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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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PCM briefing: PureTemp fabrics featured at Materio library; new round of funding for Ecozen Solutions

Ben Welter - Friday, July 26, 2019

PureTemp-enhanced fabrics were among the new materials presented at a gathering of architects, designers and journalists at the MatériO library in Paris this week. The materials library, which also has showrooms in Brussels, Seoul and Shanghai, lists thousands of "cutting edge" materials and technologies in its online database, including PureTemp's biobased PCM.

Southern Research opened the new Energy Storage Research Center on its engineering campus in Birmingham, Ala., this month. The center will work to speed the development of clean and sustainable energy storage technology, including thermal energy storage systems. 

Ecozen Solutions of India, which makes portable solar cold rooms for use on small farms, recently closed a Series A round of funding from investors including impact investment fund manager Caspian and Hivos-Triodos Fund, which is affiliated with Netherlands-based Triodos Bank. Omnivore Capital Management Advisors, which originally invested in Ecozen in 2015, also participated in the round, AgFunder News reports. The solar cold room's thermal storage unit can store power for more than 36 hours in case of cloudy or rainy weather. 

Research roundup: Spent coffee grounds; tropical tree fruit oils; natural rubber composites; more

Ben Welter - Friday, July 05, 2019

From Chemosphere:

Spent coffee grounds as supporting materials to produce bio-composite PCM with natural waxes

From Biotechnology Reports:

Novel phase change materials for thermal energy storage: evaluation of tropical tree fruit oils

From Construction and Building Materials:

Compressive strength and hygric properties of concretes incorporating microencapsulated phase change material
Thermal enhanced cement-lime mortars with phase change materials (PCM), lightweight aggregate and cellulose fibers

From Case Studies in Thermal Engineering:

Optimal fin parameters used for enhancing the melting and solidification of phase-change material in a heat exchanger unite

From Materials Chemistry and Physics:

Porous geopolymer as a possible template for a phase change material

From Journal of Physics: Conference Series:

Thermophysical Characteristics of VCO-Soybean Oil Mixture as Phase Change Material (PCM) using T-History Method

From Rubber Chemistry and Technology:

Phase-Change Material: Natural Rubber Composites for Heat Storage Applications

From Powder Technology:

An enthalpy based discrete thermal modelling framework for particulate systems with phase change materials

From Chemistry Select:

Carbon Soot/n–carboxylic Acids Composites As Formā€stable Phase Change Materials For Thermal Energy Storage

From International Journal of Heat and Mass Transfer:

Experimental study of thermo-physical properties and application of paraffin-carbon nanotubes composite phase change materials
High thermal response rate and super low supercooling degree microencapsulated phase change materials (MEPCM) developed by optimizing shell with various nanoparticles

From Applied Thermal Engineering:

Design optimization of the phase change material integrated solar receiver: A numerical parametric study

From Solar Energy Materials and Solar Cells:

Synthesis and characterization of ditetradecyl succinate and dioctadecyl succinate as novel phase change materials for thermal energy storage

From Advanced Materials Interfaces:

Doubly Coated, Organic–Inorganic Paraffin Phase Change Materials: Zinc Oxide Coating of Hermetically Encapsulated Paraffins

From Journal of Energy Storage:

Heat transfer enhancement of charging and discharging of phase change materials and size optimization of a latent thermal energy storage system for solar cold storage application

PCM briefing: Lineup set for TES forum in Duesseldorf; CIC Energigune joins European research network

Ben Welter - Friday, June 21, 2019

Christoph Rathgeber of ZAE Bayern and Michael Andretzky of the University of Duisburg-Essen are among the speakers at next week's Thermal Energy Storage Forum in Dusseldorf, Germany. The forum will focus on the use of thermal storage in industrial processes. Rathgeber's topic is "Economy of thermal energy storage." Andretzky's topic: "PCM in buffer tank for CHPs."

Crystallize bubble• Another frosty gem from Physics Today: "Bubbles freeze in a swirl of ice crystals"

Siemens Gamesa Renewable Energy has launched an electric thermal energy storage system designed to store large quantities of energy cost-effectively. The pilot plant in Hamburg can store up to 130 MWh of thermal energy for a week. It uses a steam turbine to convert stored energy into electricity. 

