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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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PCM briefing: Registration open for PCM 2018 in Quebec; MIT finds new way to mix oil, water

Ben Welter - Friday, November 10, 2017

• Registration is open for PCM 2018, the 12th IIR Conference on Phase Change Materials and Slurries for Refrigeration and Air Conditioning. The conference will be held May 21-23, 2018, in Orford, Québec. Topics will include thermal energy storage; thermophysical and rheological properties of PCMs and slurries; and transport phenomena and time-dependent behavior of PCMs and slurries.

MIT researchers have developed a new way to mix oil and water and create an emulsion that remains stable for long periods — no shaking required.

• Registration is open for "Towards a Sustainable Solution to Melt Snow and Ice on Concrete Pavement: Use of Phase Change Materials, a presentation by Dr. Yaghoob Farnam, an assistant professor in the Department of Civil, Architectural and Environmental Engineering at Drexel University. Farnam will discuss his research on the use of PCM-enhanced concrete to inhibit the buildup of snow and ice on pavement. The program will be held Nov. 30 in King of Prussia, Penn.

• "Innovative Thoughts" blogger Harvey Wade visited the 3M Customer Innovation Centre in Bracknell, U.K., last month to find out how the big company sustains its innovative edge. Lesson No. 1: 3M listens to its customers. "They don’t guess what the customer needs," Wade writes, "they invest their time to know their needs, discovering the big problems that they can try to solve." 

BMW PCM Ride jacketBMW's 2018 Motorrad collection includes the latest version of the PCM Ride jacket, featuring microencapsulated phase change material that "adapts permanently and smartly to the current temperature."

Peli BioThermal has opened a service center in Brussels, Belgium, to handle its Credo line of reusable temperature-controlled packaging. 

Ember Technologies' newest temperature-control product, a $79 ceramic mug with an active heating system, contains no phase change material. The company's first product, a PCM-lined travel tumbler, sells for $150.

Grace Hsia, founder and CEO of Warmilu, a Michigan startup that makes an infant warming blanket, talks about the stresses and rewards of building a company from scratch. "I find my body will sometimes crash," Hsia told Crain's Detroit Business, explaining how 90-hour workweeks have led to bouts of pneumonia and bronchitis. "I've been trying to get more sleep, which is tough."

The preliminary program has been released for the fifth Building Enclosure Science & Technology conference, known as BEST5. It will take place April 15-18 in Philadelphia. 

• The American Chemical Society has won its lawsuit against Sci-Hub, a widely used pirate site for scientific papers that was established in 2011 by former neuroscientist Alexandra Elbakyan.

• New from Intellectual Research Partners: "Global Thermal Energy Storage (TES) systems Market By Technology (Molten salt, Phase change materials, Water based, Electric thermal and Solar) End User Application (Air Conditioning, Cold Storage, Power Storage, Process Cooling) Region (North America, Europe, APAC) Forecast To 2023"

PCM briefing: Survey finds chemists think field is short on innovation; Lufthansa Cargo partners with va-Q-tec

Ben Welter - Monday, October 30, 2017

• A recent survey by Reaxys found that many chemists don’t think the field is innovative enough. Eighty percent said there is too much emphasis on research with industrial applications, which is stifling innovation. Reaxys is a chemistry research tool developed by Elsevier

Min Zhu, assistant professor of textile development and marketing at the Fashion Institute of Technology, will speak about the future of phase change materials at a textiles conference in New York City Nov. 8. 

Lufthansa Cargo has partnered with va-Q-tec AG to offer the temperature-controlled specialist's va-Q-tainer thermal containers across the German carrier’s global network.

• Scientists investigating how scavenging animals are adapting to the monoculture palm oil plantations in Borneo were surprised by what turned up in their traps. "In the jungles and border regions, the team found animals such as civets, otters, mongooses and pigs," Oils & Fats International magazine reports. "But the closer they got to the plantations where the land had been disturbed and human activity was frequent, the fewer species they found until only one stood out – the Southeast Asian water monitor." The big lizards are thriving, thanks to a plentiful supply of food and less competition from mammalian scavengers and predators. 

• Researchers at the University of Maryland have developed a thermally conductive and strong textile from fibers of aligned boron nitride nanosheets embedded in a polymer matrix that can cool a person down by up to 2° C.  

