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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Cascaded cold storage unit with multiple PCMs; evolution of global heat transfer coefficient; more

Ben Welter - Tuesday, November 07, 2017

Evolution of global heat transfer coefficient on PCM energy storage cycles [Energy Procedia]

Thermal performance analysis of a cascaded cold storage unit using multiple PCMs [Energy]

An experimental investigation of discharge/solidification cycle of paraffin in novel shell and tube with longitudinal fins based latent heat storage system [Energy Conversion and Management]

An alternative approach for assessing the benefit of phase change materials in solar domestic hot water systems [Solar Energy]

Organic-inorganic hybrid shell microencapsulated phase change materials prepared from SiO2/TiC-stabilized pickering emulsion polymerization [Solar Energy Materials and Solar Cells]

Preparation of phase change material emulsions with good stability and little supercooling by using a mixed polymeric emulsifier for thermal energy storage [Solar Energy Materials and Solar Cells]

Optimal design of PCM thermal storage tank and its application for winter available open-air swimming pool [Applied Energy]

Research roundup: TES in Toronto high-rises; rotary desiccant cooling systems; natural convection characterization; more

Ben Welter - Tuesday, October 24, 2017

Experimental investigation of latent thermal energy storage in high-rise residential buildings in Toronto [Energy Procedia]

Study on the Performance of Heat Storage and Heat Release of Water Storage Tank with PCMs [Energy and Buildings]

Design of effective fins for fast PCM melting and solidification in shell-and-tube latent heat thermal energy storage through topology optimization [Applied Energy]

Integrating photovoltaic thermal collectors and thermal energy storage systems using phase change materials with rotary desiccant cooling systems [Sustainable Cities and Society]

Development of thermal energy storage cementitious composites (TESC) containing a novel paraffin/hydrophobic expanded perlite composite phase change material [Solar Energy]

Experimental analysis of solar photovoltaic unit integrated with free cool thermal energy storage system [Solar Energy]

Natural convection characterization during melting of phase change materials: Development of a simplified front tracking method [Solar Energy]

Thermal behavior of latent thermal energy storage unit using two phase change materials: Effects of HTF inlet temperature [Case Studies in Thermal Engineering]

Experimental Investigation of a New Passive Thermal Management System for a Li-Ion Battery Pack Using Phase Change Composite Material [Electrochimica Acta]

Research roundup: Carbon-based nanoenhanced PCM; copper-powder-sintered frame/paraffin form stable PCM; thermoelectric harvester; more

Ben Welter - Monday, October 23, 2017

From Renewable and Sustainable Energy Reviews:

Experimental set-up for testing active and passive systems for energy savings in buildings – Lessons learnt
Review on thermal conductivity enhancement, thermal properties and applications of phase change materials in thermal energy storage

From Journal of Energy Storage:

Preparation and thermal performance of methyl palmitate and lauric acid eutectic mixture as phase change material (PCM)

From Applied Thermal Engineering:

A novel heat transfer model of a phase change material using in solar power plant

From Energy Procedia:

Experimental investigation of flow rate impact on thermal accumulation system with PCM

From Energy Conversion and Management:

Experimental and numerical investigation on the performance of carbon-based nanoenhanced phase change materials for thermal management applications

From International Journal of Thermal Sciences:

Thermal management of lithium ion batteries using graphene coated nickel foam saturated with phase change materials 

From Applied Energy:

Preparation of novel copper-powder-sintered frame/paraffin form-stable phase change materials with extremely high thermal conductivity
Experimental investigations of charging/melting cycles of paraffin in a novel shell and tube with longitudinal fins based heat storage design solution for domestic and industrial applications
A novel thermoelectric harvester based on high-performance phase change material for space application

From Sustainable Cities and Society:

Experimental Investigation of Phase Change Materials for Insulation of Residential Buildings
A comparison of battery and phase change coolth storage in a PV cooling system under different climates

Research roundup: Silk hydrogel as packaging material; interfacial polymerization; ecodesign of cladding system with PCM; more

Ben Welter - Wednesday, September 27, 2017

Silk hydrogel illustration

Temperature buffering capacity of silk hydrogel: A useful packaging material [Materials Letters]

Preparation and Characterization of Cross-linked Polyurethane Shell Microencapsulated Phase Change Materials by Interfacial Polymerization [Materials Letters]