CIC Energigune, a thermal energy storage research center in Spain's Basque Country, has joined the ALISTORE-ERI network. The European network brings together 20 research centers and 12 companies engaged in advanced energy storage research.

Viking Cold Solutions of Houston has made Food Logistics' list of Top Green Providers 2019. Viking was honored in two categories, refrigeration and alternative fuels &  energy. The company says its PCM-based thermal storage system, designed for use in cold storage facilities, can reduce energy consumption by more than 25 percent.

Cryopak, a maker of insulated shipping containers, gel packs and phase change materials, says it is taking steps toward reducing its carbon footprint with the launch of a new line of shipping solutions. The company, based in Edison, N.J. says its R3 Service Program "minimizes the need for insulation materials, phase change solutions, bottles and their necessary disposal by handling the coordination of container delivery, reverse logistics and required refurbishment."

Sonoco ThermoSafe has an opening for a sales manager with "experience in strategic selling across Europe."

8 Viking Cold Solutions systems installed in Massachusetts

Ben Welter - Friday, June 14, 2019

Viking Cold Solutions has completed the installation of eight thermal energy storage systems as part of a utility-backed demand management program in Massachusetts. The Houston company says its PCM-based system, designed for use in cold storage facilities,  stores enough energy to cycle off refrigeration for up to 13 hours per day and reduce energy consumption by more than 25 percent. 

https://www.vikingcold.com/news/release-viking-cold-solutions-installs-1-3-mw-of-thermal-energy-storage-in-industrial-cold-storage-facilities-as-part-of-a-massachusetts-utility-demand-management-program/

PCM briefing: Sonoco ThermoSafe partners with Cargolux; Axiom Exergy partners with Leap

Ben Welter - Friday, March 22, 2019

Amrit RobbinsAxiom Exergy has announced a partnership with Leap, a technology company that serves as an aggregator of flexible power loads in California. Axiom says the arrangement will unlock grid services revenue for its customers, including three Whole Foods Market facilities in Northern California.

Axiom's "Refrigeration Battery" system is designed to reduce a supermarket's peak power use by up to 40 percent and provide backup cooling during power outages. It uses the excess capacity of existing refrigeration systems to "store cooling" at night by freezing tanks of salt water.  

"Axiom Exergy is excited to announce that Whole Foods has connected three of their buildings to our platform, which will serve as our first Virtual Power Plant," Axiom CEO Amrit Robbins wrote in a LinkedIn post Friday. "Axiom’s platform will intelligently manage 340 kW of dispatchable load across these facilities in order to generate more value for Whole Foods and to help stabilize California’s electricity grid."

Sonoco ThermoSafe has announced a global partnership agreement with Cargolux for the leasing of the PharmaPort 360 temperature-controlled bulk shipping container. The agreement enables pharmaceutical shippers to lease PharmaPort 360 containers directly from the all-cargo airline based in Luxembourg.

• On LinkedIn this week, Ice Energy posted an update on its 5 MW contract with Riverside Public Utilities in California: "We are working to install 9 Ice Bear thermal #energystorage batteries and 13 rooftop units with Inland Mechanical Services Inc. at a car dealership in Riverside."

• A high-temperature thermal energy storage system inaugurated in Denmark this week stores heat in stones. The test system uses surplus wind power to generate hot air, which heats up small stones in an insulated container to 600 degrees. The stored heat is used to generate electricity when the wind doesn't blow. The system was developed by the energy company Seas-NVE, in collaboration with DTU Energy, Aarhus University Geoscience, Danish Energy, Energinet.dk and Rockwool.

Alexium International CEO Bob Brookins was among the presenters at the International Conference on Textile Coating and Laminating in Berlin earlier this month. His topic: "Advanced applications of phase change materials."

• The German Aerospace Center (DLR) is investigating whether Germany’s coal plants can be refitted to serve as thermal energy storage sites. "The research body, which has a track record in concentrated solar power (CSP) development, is planning a pilot that will involve ripping out the boiler from an old coal plant and replacing it with a molten salt thermal storage tank that will be heated using excess renewable energy," Greentech Media reports. "If the concept works, then advocates say it could help safeguard coal generation jobs while giving Germany tens of gigawatts of storage capacity for renewable energy load-shifting on the German grid." DLR says it is preparing a commercial-scale pilot in association with an unnamed German utility.

