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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the monthly PCM newsletter. Or join the discussion on LinkedIn.

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PCM battery shows promise in home heating system

Ben Welter - Tuesday, September 15, 2020

A home heating system equipped with a PCM battery put up encouraging numbers in a small trial in northern Italy earlier this year. The monthlong test “shows that is possible [for such a system] to supply the whole heating demand of a house reducing close to zero the costs,” says Domenico Feo, who developed the system. The full report, prepared by ThermaLink, a trademark of Sunservice Srl of Treviso, Italy, is available here.

ThermaCubeThe system is composed of a 6 kW solar array, an air/water heat pump and a thermal battery filled with BioPCM Q42, a biobased phase change material supplied by Phase Change Energy Solutions of Asheboro, N.C. A control unit, PCDCube, monitors temperatures and manages energy flow to optimize system performance. In an interview with Phase Change Matters, Feo answered questions about the heat battery, recently rebranded as ThermaCube.

Q: Thermal conductivity has proven to be a challenge in thermal energy storage across most types of PCM. Was conductivity an issue with the required charge/discharge cycles?

A: "As already known, the thermal conductivity of the PCM, especially of the organic one that we use, is low. This is, at the same time, a disadvantage and an advantage. The disadvantage has been minimized in using a heat exchanger made with a flat aluminum panel with the various layers just over 1 inch of distance; in this way we are able to make the entire volume of material work in a very efficient way. Vice versa this is an advantage for the very low heat losses during the non-work phases; in conditions of installations inside the buildings, the temperatures can be maintained for several days."

Q: If faster heat transfer is required, do you envision a redesign of the heat exchanger or a modification of the PCM to meet the demand of the energy transfer?

A: "As manufacturer, we can customize the heat exchanger dimensions and shape in order to achieve our goals, but as always in the industrial scalability, the quantities are mandatory for a good price. We designed a single heat exchanger dimension and multiply it in order to be able to produce the different storage capacities and realize a complete modular range. The transfer of energy can be however accelerated by increasing the flow rate of the fluid and the delta T between the fluid and the melting point, of course there is always a limit to this possibility. There are still studies around this point that need to be better understood."

Q: Would implementing several PCMs of different melting temperatures aid in the overall performance of the TES?

A: "Let's say that we expect a slight drop in performance at lower temperatures, but we don't have many other tests to give you a more general opinion."

Q: How is the PCM temperature measured throughout the entire storage to provide input to the PCDCube? Since the melting/solidification of PCM is not a homogenous process, are multiple measurements necessary to get a realistic status of the PCM?

A: "In the documents that we have published, we do not specify that we have installed two temperature probes, one in the center and another one near the walls and it is evident that, when the final phase of the  discharge of the PCM approaches, the perimeter probe shows a decrease of more sudden temperature than the central one. We, however, assume that the fact of having installed our thermal battery outside the building in a very cold climate, has exaggerated the heat loss despite the low heat transmission."

Q: Have you considered other PCM suppliers/products, since many are located in Europe and the RAL quality organization is based there?

A: "This is a possibility, at least for the distribution of our products in Europe and Asia. Currently we try to separate the supply of the case with exchangers (that we manufacture) from the PCM with direct purchase of the client from the supplier, especially in the larger units."

Q: What is the customer value proposition for this product? What is the expected return on investment/payback period?

A: "This is a $1 million question; the proposal is certainly into the growing wave of the storage market, even the electrical ones for PV systems. (A Tesla Powerwall is cool but not economically advantageous if you don’t pay attention at the payback that is higher than the life of the battery). The best value proposition is to separate production from the consumption of the energy and take advantage of renewable energies which, unfortunately, are linked to the day / night cycle and the outdoor temperature conditions. We see perfect the combination HP + Thermal Battery because we can concentrate the HP working hours during the best outdoor conditions that, for many reasons, are affecting and reducing the performances.  Furthermore, we also see a large market in the use of these thermal batteries in all these existing systems which are undersized or which, due to specific situations of changing use of the building, are no longer able to provide the necessary heating or cooling to the whole plant. About the ROI, this really varies a lot country by country because the cost of the electricity has different rates and peak hours schedules. The industrial needs are sometimes much more interesting and attractive than the residential ones."

