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The award-winning Phase Change Matters blog tracks the latest news and research on phase change materials and thermal energy storage. E-mail tips and comments to Ben Welter, communications director at Entropy Solutions. Follow the blog on Twitter at @PureTemp. Subscribe to the weekly PCM newsletter. Or join the discussion on LinkedIn.




Research roundup: High-conductivity nanomaterials; paper board packaging; battery thermal management; more

Ben Welter - Thursday, May 16, 2019

From Heat and Mass Transfer:

Experimental and numerical analysis of composite latent heat storage in cooling systems for power electronics

From Journal of Sol-Gel Science and Technology:

A robust, flexible superhydrophobic sheet fabricated by in situ growth of micro-nano-SiO2 particles from cured silicone rubber

From Journal of Thermal Analysis and Calorimetry:

High-conductivity nanomaterials for enhancing thermal performance of latent heat thermal energy storage systems

From Building Simulation:

Optimization and sensitivity analysis of design parameters for a ventilation system using phase change materials

From Journal of Packaging Technology and Research:

Thermal Analysis of Paper Board Packaging with Phase Change Material: A Numerical Study

From Energy Storage:

Thermal performance of battery thermal management system using composite matrix coupled with mini‐channel

From Phase Transitions:

A study on preparation and properties of carbon materials/myristic acid composite phase change thermal energy storage materials

From ACS Applied Materials & Interfaces:

Melamine Foam Supported Form-stable Phase Change Materials with Simultaneous Thermal Energy Storage and Shape Memory Property for Thermal Management of Electronic Devices

From International Conference on Thermal Engineering:

Performance Enhancement of Unitary and Packaged Air Conditioners With Phase Change Material
Performance Comparison of Different Phase Change Materials For Solar Cooking During off Sun Sunshine Hours
A Review on Enhancement of Thermophysical Properties of Paraffin Wax PCM With Nanomaterials
Nano-Enhanced PCMs for Low Temperature Thermal Energy Storage Systems and Passive Conditioning Applications

From Chemistry Select:

Designing Coconut Oil Encapsulated Poly(stearyl methacrylate‐co‐hydroxylethyl metacrylate) Based Microcapsule for Phase Change Materials

From Evolution in Polymer Technology Journal:

Enhancement of Thermo-Regulating Textile Materials Using Phase Change Material

From Materials Research Express:

Improved thermal characteristics of Ag nanoparticles dispersed myristic acid as composite for low temperature thermal energy storage

From Applied Energy:

On the performance of ground coupled seasonal thermal energy storage for heating and cooling: A Canadian context

From Solar Energy Materials and Solar Cells:

Thermal stability enhancement of d-mannitol for latent heat storage applications

Patent application: High-density latent heat storage device

Ben Welter - Friday, May 10, 2019

University of Texas patent drawing

U.S. patent application 20190137190 (applicant Board of Regents, University of Texas System, Austin, Texas):

"Latent heat storage devices are disclosed, such as latent heat storage devices comprising a phase change material encapsulated in sufficiently conductive tubes, wherein the tubes are arrayed in a hexagonal-packed pattern. The devices herein can be used, for example, in residential and/or commercial HVAC systems."

PCM briefing: Cold chain veteran joins Phase Change Energy Solutions; Outlast showcases new nylon filament yarn

Ben Welter - Friday, May 10, 2019

Bruce TruesdaleBruce Truesdale has joined Phase Change Energy Solutions of Asheboro, N.C., as director of business development - cold chain. He was formerly senior supply chain consultant at Verta Life Sciences and director of health care at Protek Pharma Worldwide. He declined an interview request, but his new job title suggests that PCES, whose product line now focuses on HVAC, building and thermal energy storage, has an interest in the temperature-controlled packaging market. Earlier this year, PCES announced an investment by Pegasus Capital Advisors, Emerald Technology Ventures and Third Prime, an early-stage venture fund and prior investor. The company said it would use the proceeds to fund the continued development of its thermal storage products and expand its operations globally.

Chalmers University of Technology of Sweden has an opening for a postdoctoral researcher in thermal energy storage for building applications. The research group Building Physics is working "to find out how novel TES with phase change materials (PCM) could complement the existing district heating and cooling networks and co-operate with other peak shaving techniques (water accumulator tanks, ground heat storage pumps, etc.) through smart thermal grids." The application deadline is June 9.