Patent application: Thermal storage system and temperature controlled container

Ben Welter - Thursday, January 03, 2019

U.S. patent application 20190003781 (applicants University of Ghent, Belgium; Colruyt Group, Halle, Belgium):

"Passive thermal storage systems and methods comprising at least one thermal storage module for storing thermal energy in a predetermined temperature range, are disclosed. The thermal storage module comprises an FT unit and a Heat Storage (HS) unit at least partially filled with a first Phase Change Material (PCM). The HS unit comprises a container. The thermal storage module may be in the form of a stacked structure comprising the FT unit having a first wall with a first heat exchange surface and the HS unit having a second wall with a second heat exchange surface, the first and second heat exchange surfaces being in thermal contact with each other. The thermal storage system may be used to maintain the temperature of the payload of a temperature controlled container at a predetermined value or within a predetermined range."

http://www.freepatentsonline.com/20190003781.pdf

PCM briefing: Viking Cold Solutions to install system in Mexico; Pluss reaches distribution deal with Ferro-Plast of Italy

Ben Welter - Friday, October 12, 2018

Viking Cold Solutions of Houston, Texas, has reached a deal to install its PCM-based thermal energy storage system in one of Red de Frios' frozen food warehouses in Monterrey, Mexico. Viking systems are designed to reduce energy costs by shifting peak demand to nighttime hours.

• The German Aerospace Center, the Karlsruhe Institute of Technology and the University of Stuttgart have signed an agreement to build a research facility in Germany to develop an efficient, cost-effective and "virtually loss-less" heat-based electrical storage technology. At this week's signing ceremony in Stuttgart, Stanford University Professor Robert B. Laughlin, right, 1998 Nobel Laureate in Physics, explained why he thinks heat storage will play a key role in the energy landscape of the future.

• The Conductive Plastics conference in Vienna Nov. 6-7 will include sessions on "Challenging the boundaries in thermally conductive and electrically conductive polyamides," "Boron nitride filler materials for high-performance thermal management applications," "Mineral flame retardants and metal oxides as thermally conductive fillers," "Investigating the effect of material molecular orientation on thermal conductivity of polymeric products" and "Thermally conductive materials based on synthetic rubber."

• In a LinkedIn post, Pluss Advanced Technologies of India announced it has reached a deal with Ferro-Plast Srl of Italy to distribute Pluss products in Europe.

• New from MarketResearch.biz: "Global Advanced Phase Change Material (PCM) Market Trends, Applications, Analysis, Growth, And Forecast: 2018 To 2027"

• New from Invant Research: "Global Advanced Phase Change Material (PCM) Market Study 2015-2025"

• New from Future Market Insights: "Salt Hydrate Market: Global Industry Analysis 2012 - 2016 and Opportunity Assessment; 2017 - 2027"

• New from Polaris Market Research: "Fatty Acid Esters Market, [By Product Type (Glycerol Monostearate, Medium Chain Trigylcerides, Isopropyl Esters (Myrsitate & Palmitate) and Others); By Application (Lubricants, Pharmaceuticals, Personal care & Cosmetics, Surfactants and Others); By Regions]: Market size & Forecast, 2018 – 2026"

Peli BioThermal has opened service centers in Basel and Berlin to support the company's line of Credo reusable temperature-control shippers.

• Nominations are being accepted for Metrohm USA's Young Chemist Award 2019. Entrants submit an abstract of their research for a chance to win a $10,000 cash prize and an all-expenses-paid trip to PITTCON 2019. The contest is limited to undergrad, grad, post-grad and doctoral students in the United States and Canada. Entrants must demonstrate novel research or a novel methodology using titration, ion chromatography, electrochemistry and/or spectroscopy. Applications are due by Dec. 31, 2018.

Sonoco ThermoSafe, a global provider of temperature assurance packaging in the life sciences sector, has an opening for a sales director, responsible for sales growth in North America.

• Sonoco ThermoSafe has posted the agenda for the next Leading Minds Seminar, to be held Nov. 6-7 in London. Co-hosted by ELPRO, the seminar is a chance for pharmaceutical manufacturers, supply chain partners and government representatives to discuss temperature-assurance packaging and data monitoring in a collaborative environment.