Q: What are your plans for a commercial rollout?

A: "We are completing the Italian sales force and are looking for international distributors. Our goal is to propose the range of products at an international level with distribution agreements for the case only with exchangers; it will obviously be our responsibility to direct the partner to some reliable and high-quality PCM manufacturers. Obviously, those who will quickly give us the opportunity to build pilot plants, demonstrating the technology, will have an advantage in introducing them into the market and in the exclusivity of the contractual relationship."

Research roundup: Hysteresis; reflective roof coating; optimizing energy balance of nearly zero energy buildings; more

Ben Welter - Monday, August 31, 2020

From Journal of Molecular Liquids:

The research progress on phase change hysteresis affecting the thermal characteristics of PCMs: A review

From Journal of Building Engineering:

Thermal behavior of a phase change material in a building roof with and without reflective coating in a warm humid zone

From Renewable Energy:

A comprehensive study on thermal storage characteristics of nano-CeO2 embedded phase change material and its influence on the performance of evacuated tube solar water heater

From Sustainable Cities and Society:

Numerical analysis of phase change materials for optimizing the energy balance of a nearly zero energy building

From Journal of Energy Storage:

Multi-objective optimization of cooling and heating loads in residential buildings integrated with phase change materials using the artificial neural network and genetic algorithm
Assessing corrosive behaviour of commercial phase change materials in the 21–25 ºC temperature range
Exergy and economic analyses of nanoparticle-enriched phase change material in an air heat exchanger for cooling of residential buildings
Experimental and numerical investigation on enhancing heat transfer performance of a phase change thermal storage tank
The effect of ultraviolet coating on containment and fire hazards of phase change materials impregnated wood structure

From Energy Conversion and Management:

Application of granular materials for void space reduction within packed bed thermal energy storage system filled with macro-encapsulated phase change materials

From Chemical Engineering Journal:

Simultaneous solar-thermal energy harvesting and storage via shape stabilized salt hydrate phase change material

From Solar Energy:

Characterization and cooling effect of a novel cement-based composite phase change material
Effect of polymer-derived silicon carbonitride on thermal performances of polyethylene glycol based composite phase change materials

From Case Studies in Thermal Engineering:

Effect of porosity and pore density of copper foam on thermal performance of the paraffin-copper foam composite Phase-Change Material

From Renewable and Sustainable Energy Reviews:

A critical assessment on synergistic improvement in PCM based thermal batteries

From Journal of Energy Resources Technology:

Experimental Analysis of Salt Hydrate Latent Heat Thermal Energy Storage System With Porous Aluminum Fabric and Salt Hydrate as Phase Change Material With Enhanced Stability and Supercooling

From Energy Sources:

Experimental study on thermal management and performance improvement of solar PV panel cooling using form stable phase change material
Experimental investigation of thermal performance of indirect mode solar dryer with phase change material for banana slices

From Aalto University:

Experimental design and investigation on a thermal energy storage system using phase change materials [thesis]

From Journal of Applied Physics:

Development of eco-sustainable plasters with thermal energy storage capability

From Chemical Engineering Transactions:

Thermal Performance of Phase Change Material Wallboard with Typical Structure: Artificial Controlled Condition Experimental Investigation

From Materials Research Express:

Fabrication of thermal energy storage wood based on graphene aerogel encapsulated polyethylene glycol as phase change material
Preparation and characterization of acrylic resin encapsulated n-dodecanol microcapsule phase change material

From ACS Sustainable Chemical Engineering:

Synthesis and Characterization of Fatty Acid Amides from Commercial Vegetable Oils and Primary Alkyl Amines for Phase Change Material Applications

From Carbohydrate Polymers:

Fibrous form-stable phase change materials with high thermal conductivity fabricated by interfacial polyelectrolyte complex spinning

From Materials Today: Proceedings:

Effect of various phase change materials (paraffin wax/hydrogenated vegetable oil) packed in a fabricated shell and tube type heat exchanger

From Solar Energy Materials and Solar Cells:

Composite phase change materials with heat transfer self-enhancement for thermal energy storage
Novel network structural PEG/PAA/SiO2 composite phase change materials with strong shape stability for storing thermal energy

From International Journal of Refrigeration:

Improving the performance of household refrigerating appliances through the integration of phase change materials in the context of the new global refrigerator standard IEC 62552:2015

From Advances in Colloid and Interface Science:

Nanoencapsulation of phase change materials (PCMs) and their applications in various fields for energy storage and management

From Building and Environment:

Space heating performance of novel ventilated mortar blocks integrated with phase change material for floor heating

From Energy:

A promising form-stable phase change material composed of C/SiO2 aerogel and palmitic acid with large latent heat as short-term thermal insulation

From Journal of Cleaner Production:

Enhanced thermal storage capacity of paraffin/diatomite composite using oleophobic modification

From International Conference on Renewable Energies for Developing Countries:

Storage efficiency of paraffin-LDPE-MWCNT phase change material for industrial building applications

Research roundup: Polythioether-based PCMS; alginate encapsulation; temperature stresses in concrete pavement; more

Ben Welter - Friday, May 08, 2020

From European Polymer Journal:

Extremely fast synthesis of polythioether based phase change materials (PCMs) for thermal energy storage

From Journal of Building Engineering:

Thermal behavior analysis of hollow bricks filled with phase-change material (PCM)

From Energies:

FEM Applied to Building Physics: Modeling Solar Radiation and Heat Transfer of PCM Enhanced Test Cells

From Iranian Polymer Journal:

Encapsulation of phase change materials with alginate modified by nanostructured sodium carbonate and silicate

From Energy & Fuels:

Aluminium ammonium sulfate dodecahydrate with multiple additives as composite phase change materials for thermal energy storage

From Materials Today: Proceedings:

Evaluation and reduction of temperature stresses in concrete pavement by using phase changing material
Optimization of Heat Energy Based on Phase Change Materials used in Solar Collector using Taguchi Method
Experimental and Theoretical Investigations on Thermal Conductivity of the Paraffin Wax using CuO Nanoparticles

From Journal of Energy Storage:

Novel synthesis of silica coated palmitic acid nanocapsules for thermal energy storage
Recent progress in phase change materials storage containers: Geometries, design considerations and heat transfer improvement methods
Effect of phase separation and supercooling on the storage capacity in a commercial latent heat thermal energy storage: Experimental cycling of a salt hydrate PCM
Energy efficiency optimization of the waste heat recovery system with embedded phase change materials in greenhouses: A thermo-economic-environmental study
Characterization of innovative mortars with direct incorporation of phase change materials

From Applied Thermal Engineering:

A trade study of a phase change system in a stratospheric airship based on a triple gasbag concept
Experimental evaluation of structural insulated panels outfitted with phase change materials
Lattice Boltzmann simulation of melting heat transfer in a composite phase change material

From Geothermics:

Parametric modeling and simulation of low temperature energy storage for cold-climate multi-family residences using a geothermal heat pump system with integrated phase change material storage tank

From Energy:

Multi-level uncertainty optimisation on phase change materials integrated renewable systems with hybrid ventilations and active cooling
A novel solar thermal system combining with active phase-change material heat storage wall (STS-APHSW): Dynamic model, validation and thermal performance

From Advances in Energy Research:

Theoretical Modeling of Phase Change Material-Based Space Heating Using Solar Energy

From Chemical Engineering Journal:

High latent heat and recyclable form-stable phase change materials prepared via a facile self-template method

From Composites Part B: Engineering:

In situ one-step construction of monolithic silica aerogel-based composite phase change materials for thermal protection

From Solar Energy:

Effects of external insulation component on thermal performance of a Trombe wall with phase change materials

From Journal of Architectural Engineering:

Experimental and Numerical Thermal Properties Investigation of Cement-Based Materials Modified with PCM for Building Construction Use

From Energy Conversion and Management:

Experimental and numerical study on the thermal performance of ventilated roof composed with multiple phase change material (VR-MPCM)

From Construction and Building Materials:

Multi-scale analysis on thermal properties of cement-based materials containing micro-encapsulated phase change materials

From Applied Energy:

D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability
Novel bio-based phase change materials with high enthalpy for thermal energy storage

From Materials Today Energy:

A detailed review on heat transfer rate, supercooling, thermal stability and reliability of nanoparticle dispersed organic phase change material for low-temperature applications

