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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.

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PCM with enhanced thermal properties developed for rail/truck container

Ben Welter - Saturday, January 12, 2019

Professor Yulong DingYulong Ding, the University of Birmingham professor who directed the development of a rail/truck shipping container designed to keep perishables cold without a power supply, says his team developed an organic phase change material with enhanced thermal properties for the project. The PCM is designed to keep the temperature inside the container between 5 and 12˚ C for up to 120 hours. Ding, director of the university's Center for Energy Storage, provided additional detail on the project in an interview this week.

Q: Describe your organization's role in the project.

A: It was funded by CRRC Shijiazhuang, a Chinese railway equipment manufacturer, and the project was collaborative. Our work at Birmingham included PCM materials development and fabrication, cold storage device design and testing, cold charging method and design. Work began in October 2017.

Q: What role did CRRC Shijiazhuang play?

A: CRRC was the project sponsor. Their work included manufacture and test of the device and cold charge device, installation of cold storage devices into large container, data-logging and IT, real application demonstration and testing (35,000 km combined road and railway testing across a wide climate zones).

Q: Can you briefly describe the testing methods and results?

A: I believe two standard containers were used, goods include all sorts of vegetables, flowers and fruits. Energy saving data have not been processed for the real tests but we do have testing data from labs, which is around 20 percent.

Q: Describe the PCM used in the application.

A: We used organic based PCM reformulated for enhanced thermal properties. Melting temperatures can be turned between -4 and 4 degree C, and the thermal storage capacity is >~200 kJ/kg.

Q: How big are the rail containers, typically, and how much PCM is used in each container?

A: We used the standard container for road transportation, which can be used for rail use. I prefer not to say the amount of PCM used, which may need approval from our sponsor.

Q: How is the PCM charged, and how long does it take to charge the PCM in a typical container?

A: We have a mobile charge device. The charging time is relatively short. The details will need our sponsor to approve before I can tell.

Q: In what material is the PCM contained (HDPE, film, metal)?

A: We used composite PCM contained in PCM storage device.

Q: How is the PCM deployed in the rail containers?

A: The PCM devices are installed inside the container.

Q: Does CRRC plan to manufacture the rail containers?

A: I doubt they would make the container.

https://www.birmingham.ac.uk/news/latest/2018/12/scientists-develop-world-first-cold-storage-roadrail-container.aspx

Microtek sponsors Spanish entry in Solar Decathlon Europe 2019

Ben Welter - Saturday, January 12, 2019

A team representing the Polytechnic University of Valencia, Spain, plans to use phase change material in the energy-efficient home it is building for Solar Decathlon Europe 2019. Azalea, one of 16 teams selected for the competition, is made up of 30 students and professionals representing fields such as architecture and engineering. 

Microtek Laboratories of Dayton, Ohio, is providing Azalea with technical and financial support.

Tim Riazzi"We are proud to be a sponsor of the Polytechnic team and the Azalea Project," said Tim Riazzi, Microtek president. "As a company who practices and is concerned with environmental stewardship, we are excited about their efforts to create a sustainable ecological dwelling that will reduce our impact on the environment and reduce our energy consumption." 

Riazzi said Microtek provided Azalea with Micronal 28D (formerly Micronal 5528X).

"Instead of providing them with a final product," Riazzi said, "we have worked with the team and decided that it would be better to provide them our dried Micronal product so that they could use it in the specific areas that they needed. We can say that they are incorporating it into a variety of elements/components of their wall and floor design, but they have asked us not to divulge the exact use of it because the competition is active. ... We can say that we have provide them over 200 kg of material."

https://www.microteklabs.com/blog/azalea-project-solar-decathlon-europe

Research roundup: Hydrophobic lauric acid; paraffin in heat exchanger; EnergyPlus vs. IES; more

Ben Welter - Thursday, January 10, 2019

From Journal of Energy Storage:

Preparation of hydrophobic lauric acid/SiO2 shape-stabilized phase change materials for thermal energy storage

From Applied Thermal Engineering:

Development of paraffin wax as phase change material based latent heat storage in heat exchanger

From Renewable Energy:

Characterization and stability study of a form-stable erythritol/expanded graphite composite phase change material for thermal energy storage

From Journal of Building Engineering:

Comparison of EnergyPlus and IES to model a complex university building using three scenarios: Free-floating, ideal air load system, and detailed

From 4th International Conference on Renewable Energies for Developing Countries :

Phase Change Materials in a Domestic Solar Hot Water Storage Tank of the Lebanese Market
Numerical and experimental investigations of a PCM integrated solar chimney
Integrating a High Solar Combi-Plus System using PCM Storage in a Smart Network: KSA Case Study

From International Journal of Advanced Research In Applied Sciences, Engineering and Technology:

Solar Cooker with Heat Storage System: A Review [pdf]

From Energy and Buildings:


From Solar Energy Materials and Solar Cells:

Bio-based poly (lactic acid)/high-density polyethylene blends as shape-stabilized phase change material for thermal energy storage applications

From Construction and Building Materials:

Microstructure-guided numerical simulation to evaluate the influence of phase change materials (PCMs) on the freeze-thaw response of concrete pavements

From Energy Conversion and Management:

Thermal management of Li-ion battery pack with the application of flexible form-stable composite phase change materials
Experimental investigation on cylindrically macro-encapsulated latent heat storage for space heating applications

From International Communications in Heat and Mass Transfer:

Experimental investigation on using a novel phase change material (PCM) in micro structure photovoltaic cooling system
Experimental investigation on a novel composite heat pipe with phase change materials coated on the adiabatic section

From Journal of Cleaner Production:

PCM briefing: Sunamp among 'Scottish tech companies to watch' in 2019; C-Therm webinar on new thermal conductivity instrument

Ben Welter - Monday, January 07, 2019

Rail shipping container with PCM

• The University of Birmingham's Center for Energy Storage has teamed up with a Chinese railway equipment manufacturer to develop a shipping container that uses phase change materials to maintain a low temperature over several days without a power supply. "Once ‘charged’, PCM inside the container - which can be transferred from train to truck and vice versa - can keep the inside temperature between 5-12 ˚C for up to 120 hours," the university reports.

CNET's Scott Stein takes a close look at PowerStation, "a battery of sorts that can keep a low-power sensor running off the temperature differences in everyday weather conditions." The device, made by Matrix Industries of Menlo Park, Calif., stores heat in a substance the company calls "Luna Phase Change Material" and later releases the heat in the form of electricity.

Scottish Business Insider has named Sunamp Ltd. one of five Scottish tech companies to watch in 2019. "The £2.2m raised in its latest fundraising sets the company up for a Series A round in 2019 as it looks to expand its international footprint and further scale its operations," Insider writes. "Sunamp heat batteries have so far been installed in over a thousand homes across the UK." 

C-Therm managing director Adam Harris is hosting a webinar this week to introduce the company's new thermal conductivity instrument, the C-Therm Trident. Advance registration is required for the webinar, which will be held at 1 p.m. EST Thursday, Jan. 10.

• At a business summit in Wisconsin last month, Encapsys President Mary Goggans said the Appleton-based company offers internships to students at regional colleges, including the children of employees. “The interns see the jobs and technologies they are interested in right here in the area,” Goggans said. “They realize they don’t need to get a job outside of the region to have the career they are looking for.”