Environmental and spatial assessment for the ecodesign of a cladding system with embedded Phase Change Materials [Energy and Buildings]

Novel shapeable phase change material (PCM) composites for thermal energy storage (TES) applications [Solar Energy Materials and Solar Cells]

Novel approaches and recent developments on potential applications of phase change materials in solar energy [Renewable and Sustainable Energy Reviews]

Study of thermal conductive enhancement mechanism and selection criteria of carbon-additive for composite phase change materials [International Journal of Heat and Mass Transfer]

Natural aging of shape stabilized phase change materials based on paraffin wax [Polymer Testing]

Multiphase transport phenomena in composite phase change materials for thermal energy storage [13th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics]

Numerical investigation of cylindrical and spherical encapsulated thermal energy storage system with phase change materials [Transylvania Review]

Temperature Dependence of the Enthalpy of Alkanes and Related Phase Change Materials [Enthalpy and Internal Energy: Liquids, Solutions and Vapours]

Heat transfer enhancement of phase change materials by fins under simultaneous charging and discharging [Energy Conversion and Management]

Paraffin-enhanced concrete shows promise in melting ice, snow

Ben Welter - Monday, September 25, 2017

PCM LWA video

Dr. Yaghoob Farnam has spent four years combining concrete and phase change material in various ways in a quest to develop a durable paving material that can melt ice and snow. 

Farnam, an assistant professor in Drexel University’s College of Engineering, has previously measured the effectiveness of paraffin oil and methyl laurate, materials that have relatively high heat storage capacity (about 130 to 170 joules per gram) and a suitable phase transformation temperature (about 2 to 3 degrees Celsius). Both showed promise when contained in plastic tubes embedded in concrete. But the paraffin oil proved to be far more effective than methyl laurate in concrete made of lightweight aggregate infused with the PCMs. Chemical reactions between the methyl laurate and materials in the cement rendered that PCM ineffective and also appeared to cause cracks in the concrete.

In his latest paper, published in Cement and Concrete Composites, Farnam's research team focused on paraffin oil. The team used concrete slabs to compare two methods of deploying the PCM. Steel pipes filled with paraffin and sealed with PVC caps were embedded in one slab. A second slab was made of porous lightweight aggregate infused with paraffin. A third slab, containing no paraffin, served as a reference point. Each slab was sealed in an insulated container and then covered with about 5 inches of shaved ice.

DrexelNow describes what happened in two tests:

"With temperatures inside the boxes held between 35-44 degrees Fahrenheit, both of the paraffin-treated slabs were able to completely melt the snow within the first 25 hours of testing, while the snow on the reference sample remained frozen. The slab with the paraffin-filled tubes melted the snow slightly faster than the one composed of paraffin-treated aggregate. Farnam suggests that this is because the paraffin inside the tubes is able to solidify more quickly — thus releasing its energy — because of the regular diameter of the pipes. While the diameter of the pores of the aggregate vary in size.

"But in the group’s second experiment, in which the ambient air temperature in the box was lowered to freezing before the snow was added, the paraffin-treated aggregate was more effective than the embedded pipes. This is because the capillary pore pressure delayed the freezing of the paraffin, thus allowing it to release its heat energy over a longer period of time." 

The research is of particular importance to the airline industry, which has a keen interest in finding cost-effective and environmentally friendly ways to clear runways of ice and snow. The Federal Aviation Administration has supported Farnam's work with nearly $500,000 in grants through its PEGASAS program.

Farnam says additional research is needed to better understand how the addition of PCM affects pavement durability, skid resistance and long-term stability.  

http://drexel.edu/now/archive/2017/September/self-melting-concrete-roads/

German researchers roll out PCM warming mats for greenhouse plants

Ben Welter - Tuesday, September 19, 2017

Researchers at the University of Zwickau's Institute for Textile and Leather Technologies are developing a latent heat storage mat that uses phase change material to increase plant root temperatures in cold seasons. 

Dr. Silke HessburgThe passive system, designed for use in greenhouses, requires no additional energy supply. Dr. Silke Hessberg, who is directing the research, says root climate control promotes plant growth efficiently.

"There are already various heating systems on the market, such as underfloor heating systems, hot water systems or electric and gas heaters," she says. "These are always cost-intensive heating systems, since energy must be actively supplied."

