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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

Two Entropy advisors, Dr. Mohammed Farid and Lucas B. Hyman, are pleased to take your questions about PCMs and thermal energy storage. Send your questions to bwelter@puretemp.com. We'll select the best and post the answers here each week.

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Research roundup: PCM-assisted night purge ventilation; dispersed metallic nanoparticles; crystallohydrates; more

Ben Welter - Tuesday, June 20, 2017

Nanoencapsulated crystallohydrate mixtures for advanced thermal energy storage [Journal of Materials Chemistry A]

Hexadecane-in-water emulsions as thermal-energy storage and heat transfer fluids: Connections between phase-transition temperature and period of hexadecane droplets dispersed in hexadecane-in-water emulsions and characteristics of surfactants [Colloids and Surfaces A: Physicochemical and Engineering Aspects]

Evaluating the Performance of American Change Phase Paraffin Cooling Vest and Iranian Spadana Gel Ice Cooling Vest on the Perceptual and Physiological Strain Score Index in Hot and Humid Working Conditions of Assaluyeh in Iran [International Journal of Occupational Hygiene]

Development of thermal enhanced n-octadecane/porous nano carbon-based materials using 3-step filtered vacuum impregnation method [Thermochimica Acta]

The impact of phase change materials assisted night purge ventilation on the indoor thermal conditions of office buildings in hot-arid climates [Energy and Buildings]

Thermal energy harvest in the discharge of CO2 semi-clathrate hydrate in an emulated cold storage system [Applied Thermal Engineering]

Melting dynamics of a phase change material (PCM) with dispersed metallic nanoparticles using transport coefficients from empirical and mean field models [Applied Thermal Engineering]

Comparative assessment of thermal comfort with insulation and phase change materials utilizations in building roofs and walls [pdf] [Advanced Materials Proceedings]

Fabrication and properties of graphene oxide-grafted-poly(hexadecyl acrylate) as a solid-solid phase change material [Composites Science and Technology]

PCM briefing: Viking Cold Solutions lands deal in Phoenix; study finds ARPA-E is doing what it was designed to do

Ben Welter - Monday, June 19, 2017

Viking Cold Solutions has announced a collaboration between Salt River Project and Bashas' Supermarkets to install and evaluate the performance of Viking's PCM-based thermal energy storage system at Bashas' distribution center in the Phoenix area. The system is expected to significantly reduce energy costs by shifting peak demand to nighttime hours.

A six-year study finds that ARPA-E, the U.S. Energy Department program that supports cutting-edge energy technologies, is meeting the goals of the 2007 law that created it even as the Trump administration seeks to eliminate its funding. The National Academies of Sciences, Engineering and Medicine report concludes that the program is moving in the right direction and does not require major changes to keep bringing new energy technologies to market.

• The co-creator of a camisole that uses phase change material to reduce the discomfort of hot flashes is profiled in ChicagoInno this month. Nancy Munro, who is selling "CoolCami" online, hopes to partner with a women’s undergarment company like Spanx or Soma. CoolCami is made of absorbent bamboo fabric and features a PCM-filled cooling liner.

Peli BioThermal reports that its ProMed thermal transport bags performed well in a five-month trial in the United Kingdom. The Great North Air Ambulance Service used the bags to transport blood plasma to accident scenes.

Ministry of Supply, the Boston startup that integrates phase change material in its high-tech menswear, has added a lightweight polo shirt to its lineup. The machine-washable Apollo 3 Polo sells for $70. 

Axiom Exergy, maker of "refrigeration batteries" designed to reduce energy use in supermarkets, is looking to fill eleven positions, including product engineer, product engineer manager and engineering intern. Candidates for the internship are asked to give a concise response to a "bonus question": "Given the choice between pure water and a NaCl-water solution as the thermal energy storage medium in medium temperature (40°F, 4.4°C) refrigeration applications, what are the pros and cons of each material?"

CIC energiGUNE is looking for a laboratory technician to join the Thermal Energy Storage unit's materials development and characterization group.