Outlast will showcase its new nylon filament yarn at the Techtextil trade show in Frankfurt, Germany, next week. "The PCMs optimized for this specific application," Outlast says, "are included directly inside the polyamide fibers." Potential applications include next-to-skin products such as undergarments, shapewear, sportswear and hosiery. The company says it now sources the majority of PCMs used in its products from renewable instead of synthetic raw materials.

PCM coolerA PCM coating designed to absorb heat from rockets is among the dozens of NASA spinoffs listed in the latest issue of Spinoff, an annual publication that has been documenting space agency spinoffs since 1976. In the early 2000s, Raj Kaul, a materials scientist at Marshall Space Flight Center, began researching a way to use PCM to keep the outside of spacecraft at a safe temperature. An entrepreneur eventually snapped up the patent for the coating Kaul developed and is working on a number of products based on the technology, including aircraft paint, pipe heat traps and an iceless cooler, shown at right. 

• The U.S. Department of Energy this week announced $89 million in funding for "innovative, advanced manufacturing research and development projects." "Innovations for the Manufacture of Advanced Materials," one of three areas to receive funding, includes phase change storage materials for heating and cooling applications. The department anticipates making up to 55 awards for up to three years. Concept papers are due on June 20.

Research roundup: Zinc oxide coating; TEG-PCM power enhancement; graphen-oxide aerogel beads; more

Ben Welter - Friday, May 10, 2019

From Advanced Materials Interfaces:

Doubly Coated, Organic–Inorganic Paraffin Phase Change Materials: Zinc Oxide Coating of Hermetically Encapsulated Paraffins

From Applied Energy:

Efficiency analysis and experimental validation of the ocean thermal energy conversion with phase change material for underwater vehicle
A numerical and experimental analysis of an integrated TEG-PCM power enhancement system for photovoltaic cells
Molten salt selection methodology for medium temperature liquid air energy storage application

From Applied Energy Materials:

Graphene-Oxide Aerogel Beads Filled with Phase Change Material for Latent Heat Storage and Release

From Journal of Wuhan University of Technology:

Effect of Modified Vermiculite on the Interface of a Capric Acid-expanded Vermiculite Composite Phase Change Material with Phase Transition Kinetics

From Journal of Molecular Liquids:

Numerical simulation of the melting process of nanostructured based colloidal suspensions phase change materials including the effect of the transport of the particles

From Fibers and Polymers:

Encapsulated Phase Change Material Embedded by Graphene Powders for Smart and Flexible Thermal Response

From Applied Thermal Engineering:

Influence of orientation on thermal performance of shell and tube latent heat storage unit

From Journal of Energy Storage:

Development and validation of the numerical model of an innovative PCM based thermal storage system

From 2nd International Conference on Power, Energy and Environment:

Feasibility Study of the Application of a Latent Heat Storage in a Solar Dryer for Drying Green Chili

From Solar Energy:

Tetradecyl oxalate and octadecyl oxalate as novel phase change materials for thermal energy storage
An analytical and comparative study of the charging and discharging processes in a latent heat thermal storage tank for solar water heater system
Effect of alkaline pH on formation of lauric acid/SiO2 nanocapsules via sol-gel process for solar energy storage

From Journal of Applied Polymer Science:

Preparation and characterization of paraffin microcapsules for energy‐saving applications

From Energy:

Flexible heatsink based on a phase-change material for a wearable thermoelectric generator

From Journal of Nanoscience and Nanotechnology:

Superior Form-Stable Phase Change Material Made with Graphene-Connected Carbon Nanofibers and Fatty Acid Eutectics

From Construction and Building Materials:

Thermal and rheological characterization of bitumen modified with microencapsulated phase change materials

From Thermochimica Acta:

Development of spherical α-Al2O3-based composite phase change materials (PCMs) and its utilization in thermal storage building materials

From Journal of Power Sources:

Thermophysical properties of trimethylolethane (TME) hydrate as phase change material for cooling lithium-ion battery in electric vehicle

From Solar Energy Materials and Solar Cells:

Applications of cascaded phase change materials in solar water collector storage tanks: A review
Thermal conductivity enhancement of hydrated salt phase change materials employing copper foam as the supporting material

