Phase Change Matters RSS


The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.




Research roundup: Dynamic behavior of PCM-27; Al2O3, SiO2 and TiO2 nano-inclusions; coacervation microencapsulation; more

Ben Welter - Tuesday, August 14, 2018

From International Journal of Thermal Sciences:

An experimental and a numerical analysis of the dynamic behavior of PCM-27 included inside a vertical enclosure: Application in space heating purposes

From Journal of Molecular Liquids:

Thermal conductivity enhancement in organic phase change material (phenol-water system) upon addition of Al2O3, SiO2 and TiO2 nano-inclusions

From Applied Thermal Engineering:

Experimental and numerical investigations of nano-additives enhanced paraffin in a shell-and-tube heat exchanger: A comparative study
Three-dimensional numerical and experimental investigation of the behavior of solar salts within thermal storage devices during phase change

From Energy Conversion and Management:

Formulation of a model predictive control algorithm to enhance the performance of a latent heat solar thermal system
Performance assessment of a new hydrogen cooled prismatic battery pack arrangement for hydrogen hybrid electric vehicles

From Carbohydrate Polymers:

Chitosan composite microencapsulated comb-like polymeric phase change material via coacervation microencapsulation

From Renewable Energy:

Analytical Considerations on Optimization of Cascaded Heat Transfer Process for Thermal Storage System with Principles of Thermodynamics

From Proceedings of Microscopy & Microanalysis 2018:

In-Situ TEM Observation of Crystallization in Phase-Change Material

From International Journal of Energy Research:

Patent application: Method for low-temperature microencapsulation of phase change material

Ben Welter - Sunday, August 12, 2018

U.S. patent application 20180223146 (inventors Mohammed Farid, Auckland, New Zealand, and Refat Al Shannaq, Shaheen Al-muhtaseb and Jamal Kurdi, Doha, Qatar):

Farid patent image"The method for low temperature microencapsulation of phase change materials or other components includes the following steps: (a) preparing a phase change emulsion including droplets of at least one active phase-change material in water with a surfactant; (b) adding a monomer of at least one encapsulating agent; (c) introducing the phase change emulsion into a UV reactor while stirring the emulsion; and (d) initiating the photo polymerization of monomers using at least one UV lamp inside the UV reactor for photo polymerization until the phase change material is encapsulated within a polymeric shell to form microcapsules. The microcapsules obtained by this process may have a diameter between about 0.5 to about 2 μm. Other sizes can also be obtained by changing stirring speed of the emulsion."

PCM briefing: Shipping costs rise for chemical companies; Inventure to build plant in China

Ben Welter - Saturday, August 11, 2018

Viking Cold Solutions founder and board chairman Paul Robbins, who retired as president at Caribbean Shipping Services in July, says he plans to resume a more active role in the day-to-day operations at Viking. The Houston company makes TES systems that pair phase change material with intelligent controls and remote energy-monitoring software to reduce commercial refrigeration costs.  

Chemical Week reports that shipping costs are on the rise for chemical companies as capacity tightens and truck traffic shifts to railroads.  

Inventure Renewables of Tuscaloosa, Ala., is partnering with Wilmar International and Desmet Ballestra Group on a new manufacturing plant in China's Jiangsu province, the Birmingham Business Journal reports. Construction is expected to begin in 2019. The plant will use Inventure’s soap carbonate technology to convert low-value processing residues into uncontaminated free fatty acids.

Maurizio ZaglioMaurizio Zaglio‎, right, international business development manager at Sunamp Ltd., was in Hangzhou, China, this week to present the company's new products at the 2018 China Heat Pump Annual Conference.

• New from Research and Markets: "Phase Change Materials (PCMs) - A Global Market Overview"

ARPA-E has issued a funding opportunity of up to $35 million for the High Intensity Thermal Exchange through Materials and Manufacturing Processes program, to develop new approaches and technologies for the design and manufacture of high-temperature, high-pressure, and highly compact heat exchangers. 

• The American Chemistry Council confirmed this week that high-density polyethylene (HDPE) is on the list of U.S. petrochemicals and plastics targeted for $16 billion in retaliatory tariffs from China. "Prospects of trade war are eroding business confidence from the Tax Cuts and Jobs Act," says the ACC's Kevin Swift. The U.S. economy is expected to grow by 2.4 percent in 2019, Morningstar reports, but economists have cut the average forecast for 2020 from 2 percent to 1.8 percent. 