Research roundup: Thermally modulated fiber sorbents; metamaterial-based radiative cooling; stearic–capric acid/porous nanoceramics; more

Ben Welter - Friday, January 04, 2019

From Industrial & Engineering Chemistry Research:

Development of Phase-Change-Based Thermally Modulated Fiber Sorbents

From ChemistrySelect:

Preparation and Thermal Properties of 1‐Hexadecanol‐Palmitic Acid Eutectic Mixture/Activated Carbon Composite Phase Change Material for Thermal Energy Storage

From Energies:

Thermal Conductivity Enhancement of Phase Change Materials for Low-Temperature Thermal Energy Storage Applications [pdf]
Metamaterial-Based Radiative Cooling: Towards Energy-Free All-Day Cooling [pdf]

From Renewable and Sustainable Energy Reviews:

A review and evaluation of thermal insulation materials and methods for thermal energy storage systems

From Materials Letters:

Stearic–capric acid/porous nanoceramics as a novel form-stable composite phase change material (FSPCM) for thermal energy storage

From International Refrigeration and Air Conditioning Conference:

Analysis of TES with PCM (Solid/Liquid) Integrated in a Residential System
Experimental Study on Portable Air-Conditioning System with Enhanced PCM Condenser

Research roundup: Solidification/subcooling in spherical capsule; cement-based thermal storage; heat transfer in flexible container; more

Ben Welter - Friday, December 21, 2018

From International Journal of Refrigeration:

Experimental studies on solidification and subcooling characteristics of water-based phase change material (PCM) in a spherical encapsulation for cool thermal energy storage applications

From Construction and Building Materials:

Thermal energy storage characterization of cement-based systems containing microencapsulated-PCMs

From Renewable and Sustainable Energy Reviews:

Seasonal thermal energy storage system for cold climate zones: A review of recent developments

From Heat and Mass Transfer:

Analysis of heat transfer in latent heat thermal energy storage using a flexible PCM container

From Energy Conversion and Management:

Plate type heat exchanger for thermal energy storage and load shifting using phase change material

From Applied Thermal Engineering:

Experimental studies on the charging performance of single-tank single-medium thermal energy storage
Investigation of thermal energy storage properties of a microencapsulated phase change material using response surface experimental design methodology
Financial and energetic evaluation of solar-assisted heat pump underfloor heating systems with phase change materials

From IOP Conference Series: Materials Science and Engineering:

Thermal Performance Through the Use of Radiant Barrier and Phase Change Material in Concrete Flat Roofs

From Solar Energy Materials and Solar Cells:

Synthesis of novel form-stable composite phase change materials with modified graphene aerogel for solar energy conversion and storage

From International Journal of Heat and Mass Transfer:

Development of vacuum impregnation equipment and preparation of mass/uniform shape-stabilized phase change materials

PCM briefing: McGill joins Phase Change Energy Solutions as CEO; Croda is No. 3 on Britain's Most Admired Companies list

Ben Welter - Friday, December 21, 2018

Dennis McGillDennis McGill, operations advisor at Pegasus Capital Advisors, has joined Phase Change Energy Solutions as chief executive officer and chairman of the board. McGill, right, has more than 30 years of experience in senior financial and executive leadership roles. For the past three years, he has been the CEO and chairman of the board for ReCommunity Recycling of Charlotte, N.C. 

Malta Inc., a spinoff of Alphabet’s Moonshot Factory, has raised $26 million in Series A funding. The Massachusetts company is developing an electro-thermal energy storage system that stores energy in the form of the thermal differential between hot and cold storage media. 

Croda International, maker of phase change materials and other specialty chemicals, is No. 3 on Management Today's list of Britain's Most Admired Companies 2018. Diageo and McDonald's took the top two spots.

• From Andrew Chang, regional operations director at Ice Energy, on LinkedIn: "Today was a major milestone for Ice Energy. We commissioned our 100th Ice Bear in the SCE LCR program in #OrangeCounty! We are currently offsetting about 1.5MW for 4 hours every day in Orange County."

MIT researchers have developed a way to use light to trigger the storage and release of waste heat from car engines and other sources. "Once melted and activated by ultraviolet light, the [phase change] material stores the absorbed heat until a beam of visible light triggers solidification and heat release," Phys.org reports. "Key to that control are added molecules that respond to light by changing shape from one that impedes solidification to one that permits it."

