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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

Two Entropy advisors, Dr. Mohammed Farid and Lucas B. Hyman, are pleased to take your questions about PCMs and thermal energy storage. Send your questions to bwelter@puretemp.com. We'll select the best and post the answers here each week.

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PCM briefing: Energy storage rebate falters in California Assembly; at Los Alamos lab, it's ice ice ice ice ice ice ice baby

Ben Welter - Tuesday, July 18, 2017

• The California Assembly has essentially killed a bill to create a long-term energy storage rebate. The bill, known as SB 700, had earlier cleared the state Senate. Last week's unexpected move pushes consideration of the rebate, which would have applied to a wide range of technologies, including thermal energy storage, into next year. 

"Ice Energy and others interested in energy storage for the residential market have closely followed and supported SB 700," said Ice Energy CEO Mike Hopkins. "The Duck Curve problem is serious and storage is the solution. SB 700 would have significantly accelerated the solution so the delay is disappointing to anyone who cares about replacing fossil fuels with renewables, lowering the cost of power, and improving grid reliability. In the meantime, Ice Energy will continue to work with utilities and utilize SGIP to deliver cost effective and reliable energy storage to the residential market."

• For the first time, scientists have recorded water freezing into a structure called Ice VII under extreme, controlled conditions in the lab, Science Alert reports. "These experiments with water are the first of their kind, allowing us to witness a fundamental disorder-to-order transition in one of the most abundant molecules in the Universe," says geophysicist Arianna Gleason of the Los Alamos National Laboratory in New Mexico.

• The Hohenstein Institute for Textile Innovation has developed a new method for measuring the cooling effect of intelligent textiles, a heat release tester called WATson. The institute's thermophysiological evaluation system "will compare the results of the WATson heat loss tester to data from experiments on subjects in a climate chamber under a range of ambient conditions," Advanced Textiles Source reports.   

• A team at the National Institute of Standards and Technology has submitted a precise new calculation of a key formula to redefine the kilogram based on a fundamental universal constant. 

• California startup Axiom Exergy, maker of behind-the-meter thermal energy storage systems, has an opening for a computational thermal systems engineer. Axiom announced a deal last week to collaborate with Hillphoenix, a manufacturer of refrigeration equipment used in U.S. supermarkets. The two companies plan to develop and market storage-enabled refrigeration platforms.

Research roundup: Transient energy storage; metal alloys for high-temperature applications; low-cost PCM emulsion; more

Ben Welter - Wednesday, July 12, 2017

Transient thermal energy storage in partitioned enclosures packed with microencapsulated phase change materials [International Communications in Heat and Mass Transfer]

Considerations for the use of metal alloys as phase change materials for high temperature applications [Solar Energy Materials and Solar Cells]

Experimental analysis of a coiled stirred tank containing a low cost PCM emulsion as a thermal energy storage system [Energy]

Fabrication and characterization of novel shape-stabilized synergistic phase change materials based on PHDA/GO composites [Energy]

Fabrication of hard-shell microcapsules containing inorganic materials [International Journal of Refrigeration]

Renewable Energy and Energy Storage Systems [Energy]

Thermal Storage Capacity and Night Ventilation Performance of a Solar Chimney Combined with Different PCMs [International Journal of Photoenergy]

Preparation and characterizations of asphalt/lauric acid blends phase change materials for potential building materials [Construction and Building Materials]

Numerically Study the Performance of An Air—multiple PCMs unit for Free Cooling and Ventilation [Energy and Buildings]

Research roundup: Macro-packed fatty acid ester composites; selective laser sintering; more

Ben Welter - Tuesday, July 11, 2017

From Journal of Industrial and Engineering Chemistry:

Performance evaluation of macro-packed fatty acid ester composites using energy-efficient thermal storage systems

From Procedia Manufacturing:

Selective Laser Sintering of Phase Change Materials for Thermal Energy Storage Applications

From Applied Energy:

Synthesis and characterization of microencapsulated myristic acid–palmitic acid eutectic mixture as phase change material for thermal energy storage
Advances in thermal energy storage materials and their applications towards zero energy buildings: A critical review