Patent application: Cellulosic fibers with enhanced reversible thermal properties

Ben Welter - Monday, August 28, 2017

U.S. patent application 20170241045 (applicant Outlast Technologies LLC, Golden, Colo.):

"A cellulosic fiber includes a fiber body including a cellulosic material and non-encapsulated phase change material dispersed within the cellulosic material. The non-encapsulated phase change material forms a plurality of distinct domains dispersed within the cellulosic material. The non-encapsulated phase change material has a latent heat of at least 40 Joules per gram and the cellulosic fiber has a latent heat between 9.8 Joules per gram and 132 Joules per gram and a transition temperature in the range of 0° C. to 100° C., and cellulosic fiber provides thermal regulation based on at least one of absorption and release of the latent heat at the transition temperature."

http://www.freepatentsonline.com/20170241045.pdf

Ethylene glycol improves performance of SAT for use in warming apparel

Ben Welter - Monday, August 21, 2017

Scientists at India's Defense Laboratory Jodhpur and the Indian Institute of Technology-Jodhpur have designed a sodium acetate trihydrate-ethylene glycol composite phase change material that could be used in vests and other apparel to protect the wearer from frostbite and hypothermia.

The addition of ethylene glycol in aqueous SAT "enhances the softness of SAT crystallites, its degree of supercooling and most importantly the effective heat releasing time by ~10%," the researchers explained in a paper published last month in Nature's Scientific Reports. 

https://www.nature.com/articles/s41598-017-05310-3

Research roundup: PCM-assisted night purge ventilation; dispersed metallic nanoparticles; crystallohydrates; more

Ben Welter - Tuesday, June 20, 2017

Nanoencapsulated crystallohydrate mixtures for advanced thermal energy storage [Journal of Materials Chemistry A]

Hexadecane-in-water emulsions as thermal-energy storage and heat transfer fluids: Connections between phase-transition temperature and period of hexadecane droplets dispersed in hexadecane-in-water emulsions and characteristics of surfactants [Colloids and Surfaces A: Physicochemical and Engineering Aspects]

Evaluating the Performance of American Change Phase Paraffin Cooling Vest and Iranian Spadana Gel Ice Cooling Vest on the Perceptual and Physiological Strain Score Index in Hot and Humid Working Conditions of Assaluyeh in Iran [International Journal of Occupational Hygiene]

Development of thermal enhanced n-octadecane/porous nano carbon-based materials using 3-step filtered vacuum impregnation method [Thermochimica Acta]

The impact of phase change materials assisted night purge ventilation on the indoor thermal conditions of office buildings in hot-arid climates [Energy and Buildings]

Thermal energy harvest in the discharge of CO2 semi-clathrate hydrate in an emulated cold storage system [Applied Thermal Engineering]

Melting dynamics of a phase change material (PCM) with dispersed metallic nanoparticles using transport coefficients from empirical and mean field models [Applied Thermal Engineering]

Comparative assessment of thermal comfort with insulation and phase change materials utilizations in building roofs and walls [pdf] [Advanced Materials Proceedings]

Fabrication and properties of graphene oxide-grafted-poly(hexadecyl acrylate) as a solid-solid phase change material [Composites Science and Technology]

PCM briefing: Viking Cold Solutions lands deal in Phoenix; study finds ARPA-E is doing what it was designed to do

Ben Welter - Monday, June 19, 2017

Viking Cold Solutions has announced a collaboration between Salt River Project and Bashas' Supermarkets to install and evaluate the performance of Viking's PCM-based thermal energy storage system at Bashas' distribution center in the Phoenix area. The system is expected to significantly reduce energy costs by shifting peak demand to nighttime hours.

A six-year study finds that ARPA-E, the U.S. Energy Department program that supports cutting-edge energy technologies, is meeting the goals of the 2007 law that created it even as the Trump administration seeks to eliminate its funding. The National Academies of Sciences, Engineering and Medicine report concludes that the program is moving in the right direction and does not require major changes to keep bringing new energy technologies to market.

• The co-creator of a camisole that uses phase change material to reduce the discomfort of hot flashes is profiled in ChicagoInno this month. Nancy Munro, who is selling "CoolCami" online, hopes to partner with a women’s undergarment company like Spanx or Soma. CoolCami is made of absorbent bamboo fabric and features a PCM-filled cooling liner.

