• Design, Build, and Test a Hybrid Cooling System for Crash Helmet

From Journal of Thermal Analysis and Calorimetry:

• Capric acid/intercalated diatomite as form-stable composite phase change material for thermal energy storage
• Preparation and thermal performances of microencapsulated phase change materials with a nano-Al2O3-doped shell

From Energy Procedia:

• Development of microencapsulated phase change material with poly (methyl methacrylate) shell for thermal energy storage
• Supercooling study of erythritol/EG composite phase change materials
• Thermal performance of pouch Lithium-ion battery module cooled by phase change materials
• Active cooling based battery thermal management using composite phase change materials
• Investigation on Thermal Performance of an Integrated Phase Change Material Blind System for Double Skin Facade Buildings
• Experimental study on preparation of a novel foamed cement with paraffin/ expanded graphite composite phase change thermal energy storage material

From Colloids and Surfaces A: Physicochemical and Engineering Aspects:

• Synthesis and performance evaluation of paraffin microcapsules with calcium carbonate shell modulated by different anionic surfactants for thermal energy storage

From Journal of Materials Chemistry A:

• A novel shape-stabilization strategy for phase change thermal energy storage

From Journal of Molecular Liquids:

• Melting of phase change materials in a trapezoidal cavity: Orientation and nanoparticles effects

From Energy and Buildings:

• Development of new nano-enhanced phase change materials (NEPCM) to improve energy efficiency in buildings: lab-scale characterization

From Applied Sciences:

• Efficient Characterization of Macroscopic Composite Cement Mortars with Various Contents of Phase Change Material

From Solar Energy:

• Modelling and performance analysis of a new concept of integral collector storage (ICS) with phase change material

From Energies:

• Analysis of Thermal Performance and Energy Saving Potential by PCM Radiant Floor Heating System based on Wet Construction Method and Hot Water

From Applied Energy:

• Supercooling of phase-change materials and the techniques used to mitigate the phenomenon

From Polymer Chemistry:

• Encapsulating an organic phase change material within emulsion-templated poly(urethane urea)s

From AIP Advances:

• Thermal expansion effects on the one-dimensional liquid-solid phase transition in high temperature phase change materials

From Journal of Materials Chemistry A:

• A thermal energy storage composite with sensing function and its thermal conductivity and thermal effusivity enhancement

From Materials Science and Engineering:

• Experimental Measurements of Hot Water Stratification in a Heat Storage Tank

From Thermochimica Acta:

• Modification of physical and thermal characteristics of stearic acid as a phase change materials using TiO2-nanoparticles

From Energy and Buildings:

• Thermal and Structural Performance of Geopolymer Concrete Containing Phase Change Material Encapsulated in Expanded Clay
• An experimental study on applying organic PCMs to gypsum-cement board for improving thermal performance of buildings in different climates

From International Journal of Biological Macromolecules:

• Sodium alginate/feather keratin-g-allyloxy polyethylene glycol composite phase change fiber

From Construction and Building Materials:

• Thermal properties of lightweight concrete incorporating high contents of phase change materials

From Progress in Organic Coatings:

• Fabrication and characterization of microencapsulated n-heptadecane with graphene/starch composite shell for thermal energy storage

From Sustainable Energy and Fuels:

• A thermal energy storage prototype using sodium magnesium hydride

From Thermal Science and Engineering Progress:

• Experimental investigation of the thermal performance of a helical coil latent heat thermal energy storage for solar energy applications

From International Journal of Sports Physiology and Performance:

• Exploring the Efficacy of a Safe Cryotherapy Alternative: Physiological Temperature Changes from Cold Water Immersion vs Prolonged Phase Change Material Cooling

From Applied Sciences:

• A Form Stable Composite Phase Change Material for Thermal Energy Storage Applications over 700° C

From Journal of Thermal Science:

• Energy Storage Performance of a PCM in the Solar Storage Tank

From International Journal of Applied Engineering Research:

• Numerical assessment of suitability of phase-change materials in a concentric PCM-module for thermal storage applications [pdf]

From International Journal of Energy Research:

• Experimental measurements and numerical computation of nanofluid and microencapsulated phase change material in porous material

From IOP Conference Series: Materials Science and Engineering:

• Nano-enhanced phase change material effects on the supercooling degree improvement: A review

From Renewable Energy:

• Potential of ventilation systems with thermal energy storage using PCMs applied to air conditioned buildings

From Journal of Mechanical Engineering and Technology:

• Thermal performance analysis of nano enhanced paraffin wax and myristic acid

From Solar Energy:

• Synthesis and characterization of microencapsulated phase change materials with comb-like acrylic co-polymer shell as thermal energy storage materials
• Sensible and latent heat energy storage systems for concentrated solar power plants, exergy efficiency comparison

From Solar Energy Materials and Solar Cells:

• Thermal energy storage characteristics of myristic acid-palmitic eutectic mixtures encapsulated in PMMA shell

From Thermal Science and Engineering Progress:

• Parametric analysis and optimization of an underfloor solar assisted heating system with phase change materials

From International Journal of Heat and Mass Transfer:

• The improved enthalpy-transforming based lattice Boltzmann model for solid-liquid phase change

From Applied Energy:

• Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell

From AIP Conference Proceedings:

• Preparation and characterization of nanoparticle blended polymers for thermal energy storage applications

From Energy:

• Energy performance and economic analysis of a TIM-PCM wall under different climates