Research roundup: Spherical encapsulation; thermal therapy respirator; nanoporous composite; PCM effect on cement; more

Ben Welter - Friday, May 03, 2019

From Journal of Energy Storage:

Performance comparison of four spherically encapsulated phase change materials for medium temperature domestic applications

From International Journal of Thermal Sciences:

Exploration of a thermal therapy respirator by introducing a composite phase change block into a commercial mask

From Renewable and Sustainable Energy Reviews:

Review on nanoporous composite phase change materials: Fabrication, characterization, enhancement and molecular simulation

From Sci:

The Effect of Phase Change Materials on the Physical, Thermal and Mechanical Properties of Cement 

From Applied Energy:

High energy-density and power-density thermal storage prototype with hydrated salt for hot water and space heating

From Journal of Thermal Science and Engineering Applications:

Thermal Cycling of Calcium Chloride Hexahydrate With Strontium Chloride as a Phase Change Material for Latent Heat Thermal Energy Storage Applications in a Nondifferential Scanning Calorimeter Set-Up
Numerical Investigation of Scheffler Concentrator Receiver for Steam Generation Using Phase Change Material

From IntechOpen:

Solar Thermal Energy Storage Using Paraffins as Phase Change Materials for Air Conditioning in the Built Environment

From Reactive and Functional Polymers:

Design and fabrication of pH-responsive microencapsulated phase change materials for multipurpose applications

From Advances in Fluid and Thermal Engineering:

Experimental Investigation on a Solar Thermal Energy Packed Bed Sensible Heat Storage Combined with Latent Heat Storage

From Bulletin of Materials Science:

Development of an acetanilide/benzoic acid eutectic phase change material based thermal energy storage unit for a passive water heating system

From International Journal of Heat and Mass Transfer:

Solidification performance of a latent heat storage unit with innovative longitudinal triangular fins

Research roundup: Surface functionalization of composite PCM; EnergyPlus optimization; direct expansion solar heat pump; more

Ben Welter - Friday, April 26, 2019

From Applied Surface Science:

Effects of surface functionalization on thermal and mechanical properties of graphene/polyethylene glycol composite phase change materials

From Applied Energy:

Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor
Shape-remodeled macrocapsule of phase change materials for thermal energy storage and thermal management
Investigation on the thermal performance of a high temperature packed bed thermal energy storage system containing carbonate salt based composite phase change materials
Toward a new method for the design of combined sensible/latent thermal-energy storage using non-dimensional analysis
Strategic control and cost optimization of thermal energy storage in buildings using EnergyPlus
Adaptive measures for mitigating urban heat islands: The potential of thermochromic materials to control roofing energy balance

From Solar Energy Materials and Solar Cells:

Poly(styrene-co-divinylbenzene-co-acrylamide)/n-octadecane microencapsulated phase change materials for thermal energy storage

From Renewable and Sustainable Energy Reviews:

Recent advances in direct expansion solar assisted heat pump systems: A review
Review on nanoporous composite phase change materials: Fabrication, characterization, enhancement and molecular simulation

From Energy and Buildings:

Experimental Testing of Phase Change Materials in a Warm-Summer Humid Continental Climate

From International Journal of Energy Research:

Development of pentadecane/diatomite and pentadecane/sepiolite nanocomposites fabricated by different compounding methods for thermal energy storage

From Applied Thermal Engineering:

Heat transfer performance of graphene nano-platelets laden micro-encapsulated PCM with polymer shell for thermal energy storage based heat sink

From Journal of Applied Polymer Science:

Investigations on thermal properties of microencapsulated phase‐change materials with different acrylate‐based copolymer shells as thermal insulation materials

From Solar Energy:

Experimental investigation on the impact of thermal energy storage on the solar still performance coupled with PV module via new integration

From Thermochimica Acta:

Nanoencapsulated phase change material with polydopamine-SiO2 hybrid shell for tough thermo-regulating rigid polyurethane foam

From International Journal of Heat and Mass Transfer:

Optimization of the detailed factors in a phase-change-material module for battery thermal management

From Journal of Traffic and Transportation Engineering :

A review on the best practices in concrete pavement design and materials in wet-freeze climates similar to Michigan

From Case Studies in Thermal Engineering:

Study of a passive solar air heater using palm oil and paraffin as storage media

From Acta Microscopica:

Preparation of Graphene Hybrid Material and Thermal Properties of Polymer Composites

PCM briefing: 'Awareness' of PCM technology seen as key challenge; researchers develop novel anti-icing material

Ben Welter - Friday, April 26, 2019

University of Illinois at Chicago researchers say they've developed a material that can inhibit the formation of ice much longer than existing technologies, New Atlas reports. The anti-icing material is made of phase-changing liquids that have heat-trapping properties. Researchers say the material works effectively in temperatures as low as -15° C.