From International Journal of Thermal Sciences:

Experimental study and assessment of high-tech thermal energy storing radiant floor heating system with latent heat storage materials

From Advanced Powder Technology:

Paraffin core-polymer shell micro-encapsulated phase change materials and expanded graphite particles as an enhanced energy storage medium in heat exchangers

PCM briefing: EnergyNest is finalist for startup award; Croda website offers live chat

Ben Welter - Tuesday, March 24, 2020

EnergyNest is one of 15 start-ups nominated as finalists of the Start Up Energy Transition Award 2020. EnergyNest's thermal battery consists of steel cassettes with pipes encased in a special type of concrete. The Norwegian company announced earlier this year that an EnergyNest battery with a capacity of 6-8 MWh would be installed at a brick manufacturing plant in Austria.

• "T-History Simplified: Combining a Universal Standard with an IoT Strategy," presented by Madison Hammerberg, product development engineering manager at CAVU Group, will be among the presentations at the Advancements in Thermal Management conference in Denver, Aug. 6-7, 2020.

Croda now offers live chat on its CrodaTherm website, www.crodatherm.com. The "Chat with a Croda Expert" feature is designed to provide visitors with "instant support."

Terrafore Technologies of Minneapolis is one of 13 companies to be awarded a Launch Minnesota Innovation Grant from the state's Department of Employment and Economic Development. The grants total $344,000; the amounts of individual grants were not disclosed. Terrafore is developing thermal energy storage to provide dispatchable solar power generation to the grid.

RayGen Resources Pty. Ltd. of Australia has been awarded $3 million AUD toward a feasibility study for a 4 MW “solar hydro” power plant in Victoria. The money will come from the Australian Renewable Energy Agency. RayGen's system extracts heat from solar panels and stores it in a water reservoir acting as a heat store. The hot reservoir is paired with cold reservoir chilled by electricity from the solar panels and the grid. The temperature difference powers an Organic Rankine Cycle engine to generate electricity with a round-trip efficiency of 70%.

• The Swedish thermal energy storage company Azelio has completed the installation of "a system that will store solar energy from what is claimed to be the world’s largest concentrated solar power plant project," Energy Storage Journal reports. "The complex [in Morocco] is 2,500 hectares in size, and solar panels cover 1,000 square metres — which means it could potentially harvest a total of 2.6GW a year." The system uses recycled aluminum as the heat storage material.

Sunamp Ltd. of Edinburgh, Scotland, has signed a memo of understanding with Ripple Energy, a company that enables customers to part-own large-scale wind farms to power their homes. Under the agreement, Ripple will offer its customers Sunamp heat batteries, which use a specially formulated phase change material to store large amounts of energy from renewable and other sources and release it as heat to deliver hot water and space heating as needed.

Research roundup: Corn oil PCM in frozen food cooling machine; portable solar box cooker; expanded graphite/1-octadecanol composite; more

Ben Welter - Saturday, March 21, 2020

From Journal of Physics:

Corn oil phase change material (PCM) in frozen food cooling machine to improve energy efficiency

From Materials Today: Proceedings:

Investigating thermal properties of Nanoparticle Dispersed Paraffin (NDP) as phase change material for thermal energy storage

From Energy:

Effects of fluctuating thermal sources on a shell-and-tube latent thermal energy storage during charging process

From Solar Energy:

Design, realization, and tests of a portable solar box cooker coupled with an erythritol-based PCM thermal energy storage
Diversiform microstructure silicon carbides stabilized stearic acid as composite phase change materials

From International Journal of Thermofluids:

Investigating the performance of a thermal energy storage unit with paraffin as phase change material, targeting buildings’ cooling needs: an experimental approach

From Journal of Cleaner Production:

Energy and exergy analysis of wind farm integrated with compressed air energy storage using multi-stage phase change material

From Powder Technology:

Effect of nano-SiC on thermal properties of expanded graphite/1-octadecanol composite materials for thermal energy storage

From Journal of Energy Storage:

A multi-objective optimal design method for thermal energy storage systems with PCM: A case study for outdoor swimming pool heating application
Reducing PV module temperature with radiation based PV module incorporating composite phase change material
Numerical investigation on the effect of fin design on the melting of phase change material in a horizontal shell and tube thermal energy storage

