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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the monthly PCM newsletter. Or join the discussion on LinkedIn.




Patent application: Mattress assemblies including panel with PCMs

Ben Welter - Sunday, September 06, 2020

U.S. patent application 20200260882 (applicant Dreamwell Ltd., Atlanta, Ga.):

"A mattress assembly comprising: at least one layer proximate to a sleeping surface of the mattress assembly spanning at least a portion of the length and/or width of the sleeping surface comprising: a two-ply preformed capsulate sheet comprising a plurality of cells; and a phase change material within at least a portion of the plurality of cells."

Research roundup: Hysteresis; reflective roof coating; optimizing energy balance of nearly zero energy buildings; more

Ben Welter - Monday, August 31, 2020

From Journal of Molecular Liquids:

The research progress on phase change hysteresis affecting the thermal characteristics of PCMs: A review

From Journal of Building Engineering:

Thermal behavior of a phase change material in a building roof with and without reflective coating in a warm humid zone

From Renewable Energy:

A comprehensive study on thermal storage characteristics of nano-CeO2 embedded phase change material and its influence on the performance of evacuated tube solar water heater

From Sustainable Cities and Society:

Numerical analysis of phase change materials for optimizing the energy balance of a nearly zero energy building

From Journal of Energy Storage:

Multi-objective optimization of cooling and heating loads in residential buildings integrated with phase change materials using the artificial neural network and genetic algorithm
Assessing corrosive behaviour of commercial phase change materials in the 21–25 ºC temperature range
Exergy and economic analyses of nanoparticle-enriched phase change material in an air heat exchanger for cooling of residential buildings
Experimental and numerical investigation on enhancing heat transfer performance of a phase change thermal storage tank
The effect of ultraviolet coating on containment and fire hazards of phase change materials impregnated wood structure

From Energy Conversion and Management:

Application of granular materials for void space reduction within packed bed thermal energy storage system filled with macro-encapsulated phase change materials

From Chemical Engineering Journal:

Simultaneous solar-thermal energy harvesting and storage via shape stabilized salt hydrate phase change material

From Solar Energy:

Characterization and cooling effect of a novel cement-based composite phase change material
Effect of polymer-derived silicon carbonitride on thermal performances of polyethylene glycol based composite phase change materials

From Case Studies in Thermal Engineering:

Effect of porosity and pore density of copper foam on thermal performance of the paraffin-copper foam composite Phase-Change Material

From Renewable and Sustainable Energy Reviews:

A critical assessment on synergistic improvement in PCM based thermal batteries

From Journal of Energy Resources Technology:

Experimental Analysis of Salt Hydrate Latent Heat Thermal Energy Storage System With Porous Aluminum Fabric and Salt Hydrate as Phase Change Material With Enhanced Stability and Supercooling

From Energy Sources:

Experimental study on thermal management and performance improvement of solar PV panel cooling using form stable phase change material
Experimental investigation of thermal performance of indirect mode solar dryer with phase change material for banana slices

From Aalto University:

Experimental design and investigation on a thermal energy storage system using phase change materials [thesis]

From Journal of Applied Physics:

Development of eco-sustainable plasters with thermal energy storage capability

From Chemical Engineering Transactions:

Thermal Performance of Phase Change Material Wallboard with Typical Structure: Artificial Controlled Condition Experimental Investigation

From Materials Research Express:

Fabrication of thermal energy storage wood based on graphene aerogel encapsulated polyethylene glycol as phase change material
Preparation and characterization of acrylic resin encapsulated n-dodecanol microcapsule phase change material

From ACS Sustainable Chemical Engineering:

Synthesis and Characterization of Fatty Acid Amides from Commercial Vegetable Oils and Primary Alkyl Amines for Phase Change Material Applications

From Carbohydrate Polymers:

Fibrous form-stable phase change materials with high thermal conductivity fabricated by interfacial polyelectrolyte complex spinning

From Materials Today: Proceedings:

Effect of various phase change materials (paraffin wax/hydrogenated vegetable oil) packed in a fabricated shell and tube type heat exchanger

From Solar Energy Materials and Solar Cells:

Composite phase change materials with heat transfer self-enhancement for thermal energy storage
Novel network structural PEG/PAA/SiO2 composite phase change materials with strong shape stability for storing thermal energy

From International Journal of Refrigeration:

Improving the performance of household refrigerating appliances through the integration of phase change materials in the context of the new global refrigerator standard IEC 62552:2015

From Advances in Colloid and Interface Science:

Nanoencapsulation of phase change materials (PCMs) and their applications in various fields for energy storage and management

From Building and Environment:

Space heating performance of novel ventilated mortar blocks integrated with phase change material for floor heating

From Energy:

A promising form-stable phase change material composed of C/SiO2 aerogel and palmitic acid with large latent heat as short-term thermal insulation

From Journal of Cleaner Production:

Enhanced thermal storage capacity of paraffin/diatomite composite using oleophobic modification

From International Conference on Renewable Energies for Developing Countries:

Storage efficiency of paraffin-LDPE-MWCNT phase change material for industrial building applications

Research roundup: Polythioether-based PCMS; alginate encapsulation; temperature stresses in concrete pavement; more

Ben Welter - Friday, May 08, 2020

From European Polymer Journal:

Extremely fast synthesis of polythioether based phase change materials (PCMs) for thermal energy storage

From Journal of Building Engineering:

Thermal behavior analysis of hollow bricks filled with phase-change material (PCM)

From Energies:

FEM Applied to Building Physics: Modeling Solar Radiation and Heat Transfer of PCM Enhanced Test Cells

From Iranian Polymer Journal:

Encapsulation of phase change materials with alginate modified by nanostructured sodium carbonate and silicate

From Energy & Fuels:

Aluminium ammonium sulfate dodecahydrate with multiple additives as composite phase change materials for thermal energy storage

From Materials Today: Proceedings:

Evaluation and reduction of temperature stresses in concrete pavement by using phase changing material
Optimization of Heat Energy Based on Phase Change Materials used in Solar Collector using Taguchi Method
Experimental and Theoretical Investigations on Thermal Conductivity of the Paraffin Wax using CuO Nanoparticles

From Journal of Energy Storage:

Novel synthesis of silica coated palmitic acid nanocapsules for thermal energy storage
Recent progress in phase change materials storage containers: Geometries, design considerations and heat transfer improvement methods
Effect of phase separation and supercooling on the storage capacity in a commercial latent heat thermal energy storage: Experimental cycling of a salt hydrate PCM
Energy efficiency optimization of the waste heat recovery system with embedded phase change materials in greenhouses: A thermo-economic-environmental study
Characterization of innovative mortars with direct incorporation of phase change materials

From Applied Thermal Engineering:

A trade study of a phase change system in a stratospheric airship based on a triple gasbag concept
Experimental evaluation of structural insulated panels outfitted with phase change materials
Lattice Boltzmann simulation of melting heat transfer in a composite phase change material

From Geothermics:

Parametric modeling and simulation of low temperature energy storage for cold-climate multi-family residences using a geothermal heat pump system with integrated phase change material storage tank

From Energy:

Multi-level uncertainty optimisation on phase change materials integrated renewable systems with hybrid ventilations and active cooling
A novel solar thermal system combining with active phase-change material heat storage wall (STS-APHSW): Dynamic model, validation and thermal performance

From Advances in Energy Research:

Theoretical Modeling of Phase Change Material-Based Space Heating Using Solar Energy

From Chemical Engineering Journal:

High latent heat and recyclable form-stable phase change materials prepared via a facile self-template method

From Composites Part B: Engineering:

In situ one-step construction of monolithic silica aerogel-based composite phase change materials for thermal protection

From Solar Energy:

Effects of external insulation component on thermal performance of a Trombe wall with phase change materials

From Journal of Architectural Engineering:

Experimental and Numerical Thermal Properties Investigation of Cement-Based Materials Modified with PCM for Building Construction Use

From Energy Conversion and Management:

Experimental and numerical study on the thermal performance of ventilated roof composed with multiple phase change material (VR-MPCM)

From Construction and Building Materials:

Multi-scale analysis on thermal properties of cement-based materials containing micro-encapsulated phase change materials

From Applied Energy:

D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability
Novel bio-based phase change materials with high enthalpy for thermal energy storage