• The European Commission, in with collaboration with Skanska, Saint-Gobain, Sustainable Building Alliance and Green Building Councils, has developed an open-source assessment framework for measuring the energy performance of buildings. Level(s) links a building’s environmental impact with resource priorities at the European level. The voluntary tool will be ready for testing this fall.

Va-Q-tec AG has established a Japanese subsidiary in Tokyo. The German company develops, manufactures and sells vacuum insulation panels and phase change materials for use in thermal packaging, air freight containers and other applications. Va-Q-tec Japan GK will focus on providing "small box and container sales and rental solutions" in the Asian market.

• A recent New York Times piece answered the question: "What if you need a battery? A really big one — big enough to run a city?" A 2.35-million-square-foot office tower in New York City is among many buildings around the world equipped with a system that stores energy in the form of ice. The system freezes water overnight to help cool the building during the day, when electricity is typically more expensive.  

Massachusetts has awarded $1.5 million to help fund installation of more than 200 residential thermal energy storage units on Nantucket. Ice Energy, which makes the Ice Bear units, is partnering with Genbright LLC on the project. The goal is to help reduce peak energy demand and demonstrate an alternative to a third undersea transmission line to the island.

SaltX Technology and Aalborg CSP have agreed to work together to develop and commercialize an integrated energy storage solution for concentrated solar power based on EnerStore, SaltX's patented technology for large-scale energy storage. A prototype is scheduled to be built later this year with the aim of securing a commercial pilot plant in 2018.

Research roundup: Polystyrene microcapsules; vermiculite composites; topology optimization; more

Ben Welter - Friday, June 16, 2017

Polystyrene Microcapsules with Palmitic-Capric Acid Eutectic Mixture as Building Thermal Energy Storage Materials [Energy and Buildings]

Preparation and characterization of capric-palmitic-stearic acid ternary eutectic mixture/expanded vermiculite composites as form-stabilized thermal energy storage materials [Journal of Materials Science and Technology]

Topology optimization for heat transfer enhancement in Latent Heat Thermal Energy Storage [International Journal of Heat and Mass Transfer]

Investigating thermal properties of using nano-tubular ZnO powder in paraffin as phase change material composite for thermal energy storage [Composites Part B: Engineering]

Patent application: Compressed gas energy storage and harvesting system

Ben Welter - Wednesday, June 14, 2017

U.S. patent application 20170160019 (applicant IFP Energies Nouvelles, France ):

"The present invention relates to an AACAES system and method in which balls make it possible to store heat. The heat exchanges are produced by means of at least one radial heat exchanger, in which the balls and a first fluid circulate, the first fluid passing radially through means for circulating the balls. ... [Said] heat storage balls are produced in alumina, in metal or by micro or nano capsules of phase change material, such as paraffins, metals or salts. "

http://www.freepatentsonline.com/20170160019.pdf

Ice Bear 20 gets high marks for energy efficiency in third-party tests

Ben Welter - Friday, June 09, 2017

Ice Energy reports that its Ice Bear 20 home cooling and energy storage system has achieved a Seasonal Energy Efficiency Ratio (SEER) of 14.56 when operating like a conventional AC unit. Not bad. But the unit's Energy Efficiency Ratio when operating in ice cooling mode is a remarkable 150. According to CEO Mike Hopkins, that is "more than three times greater than the next best rating we could find, which is a geothermal system with an EER of 46." Many wall air conditioners now in use have an EER of around 10.

During off-peak hours, the Ice Bear stores cooling energy by freezing water in an insulated tank. During peak hours, the company says, the stored ice delivers up to four hours of cooling, reducing the typical peak load by 95 percent.

Large-scale manufacturing of the Ice Bear 20 is set to begin this summer to fulfill utility-sponsored programs in California and Massachusetts. Later this year the product will be made available directly to homeowners in California, Hawaii, Australia and the Middle East.

http://www.marketwired.com/press-release/ice-energys-home-cooling-energy-storage-system-achieves-world-record-energy-2220961.htm

PCM briefing: New oil palm varieties show sharply increased yields; thermal energy workshop in Germany

Ben Welter - Friday, June 09, 2017

Dr. Halime Paksoy, EnerSTOCK 2018 chair, reports that the energy storage conference has received more than 200 abstracts. Acceptance notifications will be sent out at the end of June. The conference will be held April 25-28, 2018, at Cukurova University in Adana, Turkey. 

