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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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Research roundup: Dynamic behavior of PCM-27; Al2O3, SiO2 and TiO2 nano-inclusions; coacervation microencapsulation; more

Ben Welter - Tuesday, August 14, 2018

From International Journal of Thermal Sciences:

An experimental and a numerical analysis of the dynamic behavior of PCM-27 included inside a vertical enclosure: Application in space heating purposes

From Journal of Molecular Liquids:

Thermal conductivity enhancement in organic phase change material (phenol-water system) upon addition of Al2O3, SiO2 and TiO2 nano-inclusions

From Applied Thermal Engineering:

Experimental and numerical investigations of nano-additives enhanced paraffin in a shell-and-tube heat exchanger: A comparative study
Three-dimensional numerical and experimental investigation of the behavior of solar salts within thermal storage devices during phase change

From Energy Conversion and Management:

Formulation of a model predictive control algorithm to enhance the performance of a latent heat solar thermal system
Performance assessment of a new hydrogen cooled prismatic battery pack arrangement for hydrogen hybrid electric vehicles

From Carbohydrate Polymers:

Chitosan composite microencapsulated comb-like polymeric phase change material via coacervation microencapsulation

From Renewable Energy:

Analytical Considerations on Optimization of Cascaded Heat Transfer Process for Thermal Storage System with Principles of Thermodynamics

From Proceedings of Microscopy & Microanalysis 2018:

In-Situ TEM Observation of Crystallization in Phase-Change Material

From International Journal of Energy Research:

Research roundup: Octadecanol/expanded perlite; PV/T system design; macroencapsulated PCM for pavement; more

Ben Welter - Friday, August 10, 2018

From Renewable Energy:

Experimental investigation on thermal properties and thermal performance enhancement of octadecanol/expanded perlite form stable phase change materials for efficient thermal energy storage
Effect of graphite mass concentrations in a mixture of graphite nanoparticles and paraffin wax as hybrid storage materials on performances of solar still

From Renewable and Sustainable Energy Reviews:

A review on recent development for the design and packaging of hybrid photovoltaic/thermal (PV/T) solar systems

From Materials:

Mechanical and Thermal Performance of Macro-Encapsulated Phase Change Materials for Pavement Application

From International Journal of Heat and Mass Transfer:

Heat transfer behavior of elemental sulfur for low temperature thermal energy storage applications
A novel method for determining the melting point, fusion latent heat, specific heat capacity and thermal conductivity of phase change materials
Effect of microstructure on melting in metal-foam/paraffin composite phase change materials

From Chemical Engineering Journal:

Flexible phase change materials for thermal storage and temperature control

From Construction and Building Materials:

Experimental investigation of thermal and mechanical properties of magnesium oxychloride cement with form-stable phase change material

From Solar Energy:

New insights into the corrosion mechanism between molten nitrate salts and ceramic materials for packed bed thermocline systems: A case study for steel slag and solar salt


Research roundup: Solar thermal modeling; finned multitube storage; solid-solid PCM: more

Ben Welter - Wednesday, August 01, 2018

From Applied Thermal Engineering:

Modelling and experimental study of latent heat thermal energy storage with encapsulated PCMs for solar thermal applications

From Journal of Energy Storage:

Estimation of thermal performance and design optimization of finned multitube latent heat thermal energy storage

From Engineering Science and Technology:

Experimental study on heat transfer performance of neopentyl glycol/CuO composite solid-solid PCM in TES based heat sink

From Solar Energy:

Synthesis and characterization of stearic acid/silicon dioxide nanoencapsules for solar energy storage

Research roundup: Silicon carbide for battery thermal management; Stefan moving boundary models; alkali nitrate/nitrite salts; more

Ben Welter - Tuesday, July 24, 2018

From Renewable Energy:

Using Renewables Coupled with Thermal Energy Storage to Reduce Natural Gas Consumption in Higher Temperature Commercial/Industrial Applications

From Solar Energy:

Development of a solar thermal storage cum cooking device using salt hydrate

From Applied Energy:

One-step fabrication of fatty acids/nano copper/polyester shape-stable composite phase change material for thermal energy management and storage
Palmitic acid/polyvinyl butyral/expanded graphite composites as form-stable phase change materials for solar thermal energy storage

From Chinese Journal of Chemical Engineering:

Preparation and phase change performance of Na2HPO4·12H2O@poly(lactic acid) capsules for thermal energy storage

From Applied Thermal Engineering:

Thermal performance of sodium acetate trihydrate based composite phase change material for thermal energy storage
Performance improvement and energy consumption reduction in refrigeration systems using phase change material (PCM)
A thermal conductive composite phase change material with enhanced volume resistivity by introducing silicon carbide for battery thermal management
Numerical and Experimental study on the performance of a new two -layered high-temperature packed-bed thermal energy storage system with changed-diameter macro-encapsulation capsule

From Colloids and Surfaces A: Physicochemical and Engineering Aspects:

Green Nano-encapsulation Technique for Preparation of Phase Change Nanofibers Mats with Core-Sheath Structure
From International Journal of Thermal Sciences:

Analytical and numerical analysis of PCM solidification inside a rectangular finned container with time-dependent boundary condition

From Construction and Building Materials:

Elaboration and properties of a composite bio-based PCM for an application in building envelopes

From International Journal of Heat and Mass Transfer:

Lorentz forces effect on NEPCM heat transfer during solidification in a porous energy storage system
A translucent honeycomb solar collector and thermal storage module for building façades

PCM briefing: Brookins confirmed as Alexium CEO; palmitic acid, stearic acid on U.S. tariff list

Ben Welter - Monday, July 16, 2018

Dr. Robert BrookinsAlexium International has appointed Dr. Robert Brookins, right, as chief executive officer and managing director of the company. Brookins, formerly executive vice president of research and development, was appointed interim CEO in May, replacing Dirk Van Hyning, who resigned for personal reasons. Alexium, based in Greer, S.C., and Perth, Australia, makes flame-retardant and PCM-enhanced fabric treatments.

Palmitic acid, stearic acid and their salts and esters are on a list of more than 6,000 items on which the United States may impose additional import tariffs in its escalating trade war with China.

Two top executives at Wilmar International have stepped down after Greenpeace published a report linking the world's largest palm oil trading company to a supplier accused of deforestation.

Active Energy Systems, a clean-tech startup in Tennessee, is developing an electro-thermal energy storage system that will use waste heat generated by data centers, industrial complexes, institutions and power plants to store and distribute energy more efficiently and cheaply than systems using conventional batteries. "Using power from the grid at off-peak times," Venture Nashville Connections reports, "the process transforms water into ice -- spraying it through an oil layer, which allows the water to freeze but not stick to a submerged heat exchanger. Instead, it forms pellets resembling Dippin' Dots ice cream, [co-founder Mitch] Ishmael said. Then the cycle operates in reverse, using waste heat to melt the ice and generate electricity back to the grid."

• New from Research Mentor:" Global Phase Change Material (PCM) Market will be Worth USD 770.1 Million by 2023"

• New from Questale: "Global Eutectic Phase Change Material Market Research Report 2018"

• "What are some new trends in solar energy research and development in 2018?" a Quora member asked recently. Three answers were posted. The one provided by Yogi Goswami, director of the University of South Florida's Clean Energy Research Center, got more than 120 "upvotes" and was picked up by Forbes magazine. Goswami discussed the strengths and weaknesses of two competing technologies: photovoltaics and concentrating solar power. He expressed confidence that CSP will eventually become commercially competitive because it has two big advantages over PV: "It uses the same thermal power conversion as the conventional thermal power (fossil fuel or nuclear based) and can therefore be integrated with the existing power infra-structure easily" and it "uses thermal energy storage which is about one-tenth the cost of battery storage."

Research roundup: Novel graphite-PCM composite sphere; sunlight-driven energy conversion; PCM-rich concrete overlay; more

Ben Welter - Tuesday, July 10, 2018

From Applied Thermal Engineering:

A Novel Graphite-PCM Composite Sphere With Enhanced Thermo-Physical Properties
Fatty acids based eutectic phase change system for thermal energy storage applications

From Applied Energy:

Mathematical modeling and sensitivity analysis of solar photovoltaic panel integrated with phase change material
Compact liquid cooling strategy with phase change materials for Li-ion batteries optimized using response surface methodology
Multi-parameter optimization design of thermoelectric harvester based on phase change material for space generation

From Solar Energy:

Experimental study on the performance of a novel solar water heating system with and without PCM
Latent thermal energy storage for solar process heat applications at medium-high temperatures – A review
Carbon based material included-shaped stabilized phase change materials for sunlight-driven energy conversion and storage: An extensive review

From Construction and Building Materials:

Application of a PCM-rich concrete overlay to control thermal induced curling stresses in concrete pavements

From Energy Conversion and Management:

Energy investigation of glazed windows containing Nano-PCM in different seasons
Transforming a passive house into a net-zero energy house: a case study in the Pacific Northwest of the U.S.

PCM briefing: Cash infusion for Ice Energy; ASHRAE's new energy audit standard now available

Ben Welter - Monday, July 02, 2018

Ice Energy, make of the Ice Bear and other ice-based energy storage systems, is getting an infusion of cash from a private equity manager. The California startup will receive $40 million from Argo Infrastructure Partners to finance the delivery of its residential and commercial thermal storage contracts.

• "Chemistry for the Non-Chemist," a four-part online course offered by Chemical Watch, promises "a solid introduction to chemistry." The cost: $450.  

ASHRAE Standard 211 is now available for download. The standard "establishes consistent practices for conducting and reporting energy audits for commercial buildings. The standard defines the procedures required to perform Energy Audit Levels 1, 2, and 3; provides a common scope of work for these audit levels for use by building owners and others; c. establishes consistent methodology and minimum rigor of analysis required; and establishes minimum reporting requirements for the results of energy audits." 