From Materials Today Energy:

A detailed review on heat transfer rate, supercooling, thermal stability and reliability of nanoparticle dispersed organic phase change material for low-temperature applications

From International Journal of Thermal Sciences:

Experimental study and assessment of high-tech thermal energy storing radiant floor heating system with latent heat storage materials

From Advanced Powder Technology:

Paraffin core-polymer shell micro-encapsulated phase change materials and expanded graphite particles as an enhanced energy storage medium in heat exchangers

Patent application: Oil-in-water macro-emulsion process for forming solid gel beads

Ben Welter - Tuesday, March 24, 2020

U.S. patent application 20200071586 (applicant Microtek Laboratories, Dayton, Ohio): 

"Solid gel beads formed from a gel product of a 5 carbon to 60 carbon alkane phase change material, 5 carbon to 60 carbon alkene phase change material, or a combination thereof and a styrene-based polymer are homogeneous, has an uneven exterior surface, and a major axis length in a range of 1000 μm to 100 mm. Methods for making the solid gel bead include providing water having a preselected temperature based on a linear relationship to the melting point of a phase change material composition, mixing the phase change material composition with the styrene-based polymer at or below the preselected temperature with stirring to form a pulp, and mixing the pulp into the water with turbulent mixing while maintaining the temperature of the mixture at the preselected temperature."

Research roundup: Corn oil PCM in frozen food cooling machine; portable solar box cooker; expanded graphite/1-octadecanol composite; more

Ben Welter - Saturday, March 21, 2020

From Journal of Physics:

Corn oil phase change material (PCM) in frozen food cooling machine to improve energy efficiency

From Materials Today: Proceedings:

Investigating thermal properties of Nanoparticle Dispersed Paraffin (NDP) as phase change material for thermal energy storage

From Energy:

Effects of fluctuating thermal sources on a shell-and-tube latent thermal energy storage during charging process

From Solar Energy:

Design, realization, and tests of a portable solar box cooker coupled with an erythritol-based PCM thermal energy storage
Diversiform microstructure silicon carbides stabilized stearic acid as composite phase change materials

From International Journal of Thermofluids:

Investigating the performance of a thermal energy storage unit with paraffin as phase change material, targeting buildings’ cooling needs: an experimental approach

From Journal of Cleaner Production:

Energy and exergy analysis of wind farm integrated with compressed air energy storage using multi-stage phase change material

From Powder Technology:

Effect of nano-SiC on thermal properties of expanded graphite/1-octadecanol composite materials for thermal energy storage

From Journal of Energy Storage:

A multi-objective optimal design method for thermal energy storage systems with PCM: A case study for outdoor swimming pool heating application
Reducing PV module temperature with radiation based PV module incorporating composite phase change material
Numerical investigation on the effect of fin design on the melting of phase change material in a horizontal shell and tube thermal energy storage

From Journal of Thermal Analysis and Calorimetry:

Characterization of form-stable phase-change material for solar photovoltaic cooling

From International Journal of Thermophysics:

Thermophysical Properties of a Novel Nanoencapsulated Phase Change Material

From International Journal of Heat and Mass Transfer:

Lattice Boltzmann simulation of forced convection melting of a composite phase change material with heat dissipation through an open-ended channel
High power density thermal energy storage using additively manufactured heat exchangers and phase change material

From Energies:

Evaluation of the State of Charge of a Solid/Liquid Phase Change Material in a Thermal Energy Storage Tank [pdf]
Novel Simulation Algorithm for Modeling the Hysteresis of Phase Change Materials [pdf]

From Energy & Fuels:

Novel shape-stabilized phase change materials based on paraffin/EPDM@graphene with high thermal conductivity and low leakage rate

From Polymers and Polymer Composites:

Regulating phase-change temperatures of form-stable phase-change ternary composite fibrous membranes consisting of polystyrene nanofibers and fatty acid eutectics via co-electrospinning method

From Applied Energy:

A design protocol for enhanced discharge exergy in phase change material heat battery
Fabrication of heat storage pellets composed of microencapsulated phase change material for high-temperature applications
A high-thermal-conductivity, high-durability phase-change composite using a carbon fibre sheet as a supporting matrix