• A workshop on “Thermal Energy Storage System for Energy Efficient Buildings" will be held June 22 at Ruhr University Bochum in Bochum, Germany. The workshop, which will be conducted in English, is part of the EU-supported project TESSe2b.

• Ryan Adelman, formerly chief commercial officer at Axiom Exergy, is now executive sales director for distributed energy at Direct Energy Business.

• New industry analysis from McKinsey & Co.: "What to do when a specialty chemical business gets commoditized."

• New from QYResearch Group: "Global Thermal Energy Storage Sales Market Report 2017"

KOTUG International BV has been nominated for a Maritime Innovation Award for its zero-emission heat recycling system, which uses phase change material to store and regenerate heat on tugboats. The annual award is presented by Netherlands Maritime Technology.

• Dutch food supplier Huuskes is using BoTemp's “Cold Battery” in cold chain logistics.
The refrigerated transport system, which does not require continuous electrical power, uses phase change material to remove heat in the cargo space and maintain a temperature anywhere from -20º C to +4º C.

Two new varieties of oil palm developed in Indonesia will increase crude palm oil yields by up to double current levels, says SMART Tbk, a subsidiary of Golden-Agri Resources. The two clones of oil palm planting material – called Eka 1 and Eka 2 – were approved for use in April by the country’s Ministry of Agriculture. The new varieties also have a quicker time to harvest – 24 months – compared to the industry average of 30 months.

Sunamp Ltd.'s PCM heat battery system was featured in a BBC News piece this week: "From hand-warmer to house-warmer for tech firm."

Research roundup: Shape-stabilized PCM in epoxy matrix; myristyl alcohol/metal foam for solar thermal storage; more

Ben Welter - Thursday, June 01, 2017

Illustration of shape-stabilized PCM in epoxy matrix

Novel shape stabilized phase change material based on epoxy matrix with ultrahigh cycle life for thermal energy storage [Applied Thermal Engineering]

Thermal and electrical performance of a PV module integrated with double layers of water-saturated MEPCM [Applied Thermal Engineering]

Investigation on thermal and mechanical characteristics of concrete mixed with shape stabilized phase change material for mix design [Construction and Building Materials]

Thermal properties and thermal conductivity enhancement of composite phase change materials using myristyl alcohol/metal foam for solar thermal storage [Solar Energy Materials and Solar Cells]

Experimental and Numerical Study on Energy Performance of Buildings Integrated with Phase Change Materials [Energy Procedia]

Evaluation on Performance of a Phase Change Material Based Cold Storage House [Energy Procedia]

Using Phase Change Materials to Reduce Overheating Issues in UK Residential Buildings [Energy Procedia]

Effect of Supercooling on the Solidification Process of the Phase Change Material [Energy Procedia]

Experimental Investigation of a Spiral Tube Embedded Latent Thermal Energy Storage Tank Using Paraffin as PCM [Energy Procedia]

Investigation of specific heat and latent heat enhancement in hydrate salt based TiO2 nanofluid phase change material [Applied Thermal Engineering]

Modeling and investigation of high temperature phase change materials (PCM) in different storage tank configurations [Journal of Cleaner Production]

Lauric acid/modified sepiolite composite as a form-stable phase change material for thermal energy storage [Applied Clay Science]

PCM briefing: Managing heat in low-orbit satellites; Expert Forum on VDI 2164 canceled

Ben Welter - Tuesday, May 30, 2017

Roccor LLC of Longmont, Colo., is using phase change material in a device designed to manage internal heat in low-orbit satellites. “We have one product with paraffin wax inside a flat structure. When the spacecraft is hot, it dumps heat into that paraffin wax and turns that into a liquid — basically a store of energy,” Chris Pearson, Roccor’s vice president of space programs, said in an interview with Via Satellite. The heat is later released into the satellite to keep temperatures stable.