From Applied Energy:

• A modeling study on the heat storage and release characteristics of a phase change material based double-spiral coiled heat exchanger in an air source heat pump for defrosting
• Dynamic thermal management for industrial waste heat recovery based on phase change material thermal storage

From Solar Energy:

• Modeling of solidification including supercooling effects in a fin-tube heat exchanger based latent heat storage

From Solar Energy Materials and Solar Cells:

• Experimental study on thermal properties and thermal performance of eutectic hydrated salts/expanded perlite form-stable phase change materials for passive solar energy utilization
• Cotton-derived carbon sponge as support for form-stabilized composite phase change materials with enhanced thermal conductivity
• Enhanced thermal conductivity of microencapsulated phase change materials based on graphene oxide and carbon nanotube hybrid filler
• A novel core-shell structural montmorillonite nanosheets/stearic acid composite PCM for great promotion of thermal energy storage properties

From Energy and Buildings:

• Numerical analysis for maximizing effective energy storage capacity of thermal energy storage systems by enhancing heat transfer in PCM
• Optimization of phase change materials (PCMs) to improve energy performance within thermal comfort range in the South Korean climate

From Journal of King Saud University - Science:

• Exact and approximate solutions of a phase change problem with the moving phase change material and variable thermal coefficients

From Journal of Molecular Liquids:

• Preparation and thermophysical properties of low temperature composite phase change material octanoic-lauric acid/expanded graphite

From International Journal of Refrigeration:

• Supercooling characteristics of phase change material particles within phase change emulsions
• Enhancement of ice formation around vertical finned tubes for cold storage applications

From Frontiers in Materials:

• Thermoplastic polyurethane blends with thermal energy storage/release capability

From Energies:

• Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants

From Progress in Computational Fluid Dynamics:

• Towards the simulation of supercooling and convection in phase change materials using a thermal lattice Boltzmann method

From Nanomaterials:

• Palm Kernel Shell Activated Carbon as an Inorganic Framework for Shape-Stabilized Phase Change Material

From Journal of Power Sources:

• A comprehensive review on a passive (phase change materials) and an active (thermoelectric cooler) battery thermal management system and their limitations

From Applied Energy:

• Process integration of thermal energy storage systems – Evaluation methodology and case studies

From Journal of Nanomaterials:

• Effects of Biceramic AlN-SiC Microparticles on the Thermal Properties of Paraffin for Thermal Energy Storage

The lab folks at PureTemp have had a keen interest in the T-history method since our days as a tech startup with a small budget. T-history is a relatively simple, low-cost way to determine the heat of fusion, specific heat and thermal conductivity of phase change materials.

New research on the topic turned up in one of our automated searches earlier this month: “Characterizing phase change materials using the T-History method: On the factors influencing the accuracy and precision of the enthalpy-temperature curve.” The lead author, Pepe Tan, is a pursuing a Ph.D. at Chalmers University of Technology in Sweden. I contacted him to find out more. 

Q: What prompted your interest in studying the T-history method?

A: “When I started my Ph.D. at Chalmers, T-history was a good complement to the available DSC instrument in our research group. And it was a nice opportunity to collaborate with ZAE Bayern and learn the method. While implementing the method, we found it was very worth studying certain aspects of it in parallel, because of how different the method has been presented so far in the scientific community.”

Q: Do you envision T-history replacing DSC for characterizing and validating PCMs as an industry standard? If not for PCM validation, perhaps for application engineering and thermal modeling?

A: “I definitely consider T-history and DSC as complementary methods since their limitations for finding the intrinsic PCMs properties are still subject to research. With this uncertainty, any measurement available from different sources would be useful for the engineer to carefully estimate the actual behavior of the PCM in its application.”   

Q: When do you believe T-history will be studied and validated sufficiently to become adopted as a commercially available piece of equipment?

A: “To reach that goal, a systematic assessment of different implementations of the method (setup and data evaluation) would be necessary. But spending this effort also depends on the current needs for accurate PCM properties in typical applications.”

Q: Will the mathematical model of the method become open-source and available for laboratories?

A: “The data evaluation method in the paper should be seen as one proposal on how to calculate the enthalpy from real experimental data. And it is presented in detail, so that it can be recreated.

“The challenge in our experiments was to negate the noise amplification when differentiating the temperature over time data. But this could be done in many different ways, which will in turn affect the enthalpy results. We made the raw experimental data available so that other data evaluation methods can be tested.”

Q: What do you view as the most significant challenge with T-history? How does this compare to the challenges associated with DSC?

A: “That would be to perform a rigorous measurement uncertainty analysis in order to specify a reliable limit for accuracy and precision in terms of an uncertainty. Since this strongly depends on the individual implementation of the method and the chosen data evaluation, the DSC is in my opinion one step ahead.”

Q: Is T-history capable of accurate and precise measurement with thermal conductivity additives or nucleating agents?

A: “This depends on the material and the actual implementation of the method. And this would be an example where the possibility to use complementary methods that utilize different sample sizes like DSC and T-history will be helpful to filter out the intrinsic material behavior. The larger sample sizes of the T-history setup should increase the chance to actually have representative samples, meaning samples containing a representative amount of the nucleating agent and/or the thermal conductivity additives."  

Q: What are your postdoctoral plans?

A: “I expect to graduate by June 2020. At the moment, I plan to wait and see what options are available when the graduation date comes a bit closer.”