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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.




INUTEQ donates hundreds of cooling vests to Dutch hospitals

Ben Welter - Monday, May 11, 2020

Hundreds of INUTEQ cooling vests developed for use by Dutch athletes at the Tokyo Olympics this summer have been donated for use in Dutch hospitals during the COVID-19 pandemic.

INUTEQ PCM pulloverThe PCM-equipped pullovers, designed to help athletes cope with heat stress, became available when the Tokyo Games were postponed until 2021. The pullovers can be worn under the heavy, heat-trapping protective gear used by doctors and nurses.

The pullovers are manufactured in Netherlands. The cooling material is Croda's CrodaTherm 21, a biobased PCM with a melting temperature of 21 degrees C. The 1.3-kg pullover is a simple "one-size-fits-most" garment, with two adjustable buckles and no fabric shell. 

“Doctors and nurses at the ICU, who are treating corona patients, can work comfortably for up to three hours longer thanks to this cooling vest," said Dr. Thijs Eijsvogels, physiologist at Radboud University Medical Center, Nijmegen. "The cooling vests ensure a stable body temperature, less sweating, maintenance of concentration and a faster recovery after each intensive work session.”

The pullover is marketed as "PCM CoolOver" on the INUTEQ website. It can be worn "under military combat gear, hazardous materials suits, mascot costumes and other professional apparel."

Phase Energy announces a new shape-stable PCM

Ben Welter - Monday, May 11, 2020

Phase Energy Ltd. has announced the development of shape-stable technology for organic wax-based PCMs.

The company, based in Hull, United Kingdom, said a tetradecane-based shape-stable material would typically contain more than 90% PCM; the new technology has achieved levels of up to 96%. "Initial tests indicate that little, if any, enthalpy is lost, possibly due to the very low level of additives required," the company said.

The technology was jointly developed with Rainer Busch of IBC Europe, Germany.

"So far, the technology has been used for paraffins, esters etc. and on a range of PCMs with [melt points] of up to 53 degrees Centigrade," Phase Energy said in a LinkedIn post. "The technology permits the production of leak-resistant packs/pouches using very simple process technology." 

"We’re currently working with some companies in the cold chain area; looking at cold packs/pouches, pallet covers etc.," Ian Biggin, director at Phase Energy, said in an e-mail. "As the technology can be adapted to higher temperature PCMs we are also interested in those areas as well but we decided that cold chain was the obvious place to start."

The photo below illustrates the material's flexibility. According to the company, it "shows a shape stable sample, 100 x 30 x 12mm, containing 92% tetradecane and 8% additives, being stretched to >700mm. When released the sample returned to its original size."

Research roundup: Polythioether-based PCMS; alginate encapsulation; temperature stresses in concrete pavement; more

Ben Welter - Friday, May 08, 2020

From European Polymer Journal:

Extremely fast synthesis of polythioether based phase change materials (PCMs) for thermal energy storage

From Journal of Building Engineering:

Thermal behavior analysis of hollow bricks filled with phase-change material (PCM)

From Energies:

FEM Applied to Building Physics: Modeling Solar Radiation and Heat Transfer of PCM Enhanced Test Cells

From Iranian Polymer Journal:

Encapsulation of phase change materials with alginate modified by nanostructured sodium carbonate and silicate

From Energy & Fuels:

Aluminium ammonium sulfate dodecahydrate with multiple additives as composite phase change materials for thermal energy storage

From Materials Today: Proceedings:

Evaluation and reduction of temperature stresses in concrete pavement by using phase changing material
Optimization of Heat Energy Based on Phase Change Materials used in Solar Collector using Taguchi Method
Experimental and Theoretical Investigations on Thermal Conductivity of the Paraffin Wax using CuO Nanoparticles

From Journal of Energy Storage:

Novel synthesis of silica coated palmitic acid nanocapsules for thermal energy storage
Recent progress in phase change materials storage containers: Geometries, design considerations and heat transfer improvement methods
Effect of phase separation and supercooling on the storage capacity in a commercial latent heat thermal energy storage: Experimental cycling of a salt hydrate PCM
Energy efficiency optimization of the waste heat recovery system with embedded phase change materials in greenhouses: A thermo-economic-environmental study
Characterization of innovative mortars with direct incorporation of phase change materials

From Applied Thermal Engineering:

A trade study of a phase change system in a stratospheric airship based on a triple gasbag concept
Experimental evaluation of structural insulated panels outfitted with phase change materials
Lattice Boltzmann simulation of melting heat transfer in a composite phase change material

From Geothermics:

Parametric modeling and simulation of low temperature energy storage for cold-climate multi-family residences using a geothermal heat pump system with integrated phase change material storage tank

From Energy:

Multi-level uncertainty optimisation on phase change materials integrated renewable systems with hybrid ventilations and active cooling
A novel solar thermal system combining with active phase-change material heat storage wall (STS-APHSW): Dynamic model, validation and thermal performance

From Advances in Energy Research:

Theoretical Modeling of Phase Change Material-Based Space Heating Using Solar Energy

From Chemical Engineering Journal:

High latent heat and recyclable form-stable phase change materials prepared via a facile self-template method

From Composites Part B: Engineering:

In situ one-step construction of monolithic silica aerogel-based composite phase change materials for thermal protection

From Solar Energy:

Effects of external insulation component on thermal performance of a Trombe wall with phase change materials

From Journal of Architectural Engineering:

Experimental and Numerical Thermal Properties Investigation of Cement-Based Materials Modified with PCM for Building Construction Use

From Energy Conversion and Management:

Experimental and numerical study on the thermal performance of ventilated roof composed with multiple phase change material (VR-MPCM)

From Construction and Building Materials:

Multi-scale analysis on thermal properties of cement-based materials containing micro-encapsulated phase change materials

From Applied Energy:

D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability
Novel bio-based phase change materials with high enthalpy for thermal energy storage

From Materials Today Energy:

A detailed review on heat transfer rate, supercooling, thermal stability and reliability of nanoparticle dispersed organic phase change material for low-temperature applications

From International Journal of Thermal Sciences:

Experimental study and assessment of high-tech thermal energy storing radiant floor heating system with latent heat storage materials

From Advanced Powder Technology:

Paraffin core-polymer shell micro-encapsulated phase change materials and expanded graphite particles as an enhanced energy storage medium in heat exchangers

Research roundup: Corn oil PCM in frozen food cooling machine; portable solar box cooker; expanded graphite/1-octadecanol composite; more

Ben Welter - Saturday, March 21, 2020

From Journal of Physics:

Corn oil phase change material (PCM) in frozen food cooling machine to improve energy efficiency

From Materials Today: Proceedings:

Investigating thermal properties of Nanoparticle Dispersed Paraffin (NDP) as phase change material for thermal energy storage

From Energy:

Effects of fluctuating thermal sources on a shell-and-tube latent thermal energy storage during charging process

From Solar Energy:

Design, realization, and tests of a portable solar box cooker coupled with an erythritol-based PCM thermal energy storage
Diversiform microstructure silicon carbides stabilized stearic acid as composite phase change materials

From International Journal of Thermofluids:

Investigating the performance of a thermal energy storage unit with paraffin as phase change material, targeting buildings’ cooling needs: an experimental approach

From Journal of Cleaner Production:

Energy and exergy analysis of wind farm integrated with compressed air energy storage using multi-stage phase change material

From Powder Technology:

Effect of nano-SiC on thermal properties of expanded graphite/1-octadecanol composite materials for thermal energy storage

From Journal of Energy Storage:

A multi-objective optimal design method for thermal energy storage systems with PCM: A case study for outdoor swimming pool heating application
Reducing PV module temperature with radiation based PV module incorporating composite phase change material
Numerical investigation on the effect of fin design on the melting of phase change material in a horizontal shell and tube thermal energy storage

From Journal of Thermal Analysis and Calorimetry:

Characterization of form-stable phase-change material for solar photovoltaic cooling