Purchase College of New York will get a free replacement for its aging central heating plant, thanks to a collaborative thermal energy storage project from the New York Power Authority and Brenmiller Energy. The R&D project will investigate sensible thermal energy storage as a way to increase the efficiency of a standard combined heat and power system. The new system could save State University of New York $100,000 a year.

Fifty-four academic papers were presented at PCM 2018, the 12th IIR International Conference on Phase Change Materials and Slurries for Refrigeration and Air Conditioning, held in Orford, Canada, last month. "Investigations on the stability of metallic cans for PCM macro-encapsulation," "Investigation of compatibility of organic and inorganic PCMs with the materials of containers" and "Life cycle assessment phase changes of materials, component and system concept" are among the papers posted on the International Institute of Refrigeration website. 

John Lerch, vice president of sales and marketing at thermal energy storage company Axiom Exergy, writes about "5 things utilities should consider for energy storage." 

Wilmar International said it has ceased sourcing from palm oil suppliers allegedly associated with Gama, a company that was accused by Greenpeace of causing deforestation in Indonesia. 

• The Roundtable on Sustainable Palm Oil and Canadian supply chain consultancy Ulula are collaborating to introduce a mobile phone app to report potential workers’ incidents and abuses on palm oil plantations. 

Research roundup: Heat transfer enhancement of PCMs; CuO/palmitic acid composite; cooking applications; more

Ben Welter - Tuesday, June 12, 2018

From Materials Today: Proceedings:

Investigation of thermal performance by applying a solar chimney with PCM towards the natural ventilation of model house under Climate of Thailand
Study of Solar– PCM Walls for domestic hot water production under the tropical climate of Thailand
Improved Performance of Composite Phase Change Material for Thermal Energy Storage
Experimental investigation on freezing/melting characteristics of two different phase change materials
Review on Heat Transfer Enhancement of Phase Change Materials (PCMs)
Experimental Investigation of Improved Thermal Characteristics of Al2O3/Barium Hydroxide Octa Hydrate as Phase Change Materials (PCMs)
Improved Thermal Energy Storage Behavior of CuO/Palmitic acid Composite as Phase Change Material

From Applied Thermal Engineering:

An Experimental Investigation of the Melting Process of a Bio-based Nano-PCM filled Vertical Cylindrical Thermal Energy Storage System

From International Journal of Heat and Mass Transfer:

Experimental investigation of the effects of mass fraction and temperature on the viscosity of microencapsulated PCM slurry

From Journal of the Brazilian Society of Mechanical Sciences and Engineering:

Rapid thermal cycling of three phase change materials (PCMs) for cooking applications

From 3rd Thermal and Fluids Engineering Conference:

Use of Wood/Phase Change Material Composite in the Building Envelope for Building Thermal Control and Energy Savings

Research roundup: N-octadecane/polystyrene/expanded graphite composites; decorative wood-based panels for thermal energy storage; more

Ben Welter - Monday, June 11, 2018

From Energy:

Experimental investigation on n–octadecane/polystyrene/expanded graphite composites as form–stable thermal energy storage materials

From Green Energy and Environment:

Thermal characterization of bio-based phase changing materials in decorative wood-based panels for thermal energy storage

From Chemical Engineering Science:

Melt-Front Propagation and Velocity Profiles in Packed Beds of Phase-Change Materials Measured by Magnetic Resonance Imaging

From Thermal Science and Engineering Progress:

Employment of Finned PCM Container in a Household Refrigerator as a Cold Thermal Energy Storage System

From Energy Conversion and Management:

Melting and solidification of PCM embedded in porous metal foam in horizontal multi-tube heat storage system
Evaluation of paraffin infiltrated in various porous silica matrices as shape-stabilized phase change materials for thermal energy storage

From Construction and Building Materials:

Potential applications of phase change materials to mitigate freeze-thaw deteriorations in concrete pavement
A practical ranking system for evaluation of industry viable phase change materials for use in concrete
Experimental and numerical study of thermal performance of the PCM wall with solar radiation
Utilizing blast furnace slags (BFS) to prepare high-temperature composite phase change materials (C-PCMs) 

From International Journal of Thermophysics:

Behavior of a PCM at Varying Heating Rates: Experimental and Theoretical Study with an Aim at Temperature Moderation in Radionuclide Concrete Encasements

Patent application: Compositions comprising PCM and methods of making the same

Ben Welter - Monday, June 04, 2018

U.S. patent application 20180148621 (applicant Phase Change Energy Solutions Inc., Asheboro, S.C.):

"In one aspect, compositions are described herein. In some embodiments, a composition comprises a phase change material, a hydrophobic sorption material, and a viscosity modifier. In some embodiments, a composition comprises a foam and a latent heat storage material dispersed in the foam, the latent heat storage material comprising a phase change material and a hydrophobic sorption material."

http://www.freepatentsonline.com/20180148621.pdf