ASHRAE Learning Institute will offer 20 courses during the 2019 ASHRAE Winter Conference and AHR Expo. The conference will be held in Atlanta Jan. 12-16. Courses include "Advanced Designs for Net Zero Buildings," "Thermal Energy Storage Systems for Air Conditioning" and "Solar PV and Thermal System Analysis and Design."

PCM-equipped heat exchanger designed for use in reefer trucks, cold rooms

Ben Welter - Friday, September 14, 2018

A new PCM application turned up in my LinkedIn feed this week:

"Pluss Advanced Technologies Pvt. Ltd. presents ThermoTab active plates used for both #coldstorages and #transportation applications at India Cold Chain Show 2018" ... "Enabling last mile connectivity with fuel free refrigeration."

Vishnu SasidharanThe post offered plenty of hashtags but not much information. I asked Vishnu Sasidharan, right, vice president for new product initiatives at Pluss, for details on the thermoTab Active heat exchanger.

Q: Who developed the thermoTab Active heat exchanger and when was it introduced commercially?

A: "The thermoTab Active heat exchangers are being sourced from FIC, Italy, a company which is has been manufacturing heat exchangers for thermal energy storage in refrigerated vehicles since 1951. Pluss has partnered with FIC to offer complete solution – PCM-filled heat exchangers exclusively in India – introduced commercially in India from September 2017. The partnership leverages FIC & Pluss strength in heat exchanger and material sciences respectively to offer solutions for storage, transportation and space cooling/heating."

Q: What types of PCM are used? (salt hydrate, thermal energy capacity, peak melt point ranges, etc.)

A: "The current standardized offerings are for two categories of temperature; +2 to +8 deg C and -15 to -25 deg C. The plates offered on the basis heat load capacities and the categories under which it falls. For instance, if a customer requires 20kw-Hr of thermal storage capacity for +2 to +8 deg C the number of plates, the customer could refer to the datasheet and choose the combination of thermoTab Active plates based on its capacity. Alternatively, the datasheet also provides with a quick selection of number of thermoTab Active plates based on the volume of the container, insulation thickness and the retention hours required." 

Q: Describe how the heat exchanger functions.

Pluss thermoTab Active plateA: "The heat exchanger plates have a refrigerant coil inside. The PCM filled inside the plate remains completely immersed in the PCM solution. During charging or freezing cycle begins when refrigerant is passed through the coil at a temperature lower than the phase change point of PCM. When the temperature in the room starts to rise above the phase change point of the PCM, the surface of the heat exchangers starts to release the energy at a constant temperature, thereby maintaining the temperature of the environment."

Q: How and when are the PCM panels charged in a refrigerator truck?

A: "The thermoTab Active plates are charged by means of an electric refrigeration system on board the truck. Prior to commencement of the delivery cycle, the truck’s refrigeration system is connected to a three-phase electric source for 8-10 hours. The cost of storing energy by electricity as against active cooling using diesel the savings are substantial. The payback for such system is less than six months."

Q: How and when are the PCM panels charged in a micro cold room?

A: "In a micro cold room as well the charging takes place similar to a refrigerator truck. However, the operating cost could be further reduced by running the refrigerator unit using solar instead of grid electricity. The thermoTab Active plates provides a unique value proposition for solar based micro cold room by enabling 24/7 uninterrupted cooling without the requirement of an electrochemical battery. Most micro cold rooms operate in areas which do not have access to electricity."

Q: How does thermoTab Active differ from passive PCM systems used in reefer trucks and cold rooms?

A: "Passive PCM systems depend on a centralized freezing unit. This makes the process cumbersome for the user as the PCM modules/cartridges need to be constantly removed from the container to a freezer unit and back. It also results in temperature losses due to exposure to ambient temperature during the loading and unloading of PCM modules."

Q: How many refrigerator trucks are using the system?

A: "In India over 250 refrigerator trucks are using this system."

Q: How many micro cold units are using the system?

A: "In India approximately 60 micro cold rooms are using this system. The demand is immense and we believe the application is now beginning to transition from early stage to maturity in terms of market reach."

Q: Is the product available outside India?

A: "It is also available in Africa and southeast Asia."