From International Journal of Thermophysics:

Thermophysical Properties of a Novel Nanoencapsulated Phase Change Material

From International Journal of Heat and Mass Transfer:

Lattice Boltzmann simulation of forced convection melting of a composite phase change material with heat dissipation through an open-ended channel
High power density thermal energy storage using additively manufactured heat exchangers and phase change material

From Energies:

Evaluation of the State of Charge of a Solid/Liquid Phase Change Material in a Thermal Energy Storage Tank [pdf]
Novel Simulation Algorithm for Modeling the Hysteresis of Phase Change Materials [pdf]

From Energy & Fuels:

Novel shape-stabilized phase change materials based on paraffin/EPDM@graphene with high thermal conductivity and low leakage rate

From Polymers and Polymer Composites:

Regulating phase-change temperatures of form-stable phase-change ternary composite fibrous membranes consisting of polystyrene nanofibers and fatty acid eutectics via co-electrospinning method

From Applied Energy:

A design protocol for enhanced discharge exergy in phase change material heat battery
Fabrication of heat storage pellets composed of microencapsulated phase change material for high-temperature applications
A high-thermal-conductivity, high-durability phase-change composite using a carbon fibre sheet as a supporting matrix

From Journal of Building Engineering:

Preparation and characterization of metal-organic framework /microencapsulated phase change material composites for indoor hygrothermal control

From Indoor and Built Environment:

Numerical and experimental investigation on dynamic thermal performance of floor heating system with phase change material for thermal storage

From Applied Clay Science:

A triply synergistic method for palygorskite activation to effectively impregnate phase change materials (PCMs) for thermal energy storage

From Chemical Engineering Journal:

Lignin-fatty acid hybrid nanocapsules for scalable thermal energy storage in phase-change materials

From Construction and Building Materials:

Phase change materials for pavement applications: A review

From Carbohydrate Polymers:

Shape-stabilization of polyethylene glycol phase change materials with chitin nanofibers for applications in “smart” windows

PCM briefing: Ice Energy files for bankruptcy; Viking Cold has opening for thermal engineer

Ben Welter - Monday, February 10, 2020

Ice Energy, the Santa Barbara, Calif., company that made and distributed ice-based thermal energy storage systems, has filed for bankruptcy. The company's Ice Bear system makes ice at night when demand for electricity is low and capacity is abundant. During the day, the stored ice is used to provide cooling. Details of the Chapter 7 bankruptcy, filed in December, are sparse. The company's website is no longer active. Over the years, Ice Energy had won several major energy storage and distribution contracts with utilities, and had begun marketing a smaller version of the Ice Bear system aimed at retail customers. 

Viking Cold Solutions has an opening for a chemical/thermal engineer in Houston. The engineer will "conduct research in Thermal Science, Storage/Heat Transfer and Phase Change Materials (PCM) for low temperature applications (<10⁰C)."

Axiom Exergy has secured more than $1 million in orders for the Axiom Cloud, a software platform that helps manage energy consumption in supermarkets and cold storage facilities that use the company's PCM-powered thermal storage systems.

• The 2020 Advancements in Thermal Management conference, to be held Aug. 6-7 in Denver, has issued a call for presentations. Topics include thermal materials, thermal modeling and characterization and measurement of thermal materials. Abstracts are due Feb. 12.

EnergyNest will install a large thermal energy storage battery at a Senftenbacher brick factory in Austria. The system will temporarily store excess energy in the form of hot air from a tunnel furnace. The stored heat be converted to steam and later reused in production.

Devan Chemicals, the Belgium-based developer of finishing technologies for textiles, introduced its Tones of Cool Bio technology at the Heimtextil trade show in Frankfurt, Germany, last month. The technology "stimulates the textile to dissipate redundant heat from the body and to instantly reduce the body temperature," the company says. The phase change materials "are derived from sustainable, natural sources.

Registration is open for the 23rd Microencapsulation Industrial Convention to be held June 8-11 in Rotterdam, Netherlands.

