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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Patent application: Method and system for thermal cooling of an enclosure

Ben Welter - Friday, May 24, 2019

U.S. patent application 20190154282 (applicant International Business Machines Corp., Armonk, N.Y.):

"A computer-implemented mitigation and warning method, system, and computer program product including detecting an enclosure temperature via an enclosure temperature probe and activating, via a controller, a thermoelectric device when the enclosure temperature exceeds a predetermined threshold temperature to transfer heat between an enclosure and a phase change material (PCM) to cause the PCM to change phase and cool the enclosure."

http://www.freepatentsonline.com/20190154282.pdf

Research roundup: High-conductivity nanomaterials; paper board packaging; battery thermal management; more

Ben Welter - Thursday, May 16, 2019

From Heat and Mass Transfer:

Experimental and numerical analysis of composite latent heat storage in cooling systems for power electronics

From Journal of Sol-Gel Science and Technology:

A robust, flexible superhydrophobic sheet fabricated by in situ growth of micro-nano-SiO2 particles from cured silicone rubber

From Journal of Thermal Analysis and Calorimetry:

High-conductivity nanomaterials for enhancing thermal performance of latent heat thermal energy storage systems

From Building Simulation:

Optimization and sensitivity analysis of design parameters for a ventilation system using phase change materials

From Journal of Packaging Technology and Research:

Thermal Analysis of Paper Board Packaging with Phase Change Material: A Numerical Study

From Energy Storage:

Thermal performance of battery thermal management system using composite matrix coupled with mini‐channel

From Phase Transitions:

A study on preparation and properties of carbon materials/myristic acid composite phase change thermal energy storage materials

From ACS Applied Materials & Interfaces:

Melamine Foam Supported Form-stable Phase Change Materials with Simultaneous Thermal Energy Storage and Shape Memory Property for Thermal Management of Electronic Devices

From International Conference on Thermal Engineering:

Performance Enhancement of Unitary and Packaged Air Conditioners With Phase Change Material
Performance Comparison of Different Phase Change Materials For Solar Cooking During off Sun Sunshine Hours
A Review on Enhancement of Thermophysical Properties of Paraffin Wax PCM With Nanomaterials
Nano-Enhanced PCMs for Low Temperature Thermal Energy Storage Systems and Passive Conditioning Applications

From Chemistry Select:

Designing Coconut Oil Encapsulated Poly(stearyl methacrylate‐co‐hydroxylethyl metacrylate) Based Microcapsule for Phase Change Materials

From Evolution in Polymer Technology Journal:

Enhancement of Thermo-Regulating Textile Materials Using Phase Change Material

From Materials Research Express:

Improved thermal characteristics of Ag nanoparticles dispersed myristic acid as composite for low temperature thermal energy storage

From Applied Energy:

On the performance of ground coupled seasonal thermal energy storage for heating and cooling: A Canadian context

From Solar Energy Materials and Solar Cells:

Thermal stability enhancement of d-mannitol for latent heat storage applications

Research roundup: Zinc oxide coating; TEG-PCM power enhancement; graphen-oxide aerogel beads; more

Ben Welter - Friday, May 10, 2019

From Advanced Materials Interfaces:

Doubly Coated, Organic–Inorganic Paraffin Phase Change Materials: Zinc Oxide Coating of Hermetically Encapsulated Paraffins

From Applied Energy:

Efficiency analysis and experimental validation of the ocean thermal energy conversion with phase change material for underwater vehicle
A numerical and experimental analysis of an integrated TEG-PCM power enhancement system for photovoltaic cells
Molten salt selection methodology for medium temperature liquid air energy storage application

From Applied Energy Materials:

Graphene-Oxide Aerogel Beads Filled with Phase Change Material for Latent Heat Storage and Release

From Journal of Wuhan University of Technology:

Effect of Modified Vermiculite on the Interface of a Capric Acid-expanded Vermiculite Composite Phase Change Material with Phase Transition Kinetics

From Journal of Molecular Liquids:

Numerical simulation of the melting process of nanostructured based colloidal suspensions phase change materials including the effect of the transport of the particles

From Fibers and Polymers:

Encapsulated Phase Change Material Embedded by Graphene Powders for Smart and Flexible Thermal Response

From Applied Thermal Engineering:

Influence of orientation on thermal performance of shell and tube latent heat storage unit

From Journal of Energy Storage:

Development and validation of the numerical model of an innovative PCM based thermal storage system

From 2nd International Conference on Power, Energy and Environment:

Feasibility Study of the Application of a Latent Heat Storage in a Solar Dryer for Drying Green Chili

From Solar Energy:

Tetradecyl oxalate and octadecyl oxalate as novel phase change materials for thermal energy storage
An analytical and comparative study of the charging and discharging processes in a latent heat thermal storage tank for solar water heater system
Effect of alkaline pH on formation of lauric acid/SiO2 nanocapsules via sol-gel process for solar energy storage