From Journal of Thermal Analysis and Calorimetry:

Characterization of form-stable phase-change material for solar photovoltaic cooling

From International Journal of Thermophysics:

Thermophysical Properties of a Novel Nanoencapsulated Phase Change Material

From International Journal of Heat and Mass Transfer:

Lattice Boltzmann simulation of forced convection melting of a composite phase change material with heat dissipation through an open-ended channel
High power density thermal energy storage using additively manufactured heat exchangers and phase change material

From Energies:

Evaluation of the State of Charge of a Solid/Liquid Phase Change Material in a Thermal Energy Storage Tank [pdf]
Novel Simulation Algorithm for Modeling the Hysteresis of Phase Change Materials [pdf]

From Energy & Fuels:

Novel shape-stabilized phase change materials based on paraffin/EPDM@graphene with high thermal conductivity and low leakage rate

From Polymers and Polymer Composites:

Regulating phase-change temperatures of form-stable phase-change ternary composite fibrous membranes consisting of polystyrene nanofibers and fatty acid eutectics via co-electrospinning method

From Applied Energy:

A design protocol for enhanced discharge exergy in phase change material heat battery
Fabrication of heat storage pellets composed of microencapsulated phase change material for high-temperature applications
A high-thermal-conductivity, high-durability phase-change composite using a carbon fibre sheet as a supporting matrix

From Journal of Building Engineering:

Preparation and characterization of metal-organic framework /microencapsulated phase change material composites for indoor hygrothermal control

From Indoor and Built Environment:

Numerical and experimental investigation on dynamic thermal performance of floor heating system with phase change material for thermal storage

From Applied Clay Science:

A triply synergistic method for palygorskite activation to effectively impregnate phase change materials (PCMs) for thermal energy storage

From Chemical Engineering Journal:

Lignin-fatty acid hybrid nanocapsules for scalable thermal energy storage in phase-change materials

From Construction and Building Materials:

Phase change materials for pavement applications: A review

From Carbohydrate Polymers:

Shape-stabilization of polyethylene glycol phase change materials with chitin nanofibers for applications in “smart” windows

Cubesat propulsion concept wins $225,000 National Science Foundation grant

Ben Welter - Friday, February 14, 2020

A Cubesat propulsion system that uses phase change material to store solar thermal energy for use when needed has been awarded a $225,000 National Science Foundation SBIR grant. The ThermaSat concept, developed by Howe Industries of Tempe, Ariz., is designed to provide propulsion for a typical 15kg cubcubesat for 10 years.

Cubesats are tiny satellites — weighing as little as 200 grams — that orbit close to Earth’s atmosphere. They are cheaper to develop and launch than larger satellites. Cubesats have a wide range of purposes, including the collection of mapping and weather data. More than 1,100 have been successfully deployed.

Troy Howe, owner of Howe Industries, answered questions about the ThermaSat propulsion system.

Q: How long has your company been working on the concept?

A: "We have been working on this topic for only about a year in preparation for our NSF proposal, but have experience with optical systems and phase change materials going back about five years."

Q: Can you briefly describe how the system works?

A: "The ThermaSat works by heating liquid water propellant to high temperature steam using incident sunlight. Normally, it is difficult to reach high enough temperatures to use water as propellant, but our optical filtration system is designed to reject long wavelengths of light and only transmit short wavelengths- similar to the greenhouse effect. The phase change materials in the thermal capacitor store the solar energy over a period of hours and then heat the propellant during a 'burn' phase.

ThermaSat cutaway drawing"The PCM will be distributed throughout a graphite matrix in the form of small beads. Flow channels will run axially down the length of the cylinder for the propellant to pass through. The design is based loosely on the old NERVA fuel elements from the nuclear rocket program in the 1970s, with the UC kernels being replaced with our PCM. The drawing here shows a cutaway of the thermal capacitor surrounded by the optical system.

"The system is very conceptual at this point and has not been tested, although the propulsion characteristics are well understood. Our task at this point is to show that the optical system works as predicted and can reach the desired temperatures. Phase II will address the effects of a vacuum environment on a prototype."

Q: What type of PCM is used?