From Solar Energy Materials and Solar Cells:

A new strategy for enhanced latent heat energy storage with microencapsulated phase change material saturated in metal foam
Preparation and characterization of hybrid nanocomposite embedded organic methyl ester as phase change material

From Renewable Energy:

Cutting copper fiber/paraffin composite phase change material discharging experimental study based on heat dissipation capability of Li-ion battery

From Lehigh University:

Numerical and Experimental Study of the Melting Process of a Phase Change Material in a Partically Filled Spherical Shell [thesis]

From IEEE Internet Computing:

Thermal Time Shifting: Decreasing Datacenter Cooling Costs with Phase Change Materials

From International Journal of Heat and Mass Transfer:

Numerical modeling of solid-liquid phase change in a closed 2D cavity with density change, elastic wall and natural convection

From Applied Thermal Engineering:

Evaluation of the suitability of different calorimetric methods to determine the enthalpy-temperature curve of granular PCM composites
Heat Transfer Enhancement during Freezing Process of Nano Phase Change Material (NPCM) In a Spherical Capsule
Numerical simulation on thermal characteristics of supercooled salt hydrate PCM for energy storage: Multiphase model

PCM briefing: Cleanergy lands CSP contract in China; ASHRAE extends global reach

Ben Welter - Monday, July 03, 2017

• Team Sky cyclists competing in this year's Tour de France are using Inuteq's Siku vest to cool down after each stage. The Dutch company's hybrid vest combines PCM and evaporative cooling technologies. Inuteq says it is supplying its cooling products to two other teams: Bahrain Merida and Cannondale Drapac.

Calmac, the New Jersey company whose thermal energy storage tanks help cool more than more than 4,500 buildings worldwide, including the corporate headquarters of JC Penney, Marriott and Google, was profiled in Inc. magazine last week.  

Ember Technologies' temperature-controlled mug is a finalist in the 2017 International Design Excellence Awards in the Kitchen & Accessories category. The winners will be announced Aug. 16 at the International Designers Society of America conference in Atlanta. 

Cleanergy AB of Sweden has signed an agreement to deploy a 200-MW concentrating solar energy project in China. A Cleanergy spokeswoman confirmed that phase change material will be used in the CSP project's thermal storage system but declined to provide details about the PCM. 

Midsize energy and chemical companies are among the least prepared for the disruption that technological innovation and other changes will bring, a new report from Capital One Commercial Bank says.

• A U.S. House appropriations subcommittee last week advanced a bill that would impose deep cuts in renewable energy and efficiency programs at the Department of Energy and eliminate the Advanced Research Projects Agency-Energy, ARPA-E.

ASHRAE has announced the formation of a new ASHRAE Region in Europe and strategic partnerships with two European organizations: the UK-based Chartered Institute of Building Services Engineers and the Belgium-based Federation of European Heating, Ventilation and Air-Conditioning Associations.

• PCM will be among the topics at the 3rd International Conference: Innovative Materials and Smart Technologies for Environmental Safety. The conference will take place Sept. 27-29 in Latvia. The student conference includes a lecture titled "Heat Transfer Enhancement in Phase-Change Materials" by Dr. Gennady Ziskind, professor of mechanical engineering at Ben-Gurion University of the Negev, Israel. 

BASF, Cargill, Procter & Gamble and the Deutsche Gesellschaft für Internationale Zusammenarbeit GmbH have joined together in a development partnership to help establish a sustainable certified and transparent supply chain of coconut oil in the Philippines and Indonesia.  

• New from Zion Market Research: "Temperature Controlled Packaging Market: Global Industry Analysis, Size, Share, Growth, Trends, and Forecasts 2016–2024"

Bio-Based World News reports that the biobased sector of Finland's economy is now worth 60 billion euros. About 60 percent of the sector is rooted in the country's forest industry. 