From Journal of Applied Polymer Science:

Preparation and characterization of paraffin microcapsules for energy‐saving applications

From Energy:

Flexible heatsink based on a phase-change material for a wearable thermoelectric generator

From Journal of Nanoscience and Nanotechnology:

Superior Form-Stable Phase Change Material Made with Graphene-Connected Carbon Nanofibers and Fatty Acid Eutectics

From Construction and Building Materials:

Thermal and rheological characterization of bitumen modified with microencapsulated phase change materials

From Thermochimica Acta:

Development of spherical α-Al2O3-based composite phase change materials (PCMs) and its utilization in thermal storage building materials

From Journal of Power Sources:

Thermophysical properties of trimethylolethane (TME) hydrate as phase change material for cooling lithium-ion battery in electric vehicle

From Solar Energy Materials and Solar Cells:

Applications of cascaded phase change materials in solar water collector storage tanks: A review
Thermal conductivity enhancement of hydrated salt phase change materials employing copper foam as the supporting material

Patent application: Multilayer thermal laminate

Ben Welter - Saturday, March 23, 2019

U.S. patent application 20190089027 (applicant Dell Products L.P., Round Rock, Texas):

"A multilayer thermal laminate with aerogel is used for a battery cell enclosure to improve thermal properties and to reduce thermal inhomogeneity in the form of localized hotspots that exceed a desired rated temperature, thereby enabling a more compact design within rated thermal design limits for a given electrical performance. ... [The third layer of the laminate] serves as a thermal storage medium and may accordingly be comprised of a phase change material, such as a wax. The phase change material may be selected to have a desired melting temperature range, such as between 30 C and 70 C, between 45 C and 65 C, or between 40 C and 60 C, in given implementations, among other possible melting temperature ranges."

http://www.freepatentsonline.com/20190089027.pdf

Patent application: Removable sticker for cooling hot spots in cellular phones

Ben Welter - Saturday, March 23, 2019

U.S. patent application 20190086158 (inventor James Hirschfeld, Delray Beach, Fla.):

"A removable cooling sticker secured to the surface of a cellular telephone for extraction of heat from the cellular telephone. The cooling sticker is thin and sized to be conveniently carried. [Using phase change material as the active heat extraction material,] the cooling sticker is adhered to the cellular telephone at its hot spot for maximum efficiency. An optional feature employs thermal strips that indicate when the electronic device is exceeding a temperature threshold sticker."

http://www.freepatentsonline.com/20190086158.pdf

Research roundup: PCM wallboard; cement mortars; electric load shifting; red-mud geopolymer composite; more

Ben Welter - Wednesday, February 27, 2019

From Renewable Energy:

Phase Change Material Wallboard (PCMW) melting temperature optimisation for passive indoor temperature control

From Cement and Concrete Research:

Multiphysics analysis of effects of encapsulated phase change materials (PCMs) in cement mortars

From Journal of Molecular Liquids:

Preparation and characterization of sodium sulfate pentahydrate/sodium pyrophosphate composite phase change energy storage materials

From Energy and Buildings:

Performance of heat pump integrated phase change material thermal storage for electric load shifting in building demand side management
Indoor thermal comfort assessment using PCM based storage system integrated with ceiling fan ventilation: Experimental design and response surface approach

From International Journal of Photoenergy:

Experimental Study on the Performance of a Phase Change Slurry-Based Heat Pipe Solar Photovoltaic/Thermal Cogeneration System

From Solar Energy:

Effects of sodium nitrate concentration on thermophysical properties of solar salts and on the thermal energy storage cost
Red-mud geopolymer composite encapsulated phase change material for thermal comfort in built-sector [pdf]

From Energies:

A Novel Encapsulation Method for Phase Change Materials with a AgBr Shell as a Thermal Energy Storage Material

From Advanced Composites and Hybrid Materials:

Latent heat and thermal conductivity enhancements in polyethylene glycol/polyethylene glycol-grafted graphene oxide composites

From International Journal of Refrigeration:

Preparation and performance of form-stable TBAB hydrate/SiO2 composite PCM for cold energy storage

From Solar Energy Materials and Solar Cells:

Delignified wood/capric acid-palmitic acid mixture stable-form phase change material for thermal storage
Molten salt corrosion mechanisms of nitrate based thermal energy storage materials for concentrated solar power plants: A review

From Buildings:

Thermal Performance of Hollow-Core Slab Ventilation System with Macro-Encapsulated Phase-Change Materials in Supply Air Duct

From International Journal of Heat and Mass Transfer:

Heat transfer performance of the finned nano-enhanced phase change material system under the inclination influence

From Journal of the Electrochemical Society:

Effect of High Temperature Circumstance on Lithium-Ion Battery and the Application of Phase Change Material

From Energy:

High-temperature PCM-based thermal energy storage for industrial furnaces installed in energy-intensive industries

Patent application: Temperature control device with PCM

Ben Welter - Monday, December 10, 2018

U.S. patent application 20180347869 (inventors Anthony Boule, Toulouse, France; Pierre Lapalus, Marseille, France):

"The invention relates to a portable device for regulating the temperature of an element, comprising: an engagement part adapted to be placed in contact with the element, a temperature regulation unit comprising a thermoelectric module having two sides (41, 42), a first side (41) of the thermoelectric module being thermally coupled with the engagement part (2). The device further comprises: a reception part (5) adapted to removably receive a phase change material (PCM) (6), a second side (42) of the thermoelectric module being thermally coupled with the reception part (5), such that a phase change material (PCM) (6) provided in the reception part will also be thermally coupled with the second side (42) of the thermoelectric module."

http://www.freepatentsonline.com/20180347869.pdf

PCM briefing: Isomer can store energy for up to 18 years; concept combines pumped storage and heat storage using water as a medium

Ben Welter - Friday, November 02, 2018

• Researchers at Chalmers University of Technology and Universidad de La Rioja have created a system capable of storing solar energy for extended periods. The Molecular Solar Thermal Energy Storage system uses a molecular photo switch made from carbon, hydrogen and nitrogen. Sunlight turns the molecule into an energy-rich isomer. The isomer can be stored in a liquid form to be used for heating at night or in winter. “The energy in this isomer can now be stored for up to 18 years. And when we come to extract the energy and use it, we get a warmth increase which is greater than we dared hope for,” said Kasper Moth-Poulsen, professor at Chalmers.

• New research at California's Lawrence Livermore National Laboratory reveals how an unusual type of ice known as Ice VII can form at speeds over 1,000 miles per hour. "This ice type was only discovered occurring naturally in March, trapped inside diamonds deep underground," reports Science Alert, "and this latest study looks in detail at how exactly it takes shape – apparently in a way that's completely different to how water usually freezes into ice."

• A research team at the Graz University of Technology, Austria, has combined the advantages of pumped storage technology and heat storage using water as a medium in a hybrid storage concept called "hot-water pumped storage hydropower." The new system stores and supplies electricity, heat and cooling energy. 

• The U.S. Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E) has openings for program directors, tech-to-market advisors and two-year fellowships.  

Registration is open for the 2019 ARPA-E Energy Innovation Summit, to be held in Denver, Colo., July 8-10. Now in its 10th year, the annual conference and technology showcase "brings together experts from different technical disciplines and professional communities to think about America’s energy challenges in new and innovative ways."

A full agenda is available for the World Bio Markets conference, to be held in Amsterdam, Netherlands, April 1-3. Speakers include Rolf Hogan, executive director, Roundtable on Sustainable Biomaterials; Chris Sayner, vice president customer alliances, corporate sustainability, Croda; and Davide Bragholi, project manager, environmental innovations, Tetra Pak. 

• Registration is open for the inaugural Thermal Materials Summit to be held in Los Angeles on May 2. This technical forum will explore the latest advancements in thermal interface materials for professionals working in aerospace, automotive, telecom, batteries and other fields. Presentation proposals are due by Dec. 7.

Ecozen Solutions of India is one of five finalists in Rabobank’s inaugural Food Loss Challenge Asia. The competition aims to identify innovative ag-tech start-ups working to solve farm-to-market food loss problems. The finalists will present their solutions to a panel of judges at Rabobank’s annual Asia Food & Agribusiness advisory board meeting in Singapore later this month. Ecozen makes portable solar cold rooms for small farms, using a thermal storage unit that can store power for more than 36 hours in case of cloudy or rainy weather.

Patent application: Cooling electronic devices in a data center

Ben Welter - Saturday, August 18, 2018

U.S. patent application 20180235108 (applicant Google LLC, Mountain View, Calif.):

"A data center cooling system includes a thermosiphon, an actuator coupled to the thermosiphon, and a controller. The thermosiphon includes an evaporator; a condenser; and at least one conduit coupled between the evaporator and the condenser to transport a working fluid between the evaporator and the condenser. The controller is coupled to the actuator and configured to operate the actuator to adjust a liquid level of the working fluid in the evaporator based, at least in part, on a parameter associated with a heat load of one or more data center heat generating computing devices."

http://www.freepatentsonline.com/20180235108.pdf

Patent application: Use of a composite material for heat management

Ben Welter - Monday, July 09, 2018

U.S. patent application 20180187977 (applicant SGL Carbon SE, Wiesbaden, Germany):

"The use of a composite material for heat management in the electrical and/or electronic area, in particular in a car. A grid-like structure filled with a phase change material (PCM), and to a composite material that includes a grid-like structure filled with PCM. The filled grid-like structure being present on a cover layer or between two cover layers."

http://www.freepatentsonline.com/20180187977.pdf