From Journal of Building Engineering:

Preparation and characterization of metal-organic framework /microencapsulated phase change material composites for indoor hygrothermal control

From Indoor and Built Environment:

Numerical and experimental investigation on dynamic thermal performance of floor heating system with phase change material for thermal storage

From Applied Clay Science:

A triply synergistic method for palygorskite activation to effectively impregnate phase change materials (PCMs) for thermal energy storage

From Chemical Engineering Journal:

Lignin-fatty acid hybrid nanocapsules for scalable thermal energy storage in phase-change materials

From Construction and Building Materials:

Phase change materials for pavement applications: A review

From Carbohydrate Polymers:

Shape-stabilization of polyethylene glycol phase change materials with chitin nanofibers for applications in “smart” windows

Research roundup: Carbonized waste tires; cetyl palmitate/nickel foam; hydrated salt corrosion assessment; more

Ben Welter - Tuesday, January 14, 2020

From Waste Management:

Evaluation of carbonized waste tire for development of novel shape stabilized composite phase change material for thermal energy storage

From Journal of Energy Storage:

Development of polyurethane foam incorporating phase change material for thermal energy storage
Facile synthesis and thermal performance of cetyl palmitate/nickel foam composite phase change materials for thermal energy storage
Optimal sizing design and operation of electrical and thermal energy storage systems in smart buildings

From Energy Conversion and Management:

Numerical investigation of the effects of the nano-enhanced phase change materials on the thermal and electrical performance of hybrid PV/thermal systems
Thermal storage and thermal management properties of a novel ventilated mortar block integrated with phase change material for floor heating: an experimental study

From Applied Energy:

Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage

From Renewable Energy:

Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems
Experimental study on latent thermal energy storage system with gradient porosity copper foam for mid-temperature solar energy application
Selection of a phase change material and its thickness for application in walls of buildings for solar-assisted steam curing of precast concrete
Experimental assessment of Phase Change Material (PCM) embedded bricks for passive conditioning in buildings

From Applied Thermal Engineering:

Analysis of energy retrofit system using latent heat storage materials applied to residential buildings considering climate impacts
Experimental and numerical simulation of phase change process for paraffin/expanded graphite/ethylene-vinyl acetate ternary composite
An experimental investigation on the evaporation of polystyrene encapsulated phase change composite material based nanofluids

From Solar Energy Materials and Solar Cells:

Lightweight mesoporous carbon fibers with interconnected graphitic walls for supports of form-stable phase change materials with enhanced thermal conductivity

From Energies:

The Effects of Fin Parameters on the Solidification of PCMs in a Fin-Enhanced Thermal Energy Storage System

From Journal of Materials Science:

Graphene aerogel-based phase changing composites for thermal energy storage systems

From Journal of Mechanical Science and Technology:

A study on development of the thermal storage type plate heat exchanger including PCM layer

From Journal of Power Sources:

Delayed liquid cooling strategy with phase change material to achieve high temperature uniformity of Li-ion battery under high-rate discharge

From Scientific Reports:

Modification of asphalt mixtures for cold regions using microencapsulated phase change materials

From ASES National Solar Conference:

A Study on the Thermal Energy Storage System Using Multiple PCMs [pdf]

From Molecules:

Assessment of Thermal Performance of Textile Materials Modified with PCM Microcapsules Using Combination of DSC and Infrared Thermography Methods

From Energy and Buildings:

Experimental study on thermal performance of a mobilized thermal energy storage system: A case study of hydrated salt latent heat storage

From Chemical Engineering Journal:

Shape-stabilized hydrated salt/paraffin composite phase change materials for advanced thermal energy storage and management

From International Journal of Heat and Mass Transfer:

A conjugate heat transfer model for unconstrained melting of macroencapsulated phase change materials subjected to external convection

Patent application: Latent-heat storage body microcapsules

Ben Welter - Monday, October 14, 2019

U.S. patent application 20190300770 (applicant National University Corp., Hokkaido University, Hokkaido, Japan):

Hokkaido microcapsule patent drawing"In the present invention, after a primary coating film is formed by boehmite treatment of the surface of a core particle in a solution comprising Al ions, a secondary coating film is formed by cooling the solution to the supersaturation temperature of the Al ions to cause deposition of a hydroxide of aluminum on the surface of the primary coating film, and an Al oxide film is formed on the surface of the core particle by heat treating the secondary coating film in an oxidizing atmosphere. Consequently, the shell is thickened by the amount of secondary coating film formed, so that the cyclic strength of the capsule can be secured and the composition change of the PCM in the production process is remarkably suppressed."