Research roundup: INPATH-TES Ph.D. program; waste-to-energy plants; EnergyPlus-based building model; more

Ben Welter - Thursday, June 29, 2017

INPATH-TES: Innovative pathways to PhD research in thermal energy storage [Sustainable and Renewable Energy Engineering]

Application of high temperature phase change materials for improved efficiency in waste-to-energy plants [Waste Management]

Experimental investigation and EnergyPlus-based model prediction of thermal behavior of building containing phase change material [Journal of Building Engineering]

Experimental Analysis of Graphite Dispersed Salt Hydrates based Phase Change Materials to Determine Enhancement in their Thermophysical Properties [pdf] [Journal of Chemical and Pharmaceutical Sciences]

Use of phase change materials during compressed air expansion for isothermal CAES plants [35th UIT Heat Transfer Conference]

Simulation of Melting Process of a Phase Change Material (PCM) using ANSYS (Fluent) [pdf] [International Research Journal of Engineering and Technology]

Cellulose/Paraffin Composite Fibers for Thermal Energy Storage and Temperature Regulation [IUMRS International Conference in Asia]

Enhanced Specific Heat Capacity of Binary Chloride Salt by Dissolving Magnesium for High-temperature Thermal Energy Storage and Transfer [Journal of Materials Chemistry A]

Research roundup: Graphite particle fillers; sodium nitrate microcapsules; domestic space heating in UK; more

Ben Welter - Tuesday, June 27, 2017

Effect of temperature and graphite particle fillers on thermal conductivity and viscosity of phase change material n-eicosane [International Journal of Heat and Mass Transfer]

Thermal stability of sodium nitrate microcapsules for high-temperature thermal energy storage [Solar Energy Materials and Solar Cells]

Phase change materials to meet domestic space heating demand in the UK - A numerical study [Journal of Fluid Flow, Heat and Mass Transfer]

Synthesis of three-dimensional graphene aerogel encapsulating n-octadecane for enhancing phase-change behavior and thermal conductivity [Journal of Materials Chemistry A]

A recyclable thermochromic elastic phase change oleogel for cold compress therapy [Applied Thermal Engineering]

Patent application: Temperature-staged TES enabling low thermal exergy loss

Ben Welter - Monday, June 26, 2017

U.S. patent application 20170179879 (applicant California Institute of Technology, Pasadena, Calif.):

"A structure comprising: a photovoltaic module; a reflux boiling chamber configured to store thermal energy, the reflux boiling chamber comprising a plurality of temperature staged thermal energy storage materials, each temperature staged thermal energy storage material comprising a porous phase change material and configured to operate at a different temperature range than other temperature staged thermal energy storage materials, the reflux boiling chamber further configured to contain a working fluid; a thermodynamic heat engine; and a solar concentrator configured to concentrate sunlight towards the photovoltaic module and the reflux boiling chamber, wherein the reflux boiling chamber is further configured to transfer the thermal energy to the thermodynamic heat engine through the working fluid."

http://www.freepatentsonline.com/20170179879.pdf

PCM briefing: Ice Energy signs Australian distribution deal; program posted for thermal management conference in Denver

Ben Welter - Monday, June 26, 2017

Ice Energy of Santa Barbara, Calif., has entered into an agreement calling for Apricus Australia to become the exclusive distributor for all Ice Energy products in Australia. Apricus will market and sell to utilities, businesses and residential customers and will be responsible for installation and service. 

The program has been posted for the 2017 Advancements in Thermal Management conference to be held in Denver Aug. 9-10. Mark Hartmann, CTO at Outlast Technologies, will give a presentation on "Thermal Runaway Prevention of Li-ion Batteries by Novel Thermal Management System." Greg Albright, vice president of business development at AllCell Technologies, will give a presentation on "Conductivity Enhanced Phase Change Materials for Transient Loads." 

• At this month's Techtextil North America trade show in Chicago, Alexium International said it was on track to ship more than 90,000 kilograms of its Alexicool PCM product in June. The company, based in Greer, S.C., and Perth, Australia, sells the product to mattress fabric producers. Alexium's share price rose 21 percent last week on the Australian Securities Exchange, to 62.5 cents AUS. 