Research roundup: Octadecanol/expanded perlite; PV/T system design; macroencapsulated PCM for pavement; more

Ben Welter - Friday, August 10, 2018

From Renewable Energy:

Experimental investigation on thermal properties and thermal performance enhancement of octadecanol/expanded perlite form stable phase change materials for efficient thermal energy storage
Effect of graphite mass concentrations in a mixture of graphite nanoparticles and paraffin wax as hybrid storage materials on performances of solar still

From Renewable and Sustainable Energy Reviews:

A review on recent development for the design and packaging of hybrid photovoltaic/thermal (PV/T) solar systems

From Materials:

Mechanical and Thermal Performance of Macro-Encapsulated Phase Change Materials for Pavement Application

From International Journal of Heat and Mass Transfer:

Heat transfer behavior of elemental sulfur for low temperature thermal energy storage applications
A novel method for determining the melting point, fusion latent heat, specific heat capacity and thermal conductivity of phase change materials
Effect of microstructure on melting in metal-foam/paraffin composite phase change materials

From Chemical Engineering Journal:

Flexible phase change materials for thermal storage and temperature control

From Construction and Building Materials:

Experimental investigation of thermal and mechanical properties of magnesium oxychloride cement with form-stable phase change material

From Solar Energy:

New insights into the corrosion mechanism between molten nitrate salts and ceramic materials for packed bed thermocline systems: A case study for steel slag and solar salt

Research roundup: Solar thermal modeling; finned multitube storage; solid-solid PCM: more

Ben Welter - Wednesday, August 01, 2018

From Applied Thermal Engineering:

Modelling and experimental study of latent heat thermal energy storage with encapsulated PCMs for solar thermal applications

From Journal of Energy Storage:

Estimation of thermal performance and design optimization of finned multitube latent heat thermal energy storage

From Engineering Science and Technology:

Experimental study on heat transfer performance of neopentyl glycol/CuO composite solid-solid PCM in TES based heat sink

From Solar Energy:

Synthesis and characterization of stearic acid/silicon dioxide nanoencapsules for solar energy storage

C-Therm offers free webinar on characterizing PCMs for TES and thermal management of batteries

Ben Welter - Tuesday, July 31, 2018

C-Therm Technologies is hosting a free webinar this week on recent research on composite phase change materials for thermal energy storage and battery thermal management. C-Therm’s MTPS method for thermal conductivity characterization of PCMs was used in the research. The webinar, "Characterizing Phase Change Materials for Thermal Energy Storage and Improved Battery Thermal Management," will be held at 1 p.m. EDT Thursday, Aug. 2.

Research roundup: Alum/expanded graphite composite; geopolymeric mortars; flexible PCMs; more

Ben Welter - Monday, July 30, 2018

From Energy:

Experimental investigations of Alum/expanded graphite composite phase change material for thermal energy storage and its compatibility with metals

From International Journal of Thermal Sciences:

Numerical study on the effect of phase change materials on heat transfer in asphalt concrete

From The Open Construction & Building Technology Journal:

Thermal Performance of Resource-Efficient Geopolymeric Mortars Containing Phase Change Materials

From Chemical Engineering Journal:

Flexible Phase Change Materials for Thermal Storage and Temperature Control

From Journal of Materials Chemistry A:

Nanoconfinement of phase change materials within carbon aerogels: phase transition behaviours and photo-to-thermal energy storage

From Materiales de Construcción:

Identification of best available thermal energy storage compounds for low-to-moderate temperature storage applications in buildings

Research roundup: Silicon carbide for battery thermal management; Stefan moving boundary models; alkali nitrate/nitrite salts; more

Ben Welter - Tuesday, July 24, 2018

From Renewable Energy:

Using Renewables Coupled with Thermal Energy Storage to Reduce Natural Gas Consumption in Higher Temperature Commercial/Industrial Applications

From Solar Energy:

Development of a solar thermal storage cum cooking device using salt hydrate

From Applied Energy:

One-step fabrication of fatty acids/nano copper/polyester shape-stable composite phase change material for thermal energy management and storage
Palmitic acid/polyvinyl butyral/expanded graphite composites as form-stable phase change materials for solar thermal energy storage

From Chinese Journal of Chemical Engineering:

Preparation and phase change performance of Na2HPO4·12H2O@poly(lactic acid) capsules for thermal energy storage

From Applied Thermal Engineering:

Thermal performance of sodium acetate trihydrate based composite phase change material for thermal energy storage
Performance improvement and energy consumption reduction in refrigeration systems using phase change material (PCM)
A thermal conductive composite phase change material with enhanced volume resistivity by introducing silicon carbide for battery thermal management
Numerical and Experimental study on the performance of a new two -layered high-temperature packed-bed thermal energy storage system with changed-diameter macro-encapsulation capsule

From Colloids and Surfaces A: Physicochemical and Engineering Aspects:

Green Nano-encapsulation Technique for Preparation of Phase Change Nanofibers Mats with Core-Sheath Structure
From International Journal of Thermal Sciences:

Analytical and numerical analysis of PCM solidification inside a rectangular finned container with time-dependent boundary condition

From Construction and Building Materials:

Elaboration and properties of a composite bio-based PCM for an application in building envelopes

From International Journal of Heat and Mass Transfer:

Lorentz forces effect on NEPCM heat transfer during solidification in a porous energy storage system
A translucent honeycomb solar collector and thermal storage module for building façades

PCM briefing: Brookins confirmed as Alexium CEO; palmitic acid, stearic acid on U.S. tariff list

Ben Welter - Monday, July 16, 2018

Dr. Robert BrookinsAlexium International has appointed Dr. Robert Brookins, right, as chief executive officer and managing director of the company. Brookins, formerly executive vice president of research and development, was appointed interim CEO in May, replacing Dirk Van Hyning, who resigned for personal reasons. Alexium, based in Greer, S.C., and Perth, Australia, makes flame-retardant and PCM-enhanced fabric treatments.

Palmitic acid, stearic acid and their salts and esters are on a list of more than 6,000 items on which the United States may impose additional import tariffs in its escalating trade war with China.

Two top executives at Wilmar International have stepped down after Greenpeace published a report linking the world's largest palm oil trading company to a supplier accused of deforestation.

Active Energy Systems, a clean-tech startup in Tennessee, is developing an electro-thermal energy storage system that will use waste heat generated by data centers, industrial complexes, institutions and power plants to store and distribute energy more efficiently and cheaply than systems using conventional batteries. "Using power from the grid at off-peak times," Venture Nashville Connections reports, "the process transforms water into ice -- spraying it through an oil layer, which allows the water to freeze but not stick to a submerged heat exchanger. Instead, it forms pellets resembling Dippin' Dots ice cream, [co-founder Mitch] Ishmael said. Then the cycle operates in reverse, using waste heat to melt the ice and generate electricity back to the grid."

• New from Research Mentor:" Global Phase Change Material (PCM) Market will be Worth USD 770.1 Million by 2023"

• New from Questale: "Global Eutectic Phase Change Material Market Research Report 2018"

• "What are some new trends in solar energy research and development in 2018?" a Quora member asked recently. Three answers were posted. The one provided by Yogi Goswami, director of the University of South Florida's Clean Energy Research Center, got more than 120 "upvotes" and was picked up by Forbes magazine. Goswami discussed the strengths and weaknesses of two competing technologies: photovoltaics and concentrating solar power. He expressed confidence that CSP will eventually become commercially competitive because it has two big advantages over PV: "It uses the same thermal power conversion as the conventional thermal power (fossil fuel or nuclear based) and can therefore be integrated with the existing power infra-structure easily" and it "uses thermal energy storage which is about one-tenth the cost of battery storage."

Research roundup: Novel graphite-PCM composite sphere; sunlight-driven energy conversion; PCM-rich concrete overlay; more

Ben Welter - Tuesday, July 10, 2018

From Applied Thermal Engineering:

A Novel Graphite-PCM Composite Sphere With Enhanced Thermo-Physical Properties
Fatty acids based eutectic phase change system for thermal energy storage applications

From Applied Energy:

Mathematical modeling and sensitivity analysis of solar photovoltaic panel integrated with phase change material
Compact liquid cooling strategy with phase change materials for Li-ion batteries optimized using response surface methodology
Multi-parameter optimization design of thermoelectric harvester based on phase change material for space generation

From Solar Energy:

Experimental study on the performance of a novel solar water heating system with and without PCM
Latent thermal energy storage for solar process heat applications at medium-high temperatures – A review
Carbon based material included-shaped stabilized phase change materials for sunlight-driven energy conversion and storage: An extensive review

From Construction and Building Materials:

Application of a PCM-rich concrete overlay to control thermal induced curling stresses in concrete pavements

From Energy Conversion and Management:

Energy investigation of glazed windows containing Nano-PCM in different seasons
Transforming a passive house into a net-zero energy house: a case study in the Pacific Northwest of the U.S.