Research roundup: Passive cooling in buildings; honeycomb carbon fibers; leak-free aggregates; more

Ben Welter - Monday, October 14, 2019

From Applied Energy:

Passive cooling through phase change materials in buildings. A critical study of implementation alternatives

From Applied Thermal Engineering:

Honeycomb carbon fibers strengthened composite phase change materials for superior thermal energy storage

From e-Polymers:

Fabrication and characterization of conductive microcapsule containing phase change material

From Construction and Building Materials:

Preparation and characterization of nano-SiO2/paraffin/PE wax composite shell microcapsules containing TDI for self-healing of cementitious materials
Development of leak-free phase change material aggregates
Behavior of cementitious mortars with direct incorporation of non-encapsulated phase change material after severe temperature exposure

From Advanced Functional Materials:

Engineering the Thermal Conductivity of Functional Phase‚ÄźChange Materials for Heat Energy Conversion, Storage, and Utilization

From Journal of Energy Storage:

A numerical investigation of the effects of metal foam characteristics and heating/cooling conditions on the phase change kinetic of phase change materials embedded in metal foam
Applications of combined/hybrid use of heat pipe and phase change materials in energy storage and cooling systems: A recent review
Innovative composite sorbent for thermal energy storage based on a SrBr2·6H2O filled silicone composite foam

From ACS Applied Nano Materials:

Concentrated Ag Nanoparticles in Dodecane as Phase Change Materials for Thermal Energy Storage

From Materials Research Express:

Preparation of 1-dodecanol microcapsules with cellulose nanofibers-modified melamine-formaldehyde resin as a potential phase change material

From IOP Conference Series: Earth and Environmental Science:

Optimisation of Parameters in Thermal Energy Storage System by Enhancing Heat Transfer in Phase Change Material

From International Journal of Heat and Mass Transfer:

Thermal transport properties at interface of fatty acid esters enhanced with carbon-based nanoadditives

From Journal of Solar Energy Engineering:

Using a Novel Phase Change Material-Based Cooling Tower for a Photovoltaic Module Cooling

From Solar Energy:

Experimental investigation on micro-scale phase change material based on sodium acetate trihydrate for thermal storage

From RSC Advances:

A novel forced separation method for the preparation of paraffin with excellent phase changes

From Energy Conversion and Management:

Experimental characterisation of a novel thermal energy storage based on open-cell copper foams immersed in organic phase change material

Patent application: Controlled release dual-walled microcapsules

Ben Welter - Friday, September 20, 2019

U.S. patent application 20190282989 (applicant Encapsys LLC, Appleton, Wis.):

"A method of forming dual melamine/acrylic walled microcapsules having improved physical properties and release control as well as the microcapsules formed by the process wherein the capsule wall is formed by the use of select (meth)acrylate monomers and/or oligomers and/or select self-condensing melamine resins."

Patent application: Reduced permeability microcapsules

Ben Welter - Friday, September 20, 2019

U.S. patent application 20190275490 (applicant Trucapsol LLC, Bethlehem, Penn.):

Trucapsol patent drawing"Disclosed is a composition including controlled release particles, wherein each of the controlled release particles includes: (a) a core including at least one hydrophobic active ingredient; and (b) a wall at least partially surrounding the core and including: (i) an outer layer including a copolymer of polyacrylamide and polyacrylate; (ii) an intermediate layer under the outer layer and including a polyurea; (iii) an inner layer under the intermediate layer and including an acrylate copolymer; and optionally (iv) an optional outer layer above the outer layer and including a quaternary amine containing moiety, wherein the inner layer is a mesh and the controlled release particles are effective to retain the at least one hydrophobic active ingredient upon exposure to water and effective to release the at least one hydrophobic active ingredient in response to friction. A method for preparing the composition is also disclosed."