Nebu Block T10• Via LinkedIn: "It might not look like it, but this is how VIPs help to store energy. Vacuum insulated panels, that is. ZAE Bayern cooperates with va-Q-tec, Nebuma GmbH, Verallia, and Lungmuß Feuerfest to make industrial high-temperature energy storages more efficient and less hard to find." Nebuma's 20-foot mobile container, shown at right, is designed to store about 16 MWh of heat at a temperature of 1,000 degrees Celsius.

Dr. Yixiang Gan of the University of Sydney is among 11 researchers to win fellowships from the Australia-India Strategic Research Fund for 2019. His focus: "Optimizing thermal energy storage with phase change materials: with applications to solar energy storage in Australia and India." 

• Registration is open for the 44th Stanford Geothermal Workshop, to be held Feb. 11-13 at Stanford University in California.

• Registration is open for Energy Storage Europe, "the leading international trade fair for energy storage," to be held March 12-14 in Dusseldorf, Germany. 

• The 14th Conference on Advanced Building Skins, to be held Oct. 28-29, 2019, in Bern, Switzerland, has issued a call for papers. The deadline for submissions is June 1. Registration for the conference is expected to open once the program is published in April. 

Pelican BioThermal has appointed Lynaye Reynolds as worldwide director of quality. She joined the company three years ago as the quality manager at its site in Leighton Buzzard in the United Kingdom.

1414 Degrees’ molten silicon biogas energy storage system will be installed at a wastewater treatment plant in South Australia. The $3.2 million (AUS) pilot project is a joint effort of 1414 Degrees and SA Water.

PCM briefing: Virginia Tech takes first place in Solar Decathlon; Pluss is expanding R&D team

Ben Welter - Monday, December 10, 2018

Virginia Tech's FutureHAUS team has won first place in the 2018 Solar Decathlon Middle East, a competition organized by the U.S. Department of Energy and the United Arab Emirates’ Dubai Electricity & Water Authority. The lone American team topped 14 other finalists and more than 60 total entrants. The team said its use of phase change material in the solar-powered home set it apart from the competition. Look for an interview with Joseph Wheeler, an architecture professor who directs Virginia Tech's FutureHAUS research program, in the next issue of Phase Change Matters.

• Via LinkedIn: "Pluss Advanced Technologies Pvt. Ltd. is hashtag#Expanding its hashtag#Research team for hashtag#PCM Business. Chemistry Graduates with 0-2 years of experience preferred. However, others will be considered too. Usual job descriptions apply! Want to understand more about the opportunity? Please write to Ruchika Garg at jobs@pluss.co.in. Hurry! The vacancies are limited."

• U.S. and German researchers who have studied a PCM alloy made from germanium, antimony and tellurium say liquid water and liquid PCMs may have the same underlying physics. "The experiments reveal that the so-called Stokes-Einstein relation, which connects the viscosity of a liquid to the diffusion coefficient of its molecules, appears to break down above the melting point of the material and at very low viscosities – just as in water," Physics World reports. "The result will be important when making phase-change memories from GeSbTe alloys and related PCMs in the future."

CleanTechnica's Tina Casey takes a deep dive into the U.S. Department of Energy's efforts to develop next-generation, long-duration energy storage systems. Her conclusion: "The new R&D program practically guarantees that the hurt will continue for coal miners, their families and their communities long after Trump leaves office."  

kW Engineering of Oakland, Calif., offers tips on how to use a famously complex energy modeling program: "Best Practices for Successful Building Energy Modeling with EnergyPlus." 