A: "We chose a salt (80LiOH+20LiF) as our PCM, it melts at 700K and has a latent heat of fusion of 1163 J/g. The material was selected based on a study performed by NASA in 1986 on space energy storage. The paper was called 'Technology for Brayton-Cycle Space Powerplants Using Solar and Nuclear Energy' by Robert English.""

Q: How much PCM would be used in a system powering a typical Cubesat?

A: "The standard design includes 0.62 kg of PCM. "

Q: Are you working with any Cubesat manufacturers at this point?

A: "We received letters of interest from Pumpkin Space Systems, Aster Labs, and Arizona State University. They all expressed interest in having a safe and reliable Cubesat propulsion system but we have not formally formed collaboration with any manufacturers at this point.”

Q: How will you use the NSF SBIR grant?

A: "Our goals for this topic include demonstrating the optical system in a lab bench test, fabricating photonic crystals, and performing computational analysis on the thermal, structural, and propulsion systems."

Q: What's the next major step in commercializing the system?

A: "Our commercialization strategy right now is to build a functioning prototype and demonstrate operation on earth. From that point we will aim to do a flight test which performs a set of orbital maneuvers and successfully de-orbits itself. From there we will work with Cubesat manufacturers to move forward."

Q: What excites you most about this project?

A: "We are excited about how near term and effective this technology will be for the upcoming Cubesat revolution. We hope to provide a safe, reliable, and effective propulsion solution that can be used with thousands of different satellites and drastically increase the performance of new technologies in space in the timeframe of just a few years.”

Research roundup: Carbonized waste tires; cetyl palmitate/nickel foam; hydrated salt corrosion assessment; more

Ben Welter - Tuesday, January 14, 2020

From Waste Management:

Evaluation of carbonized waste tire for development of novel shape stabilized composite phase change material for thermal energy storage

From Journal of Energy Storage:

Development of polyurethane foam incorporating phase change material for thermal energy storage
Facile synthesis and thermal performance of cetyl palmitate/nickel foam composite phase change materials for thermal energy storage
Optimal sizing design and operation of electrical and thermal energy storage systems in smart buildings

From Energy Conversion and Management:

Numerical investigation of the effects of the nano-enhanced phase change materials on the thermal and electrical performance of hybrid PV/thermal systems
Thermal storage and thermal management properties of a novel ventilated mortar block integrated with phase change material for floor heating: an experimental study

From Applied Energy:

Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage

From Renewable Energy:

Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems
Experimental study on latent thermal energy storage system with gradient porosity copper foam for mid-temperature solar energy application
Selection of a phase change material and its thickness for application in walls of buildings for solar-assisted steam curing of precast concrete
Experimental assessment of Phase Change Material (PCM) embedded bricks for passive conditioning in buildings

From Applied Thermal Engineering:

Analysis of energy retrofit system using latent heat storage materials applied to residential buildings considering climate impacts
Experimental and numerical simulation of phase change process for paraffin/expanded graphite/ethylene-vinyl acetate ternary composite
An experimental investigation on the evaporation of polystyrene encapsulated phase change composite material based nanofluids

From Solar Energy Materials and Solar Cells:

Lightweight mesoporous carbon fibers with interconnected graphitic walls for supports of form-stable phase change materials with enhanced thermal conductivity

From Energies:

The Effects of Fin Parameters on the Solidification of PCMs in a Fin-Enhanced Thermal Energy Storage System

From Journal of Materials Science:

Graphene aerogel-based phase changing composites for thermal energy storage systems

From Journal of Mechanical Science and Technology:

A study on development of the thermal storage type plate heat exchanger including PCM layer

From Journal of Power Sources:

Delayed liquid cooling strategy with phase change material to achieve high temperature uniformity of Li-ion battery under high-rate discharge

From Scientific Reports:

Modification of asphalt mixtures for cold regions using microencapsulated phase change materials

From ASES National Solar Conference:

A Study on the Thermal Energy Storage System Using Multiple PCMs [pdf]

From Molecules:

Assessment of Thermal Performance of Textile Materials Modified with PCM Microcapsules Using Combination of DSC and Infrared Thermography Methods

From Energy and Buildings:

Experimental study on thermal performance of a mobilized thermal energy storage system: A case study of hydrated salt latent heat storage