Collin CokerIn an interview with Engineered Systems, Viking Cold Solutions' vice president of sales and marketing talks about the state of the thermal energy storage market and the company's PCM-based thermal storage systems. What's been the Houston company's biggest challenge over the past 18 months? "Awareness," said Collin Coker, right. "We constantly hear, 'This is really interesting; I've never seen it before; do you have fluid moving through the refrigeration system?' So, breaking it down and explaining that it’s non-mechanical and very simple is part of the challenge. Getting people to believe that this technology can provide savings in the range of 10-50% in some applications is also a challenge. A lot of folks are fairly guarded, because that level of savings has never been achieved in this industry before. It just seems too good to be true. "

• The World Bank announced a new program this week to accelerate the adoption of sustainable cooling technologies, including air conditioning, refrigeration and cold chain in developing countries. The program will provide technical assistance to ensure that efficient cooling is included in new World Bank Group investment projects.

Sonoco ThermoSafe has posted the agenda for the company's next Leading Minds Seminar, to be held May 29 in Princeton, N.J. Co-hosted by ELPRO, the seminars offer a chance for pharmaceutical manufacturers, supply chain partners and government representatives to discuss temperature-assurance packaging and data monitoring in a collaborative environment. Panelists for a discussion on reusable shipping systems include Mark Everitt, qualification engineer at AstraZeneca, and Michael English, director of engineering at Merck.

Research roundup: PCM use in mortars; compatibility with selected plastics; myo-inositol sugar alcohol; more

Ben Welter - Tuesday, April 23, 2019

From Materials:

Phase Change Materials for Energy Efficiency in Buildings and Their Use in Mortars

From Polymer Testing:
From Renewable Energy:

From Molecules:

From Applied Energy:

Natural convection during melting in vertical finned tube latent thermal energy storage systems
Year-round performance analysis of a photovoltaic panel coupled with phase change material

From Energy Procedia:

A Review of the Performance of Buildings Integrated with Phase Change Material: Opportunities for Application in Cold Climate

From Journal of Applied Polymer Science:

Encapsulation of polar phase change materials via multiemulsification and crosslinking method and its application in building

From Journal of Energy Storage:

Thermal performance of shell and tube latent heat storage unit: Comparative assessment of horizontal and vertical orientation
Experimental investigation of phase change in a multitube heat exchanger

From Chemistry Select:

Preparation and Thermal Properties of Stearic Acid/n‐Octadecane Binary Eutectic Mixture as Phase Change Materials for Energy Storage

From Journal of Materials Research:

Synthesis of novel shape-stabilized phase change materials with high latent heat and low supercooling degree for thermal energy storage

From Science of Advanced Materials:

Fabrication and Performance of Polyurethane/Polyurea Microencapsulated Phase Change Materials with Isophorone Diisocyanate via Interfacial Polymerization
Design and Analysis of Battery Box Based on Graphite-Phase Change Material and Air Cooling

From Experimental Techniques:

Design, Build, and Test a Hybrid Cooling System for Crash Helmet

From Journal of Thermal Analysis and Calorimetry:

Capric acid/intercalated diatomite as form-stable composite phase change material for thermal energy storage
Preparation and thermal performances of microencapsulated phase change materials with a nano-Al2O3-doped shell

PCM briefing: Ice Energy signs distribution deal; Bloom joins Sunamp as board chairman

Ben Welter - Monday, April 22, 2019

Ice Energy of Santa Barbara, Calif., has reached distribution agreements with four California companies to sell, install and maintain its ice-based thermal storage system, the Ice Bear 20. The companies are Correy Baker Heating and Air of Murrieta; Emery Mechanical Engineering of San Diego; H3 of Santa Barbara; and SunRize Mechanical of Temecula. “This distribution network will enable us to further expand our footprint in the residential market in Southern California,” said Marcel Christians, co-COO of Ice Energy.