Research roundup: Dynamic building envelope; multilayer glazing facades; spherical capsule with pin-fins; more

Ben Welter - Wednesday, December 05, 2018

From Applied Energy:

Form-stable and thermally induced flexible composite phase change material for thermal energy storage and thermal management applications
Influence of the storage period between charge and discharge in a latent heat thermal energy storage system working under partial load operating conditions
Dynamic building envelope with PCM for cooling purposes – Proof of concept

From Air Force Research Laboratory:

High Energy Advanced Thermal Storage (HEATS) [pdf]

From Solar Energy:

Synthesis and characterization of sensible thermal heat storage mixture containing phosphate compound of cobalt and sodium
Thermal performance of non-ventilated multilayer glazing facades filled with phase change material

From Applied Thermal Engineering:

Charging nanoparticle enhanced bio-based PCM in open cell metallic foams: An experimental investigation
Thermal performance analysis and optimization of a spherical PCM capsule with pin-fins for cold storage
A phase change material with enhanced thermal conductivity and secondary heat dissipation capability by introducing a binary thermal conductive skeleton for battery thermal management

From Materials:

Characterization of MgCl2·6H2O-Based Eutectic/Expanded Perlite Composite Phase Change Material with Low Thermal Conductivity

From Solar Energy Materials and Solar Cells:

Size controlled lauric acid/silicon dioxide nanocapsules for thermal energy storage

From Energy Procedia:

Life Cycle Assessment of thermal energy storage materials and components

From MATEC Web of Conferences:

A Numerical Method for Analysing Heat Conduction in Composites Containing Encapsulated Phase Change Materials [pdf]

From Journal of Building Engineering:

Agenda set for 6th Swiss symposium on thermal energy storage

Ben Welter - Monday, December 03, 2018

The agenda is confirmed for the 6th Swiss Symposium Thermal Energy Storage, to be held in Lucerne, Switzerland, on Jan. 25, 2019. The symposium will focus on seasonal storage systems and the sector coupling of power and heat. Here are the speakers and topics:

• "Heat Storage in Switzerland": Elimar Frank, Frank Energy GmbH, Switzerland

• "Thermal Energy Storage, one Key Element to link Energy Sectors": Peter Schossig, Fraunhofer Institute for Solar Energy Systems ISE, Germany

• "Enhanced Phase-Change Materials for Heat-Storage applications": Colin Pulham, School of Chemistry, University of Edinburgh, United Kingdom

• "High-Temperature Latent Heat Storage and Applications": Dan Bauer, German Aerospace Center (DLR), Stuttgart, Germany

• "High-Temperature Phase Change Materials": Yulong Ding, University of Birmingham, United Kingdom

• "Network Convergence and Sector Coupling at St. Galler Stadtwerke": Simon Schoch, St. Galler Stadtwerke, Switzerland

• "Heat4Cool – Multienergy Solutions for Heating & Cooling": Marcello Aprile, Politecnico di Milano and Philipp Schütz, Lucerne School of Engineering and Architecture, Switzerland

• "Large-Scale Thermal Energy Storage and Multi-Energy Networks in Vienna": Robert Hammerling, Wien Energie GmbH, Austria

• "Current and Future Use of Seasonal Thermal Storage in Ground Heat Exchangers": A Swedish Perspective: José Acuña, KTH Royal Institute of Technology, Sweden

• "Avoided System Cost for Grid Reinforcement and Peaker Plants by using Ecovat Seasonal Thermal Energy Storage": Aris de Groot, Ecovat Renewable Energy Technologies, Netherlands

• "Optimization of Seasonal Thermal Energy Storage Systems for Buildings": Willy Villasmil, Lucerne School of Engineering and Architecture, Switzerland

• "Seasonal Hot Water Storage with Vacuum Super Insulation": Matthias Demharter, Bayerisches Zentrum für Angewandte Energieforschung ZAE, Germany

The registration fee is 300 Swiss francs. Lunch is included. The 2018 symposium drew more than 100 participants.

https://www.hslu.ch/en/lucerne-school-of-engineering-architecture/campus/veranstaltungen/2019/01/25/cctes-sstes19