PCM newsletter marks 5th anniversary

Ben Welter - Tuesday, January 14, 2020

The Phase Change Matters newsletter is celebrating its fifth anniversary with the publication of issue No. 224. Only a handful of folks received issue No. 1; the first issue of 2020 was e-mailed to 1,303 subscribers. More than 40,000 people from more than 160 countries visited last year. Here are the most-viewed newsletter posts from 2019:

1. PureTemp introduces temperature-control fabric coating (Jan. 23)

2. New dorm at Massachusetts college features 18,000+ square feet of PCM mats (Aug. 15)

3. Croda began work on new microencapsulated PCM four years ago (July 26)

4. PCM-equipped infant warming mat set for large-scale trial in Rwanda (Jan. 7)

5. Novel PCM microspheres keep new therapy pack flexible when frozen (June 15)

6. Croda adds 2 biobased phase change materials to its lineup (May 17)

7. PCM system inefficiencies blamed on design flaws, operator errors (March 25)

8. Sunamp signs agreement with Chinese heat pump maker (March 18)

9. PureTemp shows energy-saving potential in EnergyPlus simulations (Aug. 28)

10. Microtek introduces new PCM built with nextek encapsulation technology (March 11)

Research roundup: Carbonized waste tires; cetyl palmitate/nickel foam; hydrated salt corrosion assessment; more

Ben Welter - Tuesday, January 14, 2020

From Waste Management:

Evaluation of carbonized waste tire for development of novel shape stabilized composite phase change material for thermal energy storage

From Journal of Energy Storage:

Development of polyurethane foam incorporating phase change material for thermal energy storage
Facile synthesis and thermal performance of cetyl palmitate/nickel foam composite phase change materials for thermal energy storage
Optimal sizing design and operation of electrical and thermal energy storage systems in smart buildings

From Energy Conversion and Management:

Numerical investigation of the effects of the nano-enhanced phase change materials on the thermal and electrical performance of hybrid PV/thermal systems
Thermal storage and thermal management properties of a novel ventilated mortar block integrated with phase change material for floor heating: an experimental study

From Applied Energy:

Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage

From Renewable Energy:

Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems
Experimental study on latent thermal energy storage system with gradient porosity copper foam for mid-temperature solar energy application
Selection of a phase change material and its thickness for application in walls of buildings for solar-assisted steam curing of precast concrete
Experimental assessment of Phase Change Material (PCM) embedded bricks for passive conditioning in buildings

From Applied Thermal Engineering:

Analysis of energy retrofit system using latent heat storage materials applied to residential buildings considering climate impacts
Experimental and numerical simulation of phase change process for paraffin/expanded graphite/ethylene-vinyl acetate ternary composite
An experimental investigation on the evaporation of polystyrene encapsulated phase change composite material based nanofluids

From Solar Energy Materials and Solar Cells:

Lightweight mesoporous carbon fibers with interconnected graphitic walls for supports of form-stable phase change materials with enhanced thermal conductivity

From Energies:

The Effects of Fin Parameters on the Solidification of PCMs in a Fin-Enhanced Thermal Energy Storage System

From Journal of Materials Science:

Graphene aerogel-based phase changing composites for thermal energy storage systems

From Journal of Mechanical Science and Technology:

A study on development of the thermal storage type plate heat exchanger including PCM layer

From Journal of Power Sources:

Delayed liquid cooling strategy with phase change material to achieve high temperature uniformity of Li-ion battery under high-rate discharge

From Scientific Reports:

Modification of asphalt mixtures for cold regions using microencapsulated phase change materials

From ASES National Solar Conference:

A Study on the Thermal Energy Storage System Using Multiple PCMs [pdf]

From Molecules:

Assessment of Thermal Performance of Textile Materials Modified with PCM Microcapsules Using Combination of DSC and Infrared Thermography Methods

From Energy and Buildings:

Experimental study on thermal performance of a mobilized thermal energy storage system: A case study of hydrated salt latent heat storage

From Chemical Engineering Journal:

Shape-stabilized hydrated salt/paraffin composite phase change materials for advanced thermal energy storage and management

From International Journal of Heat and Mass Transfer:

A conjugate heat transfer model for unconstrained melting of macroencapsulated phase change materials subjected to external convection

Research roundup: Passive cooling in buildings; honeycomb carbon fibers; leak-free aggregates; more

Ben Welter - Monday, October 14, 2019

From Applied Energy:

Passive cooling through phase change materials in buildings. A critical study of implementation alternatives

From Applied Thermal Engineering:

Honeycomb carbon fibers strengthened composite phase change materials for superior thermal energy storage

From e-Polymers:

Fabrication and characterization of conductive microcapsule containing phase change material

From Construction and Building Materials:

Preparation and characterization of nano-SiO2/paraffin/PE wax composite shell microcapsules containing TDI for self-healing of cementitious materials
Development of leak-free phase change material aggregates
Behavior of cementitious mortars with direct incorporation of non-encapsulated phase change material after severe temperature exposure

From Advanced Functional Materials:

Engineering the Thermal Conductivity of Functional Phase‐Change Materials for Heat Energy Conversion, Storage, and Utilization

From Journal of Energy Storage:

A numerical investigation of the effects of metal foam characteristics and heating/cooling conditions on the phase change kinetic of phase change materials embedded in metal foam
Applications of combined/hybrid use of heat pipe and phase change materials in energy storage and cooling systems: A recent review
Innovative composite sorbent for thermal energy storage based on a SrBr2·6H2O filled silicone composite foam

From ACS Applied Nano Materials:

Concentrated Ag Nanoparticles in Dodecane as Phase Change Materials for Thermal Energy Storage

From Materials Research Express:

Preparation of 1-dodecanol microcapsules with cellulose nanofibers-modified melamine-formaldehyde resin as a potential phase change material

From IOP Conference Series: Earth and Environmental Science:

Optimisation of Parameters in Thermal Energy Storage System by Enhancing Heat Transfer in Phase Change Material

From International Journal of Heat and Mass Transfer:

Thermal transport properties at interface of fatty acid esters enhanced with carbon-based nanoadditives

From Journal of Solar Energy Engineering:

Using a Novel Phase Change Material-Based Cooling Tower for a Photovoltaic Module Cooling

From Solar Energy:

Experimental investigation on micro-scale phase change material based on sodium acetate trihydrate for thermal storage

From RSC Advances:

A novel forced separation method for the preparation of paraffin with excellent phase changes

From Energy Conversion and Management:

Experimental characterisation of a novel thermal energy storage based on open-cell copper foams immersed in organic phase change material

Research roundup: Mesoporous silica; nanoencapsulation of oleic acid PCM; flexible crosslinking; more

Ben Welter - Friday, September 20, 2019

From International Journal of Energy Research:

Facile functionalized mesoporous silica using biomimetic method as new matrix for preparation of shape‐stabilized phase‐change material with improved enthalpy
Binary mixtures of fatty alcohols and fatty acid esters as novel solid‐liquid phase change materials

From Journal of Applied Polymer Science:

Phase change material with flexible crosslinking for thermal energy storage

From Journal of Thermal Analysis and Calorimetry:

Nanoencapsulation of oleic acid phase change material with Ag2O nanoparticles-based urea formaldehyde shell for building thermal energy storage

From Renewable Energy:

Enhanced properties of diatomite-based composite phase change materials for thermal energy storage

From Energy:

Perspectives for short-term thermal energy storage using salt hydrates for building heating
Design and construction of mesoporous silica/n-eicosane phase-change nanocomposites for supercooling depression and heat transfer enhancement
Numerical investigations on performance of phase change material Trombe wall in building

From Energy and Buildings:

Potential of energy flexible buildings: evaluation of DSM strategies using building thermal mass
Numerical analysis in a full-scale thermal energy storage tank with dual PCM capsules

From Applied Thermal Engineering:

Experimental determination and fractal modeling of the effective thermal conductivity of autoclave aerated concrete (AAC) impregnated with paraffin for improved thermal storage performance
Preparation and characterization of new nano-particle mixed as thermal storage material
Numerical investigation on integrated thermal management for a lithium-ion battery module with a composite phase change material and liquid cooling

From Chemical Engineering Journal:

Fatty Amines/Graphene Sponge Form-Stable Phase Change Material Composites with Exceptionally High Loading Rates and Energy Density for Thermal Energy Storage

From MATEC Web of Conferences:

Thermal conductivity of aerated concrete (AC) composites containing micro-encapsulated phase change materials [pdf]
Overheating mitigation in buildings: a computational exploration of the potential of phase change materials [pdf]

From Solar Energy:

Experimental study on the thermal performance of capric acid-myristyl alcohol/expanded perlite composite phase change materials for thermal energy storage

From Solar Energy Materials and Solar Cells:

Graphitization as efficient inhibitor of the carbon steel corrosion by molten binary nitrate salt for thermal energy storage at concentrated solar power
A strategy for designing microencapsulated composite phase change thermal storage materials with tunable melting temperature

From Institute of Electronics and Information Engineers 2019 Summer Conference:

Thermal Management System in Electric vehicle Battery Pack Using Phase Change Material

From Materials Chemistry and Physics:

Preparation and thermal properties of n-eicosane/nano-SiO2/expanded graphite composite phase-change material for thermal energy storage

From Sustainable Cities and Society:

Simulative optimization on energy saving performance of phase change panels with different phase transition temperatures

From Thermochimica Acta:

The stability and thermophysical properties of a thermal fluid containing surface-functionalized nanoencapsulated PCM

From International Journal of Heat and Mass Transfer:

Functionalized mesoporous silica as matrix for shape-stabilized phase change materials

From Applied Energy:

Synthesis and characterization of microencapsulated sodium sulfate decahydrate as phase change energy storage materials

From Energy Conversion and Management:

Prototype latent heat storage system with aluminum-silicon as a phase change material and a Stirling engine for electricity generation

From Journal of Solar Energy Engineering:

Experimental Investigation and Numerical Modeling of Room Temperature Control in Buildings by the Implementation of Phase Change Material in the Roof
Suitability Assessment and Experimental Characterization of Phase Change Materials for Energy Conservation in Indian Buildings

PCM briefing: Glacier Tek sponsors wheelchair cyclists in Kenya fundraiser; CCT closer to commercializing silicon battery

Ben Welter - Monday, September 09, 2019

Dom Coleman, Regain trustee and grants officerGlacier Tek LLC of Minneapolis is sponsoring seven quadriplegic cyclists taking part in a fundraising ride in Kenya's Rift Valley next month. The Kenya Cycle Challenge 2019, organized by Regain, a U.K.-registered charity, is on track to raise 80,000 pounds to support quadriplegic athletes in Great Britain. More than 50 riders are expected to participate. The seven sponsored riders will be wearing PureTemp-powered Glacier Tek cooling vests to help them handle the 32º C heat they will likely encounter on the five-day ride. People with spinal cord injuries are vulnerable to heat stress because their bodies cannot send the signals needed to initiate sweating in response to hot conditions. 

• Heat battery manufacturer Sunamp Ltd. is among the exhibitors at the InstallerSCOTLAND trade show in Glasgow, Scotland, on Thursday.

CCT Energy Storage is on track to install its first commercial thermal energy device at a mobile phone base station in Adelaide, South Australia, before the end of the year following an agreement in principle with an Australian infrastructure provider. CCT unveiled its first 24kW device in March, describing it as the world’s first working thermal battery using silicon as a phase change material.  

• Hundreds of Australia’s most environmentally advanced homes will open their doors to visitors on Sunday, Sustainable House Day 2019. At least two of the homes – Farrell’s House in Narara, New South Wales, and the 10 Star Home in Cape Paterson, Victoria – feature phase change technology. More than 33,000 people visited 226 homes across Australia last year.