The Thuringian Institute of Textile and Plastics Research (TITK) is supporting the two-year project. TITK's Martin Geissenhöner identifies the PCM as paraffin. 

"We have different melting points. For the root project we use melting points between 5 and 42° C, specially 17° C," he says. "The PCM is encapsulated in a network polymer. It's like a sponge structure."

Research associate Nancy Schrader says the mats are placed on the soil surface. Work on the project began in May 2015 and is expected to conclude in December. 

Research roundup: Flexible PCMs with high thermal conductivity; treatment for exercise-induced muscle damage; more

Ben Welter - Thursday, August 31, 2017

Thermal sensitive flexible phase change materials with high thermal conductivity for thermal energy storage [Energy Conversion and Management]

The efficacy of cooling with phase change material for the treatment of exercise-induced muscle damage: pilot study [Journal of Sports Sciences]

Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide [Renewable Energy]

Structure and Thermal Performances of Paraffin/Diatomite Form-stable Phase Change Materials [Chinese Journal of Materials Research]

Research roundup: Carbonized rice; erythritol-xylitol; integrated double skin façade; paraffin-based TES system; more

Ben Welter - Wednesday, August 30, 2017

Form stable composite phase change materials from palmitic-lauric acid eutectic mixture and carbonized abandoned rice: preparation, characterization, and thermal conductivity enhancement [Energy and Buildings]

Mitigation against Crude Oil Wax Solidification using TES Fin [Chemical Engineering Research and Design]

Heat transfer analysis of an integrated double skin façade and phase change material blind system [Building and Environment]

Experimental Phase Diagram Study of the Binary Polyols System Erythritol-Xylitol [Solar Energy Materials and Solar Cells]

Study of Various Aspects of Phase Change Material During Solidification and Melting: A Review [pdf] [International Journal of Scientific Research in Science and Technology]

Development in Paraffin Based Thermal Storage System Through Shell and Tubes Heat Exchanger With Vertical Fins [ASME 2017 11th International Conference on Energy Sustainability]

Europe holds PCM market lead, but North America is gaining

Ben Welter - Monday, August 28, 2017

In terms of value, Europe held the largest share of the global PCM market last year, according to the research firm MarketsandMarkets. An executive summary of the research firm's June report, "Advanced PCM Market: Global Forecast to 2022," estimates Europe's share at 49.7 percent.

"The trend towards energy efficiency in the region, accompanied by the growing demand for green buildings, fuels the growth of the advanced PCM market in the region," the summary says. "In addition, the presence of mandatory building energy codes and the increasing demand for housing in Germany and the U.K. drive the demand for advanced PCM in the region."

But MarketsandMarkets projects that North America will be the fastest-growing market for advanced PCMs between 2017 and 2022, with a compound annual growth rate of nearly 21 percent. Analyst Sushmita Singh cites "stringent building energy codes," growth in the housing sector and rising demand for green buildings as key factors.

This MarketsandMarkets graphic shows 2016 market shares in terms of value and compound annual growth rates (CAGR) between 2017 and 2022:

Research roundup: HDPE spheres; erythritol-based composites; shape-stabilized PCM sheets; graphite foam; more

Ben Welter - Wednesday, August 23, 2017

High density polyethylene spheres with PCM for domestic hot water applications: Water tank and laboratory scale study [Journal of Energy Storage]

Numerical Simulation and Optimization of the Melting Process of Phase Change Material inside Horizontal Annulus [Energies]

Evaluation and comparison of erythritol-based composites with addition of expanded graphite and carbon nanotubes [Applied Energy]

Investigation of thermo-fluidic performance of phase change material slurry and energy transport characteristics [Applied Energy]

Numerical investigation of heat transfer performance of a rotating latent heat thermal energy storage [Applied Energy]

Application of shape-stabilized phase-change material sheets as thermal energy storage to reduce heating load in Japanese climate [Building and Environment]

Graphite foam as interpenetrating matrices for phase change paraffin wax: A candidate composite for low temperature thermal energy storage [Solar Energy Materials and Solar Cells]

Alkali polyphosphates as new potential materials for thermal energy storage [Solar Energy]

Magnesium phosphate cements formulated with low grade magnesium oxide incorporating phase change materials for thermal energy storage [Construction and Building Materials]

Numerical and experimental investigation of an insulation layer with phase change materials (PCMs) [Energy and Buildings]