Viking Cold Solutions of Houston has been named to Food Logistics magazine's list of Top Green Providers for 2017. The list recognizes companies whose products, services or leadership is enhancing sustainability in the food and beverage industry. Viking makes a PCM-based thermal battery system designed cut energy consumption cold storage warehouses. 

Entropy Solutions, maker of PureTemp phase change materials, was among the companies honored with a Eureka! Innovation Award at a reception last week. The Minneapolis/St. Paul Business Journal awards program recognizes "game-changing" Minnesota businesses in energy, manufacturing, media, product design, engineering and other categories.

Monodraught Ltd. has been accredited by the Chartered Institution of Building Services Engineers to deliver three new continuing professional development modules. One of the free courses explores the use of phase change materials in ventilation systems to reduce a building’s energy consumption and carbon footprint.  

Masdar Institute and the Massachusetts Institute of Technology have tested and validated what is touted as the world’s first direct absorption molten salt receiver for concentrated solar power. The single-tank thermal energy storage system has been operational for over two weeks at the Masdar Institute Solar Platform in Abu Dhabi, United Arab Emirates. The tank holds roughly 4 tons of molten salt, capable of reaching temperatures over 500 degrees Celsius.

• A study published in the journal Disaster Medicine and Public Health Preparedness highlights the importance of cooling vests for health care workers wearing personal protective equipment in hot, humid environments. Study participants wearing vests fitted with ice packs, phase change materials or water hoses under protective equipment showed fewer signs of heat stress than those who did not.

• New research from Future Market Insights: "Chilled Water Storage System Market: Global Industry Analysis 2012 – 2016 and Opportunity Assessment; 2017 – 2027"

Research roundup: Mid-temperature solar collector; PCM use in NZEB buildings; modeling of nitrate materials; more

Ben Welter - Friday, June 23, 2017

Experimental investigation and theoretical analysis on a mid-temperature solar collector/storage system with composite PCM [Applied Thermal Engineering]

Experimental and computational study of melting phase-change material in a triplex tube heat exchanger with longitudinal/triangular fins [Solar Energy]

Thermodynamic modeling of nitrate materials for hybrid thermal energy storage: Using latent and sensible mechanisms [Solar Energy]

Outdoor Characterization of Phase Change Materials and Assessment of Their Energy Saving Potential to Reach NZEB [Buildings]

Preparation and Supercooling Modification of Salt Hydrate Phase Change Materials Based on CaCl2·2H2O/CaCl2 [Materials]

Research roundup: PCM-assisted night purge ventilation; dispersed metallic nanoparticles; crystallohydrates; more

Ben Welter - Tuesday, June 20, 2017

Nanoencapsulated crystallohydrate mixtures for advanced thermal energy storage [Journal of Materials Chemistry A]

Hexadecane-in-water emulsions as thermal-energy storage and heat transfer fluids: Connections between phase-transition temperature and period of hexadecane droplets dispersed in hexadecane-in-water emulsions and characteristics of surfactants [Colloids and Surfaces A: Physicochemical and Engineering Aspects]

Evaluating the Performance of American Change Phase Paraffin Cooling Vest and Iranian Spadana Gel Ice Cooling Vest on the Perceptual and Physiological Strain Score Index in Hot and Humid Working Conditions of Assaluyeh in Iran [International Journal of Occupational Hygiene]

Development of thermal enhanced n-octadecane/porous nano carbon-based materials using 3-step filtered vacuum impregnation method [Thermochimica Acta]

The impact of phase change materials assisted night purge ventilation on the indoor thermal conditions of office buildings in hot-arid climates [Energy and Buildings]

Thermal energy harvest in the discharge of CO2 semi-clathrate hydrate in an emulated cold storage system [Applied Thermal Engineering]

Melting dynamics of a phase change material (PCM) with dispersed metallic nanoparticles using transport coefficients from empirical and mean field models [Applied Thermal Engineering]

Comparative assessment of thermal comfort with insulation and phase change materials utilizations in building roofs and walls [pdf] [Advanced Materials Proceedings]

Fabrication and properties of graphene oxide-grafted-poly(hexadecyl acrylate) as a solid-solid phase change material [Composites Science and Technology]