Peli BioThermal reports that its ProMed thermal transport bags performed well in a five-month trial in the United Kingdom. The Great North Air Ambulance Service used the bags to transport blood plasma to accident scenes.

Ministry of Supply, the Boston startup that integrates phase change material in its high-tech menswear, has added a lightweight polo shirt to its lineup. The machine-washable Apollo 3 Polo sells for $70. 

Axiom Exergy, maker of "refrigeration batteries" designed to reduce energy use in supermarkets, is looking to fill eleven positions, including product engineer, product engineer manager and engineering intern. Candidates for the internship are asked to give a concise response to a "bonus question": "Given the choice between pure water and a NaCl-water solution as the thermal energy storage medium in medium temperature (40°F, 4.4°C) refrigeration applications, what are the pros and cons of each material?"

CIC energiGUNE is looking for a laboratory technician to join the Thermal Energy Storage unit's materials development and characterization group.

• The European Commission, in with collaboration with Skanska, Saint-Gobain, Sustainable Building Alliance and Green Building Councils, has developed an open-source assessment framework for measuring the energy performance of buildings. Level(s) links a building’s environmental impact with resource priorities at the European level. The voluntary tool will be ready for testing this fall.

Va-Q-tec AG has established a Japanese subsidiary in Tokyo. The German company develops, manufactures and sells vacuum insulation panels and phase change materials for use in thermal packaging, air freight containers and other applications. Va-Q-tec Japan GK will focus on providing "small box and container sales and rental solutions" in the Asian market.

• A recent New York Times piece answered the question: "What if you need a battery? A really big one — big enough to run a city?" A 2.35-million-square-foot office tower in New York City is among many buildings around the world equipped with a system that stores energy in the form of ice. The system freezes water overnight to help cool the building during the day, when electricity is typically more expensive.  

Massachusetts has awarded $1.5 million to help fund installation of more than 200 residential thermal energy storage units on Nantucket. Ice Energy, which makes the Ice Bear units, is partnering with Genbright LLC on the project. The goal is to help reduce peak energy demand and demonstrate an alternative to a third undersea transmission line to the island.

SaltX Technology and Aalborg CSP have agreed to work together to develop and commercialize an integrated energy storage solution for concentrated solar power based on EnerStore, SaltX's patented technology for large-scale energy storage. A prototype is scheduled to be built later this year with the aim of securing a commercial pilot plant in 2018.

PCM briefing: New RAL quality mark approved; Alexium working on undergarment for auto racing

Ben Welter - Monday, April 17, 2017

RAL Quality Mark• The RAL Quality Association PCM, established in 2004 to develop standards for the phase change materials industry, has received RAL approval to use a English-language version of its quality mark. The mark signifies that a PCM has met the association's quality and testing specifications (RAL-GZ 896) for PCM and PCM composites, objects and systems. 

Alexium International has announced plans to work with Benwel Inc. to introduce a fire-retardant undergarment for the auto racing industry. The undergarment will be treated with Alexiflam and Alexicool, Alexium's PCM-based cooling technology. 

Sonoco ThermoSafe is expanding its line of temperature-controlled pallet solutions with the launch of the LD7 Half PAG pallet shipper. The Half PAG is available for 2-8° C or 15-25° C temperature ranges with durations in excess of five days.

• The inaugural Chemical Watch Expo, REACH into the Future, will be held in Berlin April 25-26. The expo offers workshops on preparation for the REACH 2018 registration deadline.

AkzoNobel, Advanced Biochemical Co. and Ernst & Young are developing a new online tool to track the use of bio-based raw materials in products. The project partners say it will be the first tool to use e-certification to track bio-based content along the value chain. Initially the tool is focused on epoxy-derived products and coatings. AkzoNobel says more products and companies will be added later this year.