PCM briefing: Ice Energy seeks distributors in Australia, Mexico and Saudi Arabia; Thermetrics' new manikin can measure PCM effects

Ben Welter - Friday, August 31, 2018

• In an interview with Energy Storage Report, CEO Mike Hopkins discussed Ice Energy's plans to distribute its ice-based thermal energy storage technology in Australia, Mexico and Saudi Arabia. In June, the California company announced a $40 million cash infusion from Argo Infrastructure Partners to finance the delivery of Ice Energy's residential and commercial thermal storage contracts.

Thermetrics manikin ANDIThermetrics says its new ANDI sweating thermal manikin has the "unrivaled ability" to measure both positive and negative heat flux and to respond to changing environmental conditions with "unprecedented" speed and accuracy. The new manikin was unveiled this week at the 12th International Meeting of Manikins and Modeling, hosted by the Swiss research institute Empa, in St. Gallen, Switzerland. The manikin can be used to evaluate the thermal performance of apparel, blankets and seats, as well as quantify the cool-to-touch or warm-to-touch temperature-buffering effect in fabrics containing phase change materials. 

• New from LP Information: "2018-2023 Global Eutectic Phase Change Material Consumption Market Report"

• New from Research and Markets: "Phase Change Materials (PCMs) - A Global Market Overview"

• The journal Nature reports that India is cracking down on predatory journals, publications that "actively solicit manuscripts and charge authors hefty fees without providing the services they advertise, such as editing and peer review." 

• Life science laboratories are finding creative ways to reduce the amount of plastic they throw away, The Scientist reports. 

Sonoco ThermoSafe will hold its next Leading Minds Seminar Nov. 6-7 at the Sheraton Skyline Hotel Heathrow, London, England. Co-hosted by ELPRO, the seminar is a chance for pharmaceutical manufacturers, supply chain partners and government representatives to discuss temperature-assurance packaging and data monitoring in a collaborative environment.

Viking Cold Solutions says the thermal energy storage system the company installed at a 93,000-square-foot frozen food distribution center in Richmond, Calif., has reduced peak period energy consumption by up to 43 percent and reduced overall freezer energy consumption by 35 percent. Viking installed the system at the Dreisbach Enterprises warehouse earlier this year. Plastic panels filled with a proprietary salt hydrate are installed evenly throughout the warehouse atop the existing product racks. The PCM absorbs heat as it melts, allowing chillers to run less frequently and still keep the warehouse within a few degrees of the target temperature. The system also includes intelligent controls and sensors to optimize energy use and alert managers to temperature abnormalities, equipment failure and power outages.

PCM briefing: BASF to spend $2.2 billion on R&D; Sunamp heat batteries qualify for Scottish loan program

Ben Welter - Monday, May 14, 2018

Chemical & Engineering News reports that the top 50 U.S. chemical producers generated $285.4 billion in chemical revenues in 2017, a 9.4 percent increase over 2016. 

• Under its new CEO, Martin Brüdermüller, BASF is planning to pour $2.2 billion into research and development, making BASF the second-highest investor in innovation in the chemicals sector after DuPont

Grace HsiaWarmilu LLC founder Grace Hsia, right, is on Crain's 20 in Their 20s list honoring Michigan's rising young leaders. Warmilu makes a PCM-equipped infant warming blanket.   

Axiom Exergy of Richmond, Calif., has raised $7.6 million in Series A funding, for a total of $12.5 million raised to date. The round was co-led by GXP Investments and Shell Ventures. Axiom's PCM-based "refrigeration battery" is designed to reduce energy supermarket energy costs. 

Sunamp Ltd. is applauding the Scottish government's decision to include heat batteries to its Home Energy Scotland Loan program. Homeowners and private landlords are now eligible to apply for an interest-free loan of up to 6,000 pounds to install Sunamp's PCM-based heat battery systems.

• Albuquerque-based SAVSU Technologies is launching two new high-performance shipping containers branded as Evo Extreme. The containers are designed for the 2-8C and -80C temperature ranges.

Emirates District Cooling has won a contract to supply a district cooling system to the Expo Dubai 2020 event. The system will have a capacity of 60,000 tons of refrigeration. 

• Georg Rodriguez, managing director at MUTZ Engineering mbH, will present a free lecture, presumably in German, on "phase change materials for temperature management and energy storage in buildings" on Tuesday, May 15, at the KEBAB lecture room in Berlin.