From Chemical Engineering Journal:

Shape-stabilized hydrated salt/paraffin composite phase change materials for advanced thermal energy storage and management

From International Journal of Heat and Mass Transfer:

A conjugate heat transfer model for unconstrained melting of macroencapsulated phase change materials subjected to external convection

PCM briefing: Advanced Building Skins presentations are online; Ecozen raises $6 million

Ben Welter - Monday, December 16, 2019

• Presentations given at the 14th Conference on Advanced Building Skins in Switzerland in October are available via download for 80 euros. Among the topics: "Thermal performance of engineered wood flooring impregnated with phase-change materials," Damien Mathis, University LAVAL, Fontenay-sous-Bois, France; "Thermal comfort modelling and its impact on building energy performance," Vikram Sami, Olson Kundig, Seattle, Wash.; and "Integrated solar electric/thermal cooling system with storage," Mohannad Bayoumi, King Abdulaziz University, Jeddah, Saudi Arabia.

Loughborough University researchers have been awarded funding to help with the design and development of a four-wheeled electric vehicle for research, teaching and outreach in India. Engineers at Vellore Institute of Technology and PSG College of Technology, both located in Tamil Nadu, will work with Loughborough researchers to explore the use of phase change material and other technologies to manage battery heat. The high ambient temperatures in south India and similar climates can significantly reduce battery life in electric vehicles.  

• Energy storage specialist 1414 Degrees has announced plans to acquire SolarReserve Australia II, which owns the Aurora Solar Energy Project in South Australia and two solar sites in New South Wales. The Adelaide, Australia, company plans to use the Aurora site to build a 400 MW solar farm with thermal storage capacity of several thousand megawatt hours. The technology stores electricity as thermal energy by heating and melting containers full of silicon.

• Agritech startup Ecozen of Pune, India, which makes portable solar cold rooms for use on small farms, has raised a total of $6 million to fuel its growth phase. The cold rooms feature a PCM-equipped thermal storage unit that can store power for more than 36 hours in case of cloudy or rainy weather.  

Advanced Cooling Technologies Inc. of Lancaster, Penn., is seeking qualified research and development engineers at various experience and education levels to work on space, defense and energy-related applications. 

• Andreas Hauer, head of the energy storage department at ZAE Bayern (the Bavarian Center for Applied Energy Research) has joined the board of directors at the International Solar Energy Society.

Research roundup: Passive cooling in buildings; honeycomb carbon fibers; leak-free aggregates; more

Ben Welter - Monday, October 14, 2019

From Applied Energy:

Passive cooling through phase change materials in buildings. A critical study of implementation alternatives

From Applied Thermal Engineering:

Honeycomb carbon fibers strengthened composite phase change materials for superior thermal energy storage

From e-Polymers:

Fabrication and characterization of conductive microcapsule containing phase change material

From Construction and Building Materials:

Preparation and characterization of nano-SiO2/paraffin/PE wax composite shell microcapsules containing TDI for self-healing of cementitious materials
Development of leak-free phase change material aggregates
Behavior of cementitious mortars with direct incorporation of non-encapsulated phase change material after severe temperature exposure

From Advanced Functional Materials:

Engineering the Thermal Conductivity of Functional Phase‐Change Materials for Heat Energy Conversion, Storage, and Utilization

From Journal of Energy Storage:

A numerical investigation of the effects of metal foam characteristics and heating/cooling conditions on the phase change kinetic of phase change materials embedded in metal foam
Applications of combined/hybrid use of heat pipe and phase change materials in energy storage and cooling systems: A recent review
Innovative composite sorbent for thermal energy storage based on a SrBr2·6H2O filled silicone composite foam

From ACS Applied Nano Materials:

Concentrated Ag Nanoparticles in Dodecane as Phase Change Materials for Thermal Energy Storage

From Materials Research Express:

Preparation of 1-dodecanol microcapsules with cellulose nanofibers-modified melamine-formaldehyde resin as a potential phase change material

From IOP Conference Series: Earth and Environmental Science:

Optimisation of Parameters in Thermal Energy Storage System by Enhancing Heat Transfer in Phase Change Material

From International Journal of Heat and Mass Transfer:

Thermal transport properties at interface of fatty acid esters enhanced with carbon-based nanoadditives

From Journal of Solar Energy Engineering:

Using a Novel Phase Change Material-Based Cooling Tower for a Photovoltaic Module Cooling

From Solar Energy:

Experimental investigation on micro-scale phase change material based on sodium acetate trihydrate for thermal storage

From RSC Advances:

A novel forced separation method for the preparation of paraffin with excellent phase changes

From Energy Conversion and Management:

Experimental characterisation of a novel thermal energy storage based on open-cell copper foams immersed in organic phase change material

Research roundup: Mesoporous silica; nanoencapsulation of oleic acid PCM; flexible crosslinking; more

Ben Welter - Friday, September 20, 2019

From International Journal of Energy Research:

Facile functionalized mesoporous silica using biomimetic method as new matrix for preparation of shape‐stabilized phase‐change material with improved enthalpy
Binary mixtures of fatty alcohols and fatty acid esters as novel solid‐liquid phase change materials

From Journal of Applied Polymer Science:

Phase change material with flexible crosslinking for thermal energy storage

From Journal of Thermal Analysis and Calorimetry:

Nanoencapsulation of oleic acid phase change material with Ag2O nanoparticles-based urea formaldehyde shell for building thermal energy storage

From Renewable Energy:

Enhanced properties of diatomite-based composite phase change materials for thermal energy storage

From Energy:

Perspectives for short-term thermal energy storage using salt hydrates for building heating
Design and construction of mesoporous silica/n-eicosane phase-change nanocomposites for supercooling depression and heat transfer enhancement
Numerical investigations on performance of phase change material Trombe wall in building

From Energy and Buildings:

Potential of energy flexible buildings: evaluation of DSM strategies using building thermal mass
Numerical analysis in a full-scale thermal energy storage tank with dual PCM capsules

From Applied Thermal Engineering:

Experimental determination and fractal modeling of the effective thermal conductivity of autoclave aerated concrete (AAC) impregnated with paraffin for improved thermal storage performance
Preparation and characterization of new nano-particle mixed as thermal storage material
Numerical investigation on integrated thermal management for a lithium-ion battery module with a composite phase change material and liquid cooling

From Chemical Engineering Journal:

Fatty Amines/Graphene Sponge Form-Stable Phase Change Material Composites with Exceptionally High Loading Rates and Energy Density for Thermal Energy Storage

From MATEC Web of Conferences:

Thermal conductivity of aerated concrete (AC) composites containing micro-encapsulated phase change materials [pdf]
Overheating mitigation in buildings: a computational exploration of the potential of phase change materials [pdf]

From Solar Energy:

Experimental study on the thermal performance of capric acid-myristyl alcohol/expanded perlite composite phase change materials for thermal energy storage

From Solar Energy Materials and Solar Cells:

Graphitization as efficient inhibitor of the carbon steel corrosion by molten binary nitrate salt for thermal energy storage at concentrated solar power
A strategy for designing microencapsulated composite phase change thermal storage materials with tunable melting temperature

From Institute of Electronics and Information Engineers 2019 Summer Conference:

Thermal Management System in Electric vehicle Battery Pack Using Phase Change Material

From Materials Chemistry and Physics:

Preparation and thermal properties of n-eicosane/nano-SiO2/expanded graphite composite phase-change material for thermal energy storage

From Sustainable Cities and Society:

Simulative optimization on energy saving performance of phase change panels with different phase transition temperatures

From Thermochimica Acta:

The stability and thermophysical properties of a thermal fluid containing surface-functionalized nanoencapsulated PCM

From International Journal of Heat and Mass Transfer:

Functionalized mesoporous silica as matrix for shape-stabilized phase change materials

From Applied Energy:

Synthesis and characterization of microencapsulated sodium sulfate decahydrate as phase change energy storage materials

From Energy Conversion and Management:

Prototype latent heat storage system with aluminum-silicon as a phase change material and a Stirling engine for electricity generation

From Journal of Solar Energy Engineering:

Experimental Investigation and Numerical Modeling of Room Temperature Control in Buildings by the Implementation of Phase Change Material in the Roof
Suitability Assessment and Experimental Characterization of Phase Change Materials for Energy Conservation in Indian Buildings