• A new research portal for energy-optimized construction summarizes some of the funding measures of the German Federal Ministry of Economics and Technology under one umbrella. The German-language site, www.projektinfos.energiewendebauen.de, also has research on thermal energy storage and provides examples of projects and activities that apply PCM to optimize the energy needs of buildings.

Lloyds reports that Maersk Line is planning to make advanced monitoring data on premium perishables and pharma products available to its shipping customers later this year. 

• New from Research and Markets: "Global District Cooling Market By Type and Region, Competition Forecast and Opportunities, 2012-2026"

• New from HJResearch: "Global Bio-Based Phase Change Materials Industry Market Research 2017"

Pluss Advanced Technologies of Gurgaon, India, is seeking candidates for the position of research associate to design and perform experiments for the development of inorganic and organic phase change materials.

• The Swedish environmental group ChemSec has launched a free website linking companies selling alternatives to hazardous chemicals with those seeking to buy them. The first product request posted on The Marketplace: Clothing retailer H&M is looking for alternatives to the bisphenol A used in thermal paper for cash register and credit card receipts.

Celsia Inc.'s redesigned website, celsiainc.com, features a heat pipe performance calculator, a spreading delta-T calculator and a heat sink size calculator.

Glacier Tek, maker of cooling vests powered by PureTemp phase change material, has launched a redesigned website at www.glaciertek.com. The new site features improved navigation, fresh photography and a new tagline: "Prepare to be Cool."

• The City Council of Goderich, Ontario, has approved a proposal by NRStor to build a 1.75-megawatt compressed air energy storage plant in an unused salt cavern. The electricity created will feed into Ontario's energy grid.

• The Expert Forum on VDI Guideline 2164, scheduled for June 20 in Düsseldorf, Germany, has been canceled. The forum, organized by the Association of German Engineers' building and building technology group in cooperation with the RAL Quality Association PCM, may be held at a later date.

Research roundup: Stearic acid and modified expanded vermiculite; D-mannitol; acrylic-based microcapsules; more

Ben Welter - Saturday, May 27, 2017

From Renewable Energy:

Shape-stabilized composite phase change materials with high thermal conductivity based on stearic acid and modified expanded vermiculite

From AIMS Energy:

Feasibility study of D-mannitol as phase change material for thermal storage

From Thermal Science and Engineering Progress:

Computer simulations of heat transfer in a building integrated heat storage unit made of PCM composite

From European Polymer Journal:

Preparation of acrylic based microcapsules using different reaction conditions for thermo-regulating textiles production

From Energy Procedia:

Design of Experimental Investigation about the Effects of Flow Rate and PCM Placement on Thermal Accumulation

From Solar Energy Materials and Solar Cells:

A eutectic salt high temperature phase change material: Thermal stability and corrosion of SS316 with respect to thermal cycling
Novel form-stable phase change material composite for high-efficiency room temperature control

From Applied Thermal Engineering:

Thermal Energy Storage System Operating with Phase Change Materials for Solar Water Heating Applications: DOE Modelling

From Procedia Engineering:

A Comparative Study on the Effectiveness of Passive and Free Cooling Application Methods of Phase Change Materials for Energy Efficient Retrofitting in Residential Buildings
Thermal Energy Storage Enhancement of Lightweight Cement Mortars with the Application of Phase Change Materials

From Renewable and Sustainable Energy Reviews:

Thermal energy storage systems for concentrated solar power plants

From Construction and Building Materials:

The effect of low temperature phase change material of hydrated salt on the performance of magnesium phosphate cement

Patent application: Compressed gas energy storage and harvesting system

Ben Welter - Friday, May 19, 2017

U.S. patent application 20170138674 (applicant IFP Energies nouvelles, France):

"The present invention relates to an AACAES system and method in which a heat transfer fluid makes it possible to store heat. The heat transfer fluid, which comprises balls of heat storage material, circulates between two tanks: a hot tank and a cold tank, and passes through at least one heat exchanger. ... Advantageously, said balls are produced in alumina, in metal or by micro or nanocapsules of phase change material, such as paraffins, metals or salts."

http://www.freepatentsonline.com/20170138674.pdf