Patent application: Cables made of phase change material

Ben Welter - Monday, February 20, 2017

U.S. patent application 20170045301 (applicant E.I. Du Pont De Nemours and Co., Wilmington, Del.):

"Disclosed is a cable comprising a core and a PCM layer surrounding the core wherein the PCM layer consists of a PCM composition wherein the PCM composition comprises a PCM and an ethylene copolymer; and the core consists of a yarn, strand, or wire each made of a natural or synthetic polymeric material or a metal. The invention is useful for thermal management in a variety of applications in such as, for example, automotive, building, packaging, garments, and footwear."

http://www.freepatentsonline.com/20170045301.pdf

Technically speaking, PCM-infused lingerie line radiates an air of mystery

Ben Welter - Monday, February 13, 2017

Giapenta's beautiful new line of PCM-infused lingerie features soft, breathable mesh, delicate appliques and natural, moisture-wicking fabrics. As far as technical details, though, the brand’s founder is leaving much to the imagination.

Giapenta modelThe Florida startup, which launched a Kickstarter campaign last month to cover costs of its first production run, says the TempPro fabric used in the lingerie “proactively” pulls heat away to cool the body. Giapenta’s message to consumers:

“Just as you start to get warm, the phase changing materials in the fabric actively pull heat away from your body. Overheating and sweating are reduced. If you do start to get cold, stored heat is released back to you, when you need it the most.”

The company was founded by Kris Strouthopoulos, who managed Sleep Number mattress and bedding stores for 10 years. That’s where she became familiar with temperature-regulating fabrics and materials.

“Women especially would always come up to me to tell me how amazing and life changing the fabric was for them,” she said. “I always thought that if they were getting such an amazing benefit from this technology all night long, why not get the same effects during the day from their undergarments? So that is how we initially got into the lingerie industry and built a team dedicated to infusing technology and smart design solutions into garments to help improve the lives of others.”

TempPro fabric illustrationShe and her sister, Marketing VP Elena Strouthopoulos, have been working on the brand for two years. The Kickstarter campaign met its modest target of raising $25,000 in just one day, putting the company on a path to complete the production run in Canada by April and ship the first orders in May.

I contacted Kris Strouthopoulos to learn more about the TempPro fabric, which the company says is used throughout the line. What type of phase change material is used? What is its melt point? How is it encapsulated? She politely declined to answer any questions of a technical nature, saying such information is proprietary. Fair enough. We'll leave that to your imagination.

PCM briefing: New denim features phase change material; Sasol 'back on the expansion trail'

Ben Welter - Monday, February 06, 2017

• Thinking about attending BiobasedWorld 2017 in Cologne, Germany, this month? Sorry, the trade show was canceled a few months ago due to the industry's "challenging economic environment." A related show is on the horizon: Bio-Based Live Europe in Amsterdam, May 31-June 1. The focus will be on "Process Innovation and Technology" and "Sustainable Products." Speakers include Freek Snieders, managing director, Croda International; and Jean Luc Dubois, scientific director, Arkema.

Oak Ridge National Laboratory takes a look at how University of Michigan researchers used a Cray XK7 Titan supercomputer to study melting in two-dimensional systems. Deeper understanding of the process, Oak Ridge says, "could yield insights into surface interactions in materials important to technologies like solar panels, as well as into the mechanism behind three-dimensional melting." 

• The cold chain packaging class developed by Sonoco ThermoSafe’s ISC Labs will be offered at the Cold Chain GDP & Temperature Management Logistics Global Forum in San Diego in May. The all-day session on May 25 will cover the design, development and qualification of temperature-controlled packaging. The conference agenda is available for download.

Biznews.com reports that chemicals giant Sasol is "back on the expansion trail, seeking out suitable acquisitions."

• Among the new fabrics on display at the Munich Fabric Start trade show this week: Cordura denim combined with Schoeller phase change material. 

• The University of the West of England has installed two Monodraught Cool-Phase hybrid units in the university's Estates Management Office in Bristol. Monodraught says its PCM-equipped systems have been shown to "use up to 90% less energy than traditional a/c systems."  

• The 12th Conference on Advanced Building Skins, scheduled for Oct. 2-3 in Bern, Switzerland, has issued a call for papers. Possible topics include financial models, new products, advanced design and building performance. The deadline is Feb. 10. 

Pelican BioThermal has announced that its new passive pallet shipper system, CrÄ“do Cargo, is now available to rent or buy. The reusable bulk shipper uses phase change material cooling panels to maintain temperature ranges +2C to +8C and +15C to +25C.