Sonoco ThermoSafe and AirBridgeCargo Airlines have announced a global partnership agreement for the leasing of the PharmaPort 360 temperature-controlled shipping container. The agreement will enable pharmaceutical shippers to lease PharmaPort 360 containers directly from AirBridgeCargo.

Martin Bloom• Thermal battery maker Sunamp Ltd. of Scotland has appointed Martin Bloom as chairman of the board. Bloom, right, has extensive experience in high-growth technology and renewable energy companies, including Chinese solar company Renesola and Loughborough-based fuel cell specialist Intelligent Energy. Bloom succeeds Sunamp’s founding chairman, Bob Pettigrew, who oversaw its early growth.

Nominations are being accepted for the 2019 Poncelet Prize for Innovation in Microencapsulation, co-sponsored by Procter & Gamble and the Bioencapsulation Research Group. The award recognizes innovation in process design and modernization; development of new core and shell materials; innovation in characterization methods; or innovation in emerging fields of applications. The deadline for submitting nominations is May 31, 2019.

Peli BioThermal is rebranding its Chronos temperature-controlled shippers. CoolGuard PCM will replace Chronos Express, and CoolGuard Advance will replace Chronos Advance. The CoolGuard shippers will offer configurations with fewer components and additional temperature set points, such as 16º C.

• Registration is open for "Phase Change Material & Passive Cooling in Large Venues," a lunch-hour presentation by Henderson Engineers. The free event, sponsored by AIA Kansas City, will be held June 12 at the Center for Architecture & Design in Kansas City, Mo.

Axiotherm GmbH's kraftBoxx thermal energy storage system is a finalist for a Smarter E Award in the renewable energy category. KraftBoxx is a joint development with Klara Energy and Tuxhorn within the scope of the PCM-based HeatSel product line marketed by Axiotherm. Winners will be announced May 15 in Munich.

• PCM expert Harald Mehling's new book is available on Amazon: "Understanding the Basics of Energy: An Introduction from Simple to Complex Situations."

Tempur-Pedic of Lexington, Ky., says its new TEMPUR-breeze mattress will help sleepers "stay up to 8 degrees F cooler through the night." According to Tempur-Pedic: "At about 80°F, the molecules within TEMPUR-breeze’s most efficient Phase Change Material (PCM) to-date, PURECOOL+, activate, shifting from a solid to a liquid to absorb massive amounts of heat. For the first time, Tempur-Pedic’s scientists successfully altered these proprietary molecules to deliver more phase change material, increasing its capacity to absorb heat by 2x compared to other PCM."

• Two new ASHRAE publications will be available in June: "Owner’s Guide for Buildings Served by District Cooling" and an updated edition of the "District Cooling Guide" for designers and building owners around the world.

• Researchers at Sweden's KTH Royal Institute of Technology have developed a polyethylene glycol-infused wood material that could be used to make windows that absorb heat during the day and release it into the home at night. The researchers are working to increase the heat storage capacity of the transparent wood, reports.

PCM briefing: $33M in funding for CSP thermal storage research; Walero undergarment put to the test in race simulator

Ben Welter - Friday, March 29, 2019

• The U.S. Department of Energy has announced $33 million in research funding to advance technologies that work toward achieving the department's 2030 cost target of 5 cents per kilowatt-hour for CSP-generated electricity with at least 12 hours of thermal energy storage. "This research," DOE writes, "includes new materials and technologies that significantly reduce the cost of manufacturing, enable new energy storage technologies, and develop solutions that enable a solar field to operate autonomously without any human input."

Jack MitchellWalero racewear, which uses Outlast phase change technology to regulate temperature in race and rally drivers, has been put to the test on reigning British GT4 champion Jack Mitchell in a temperature-controlled race simulator. The tests were directed by racing performance coach Dean Fouache. On the first day, Mitchell, right, wore standard Nomex underwear; on the second day, he wore Walero underwear. Three measurements were recorded every five minutes during the hourlong tests: body temperature, heart rate and weight loss. In all three areas, Walero showed measurable advantages over the Nomex. "Jack sweated around 40 percent less in the Walero underwear and his average heart rate was eight beats less over the course of the hour," Fouache told Autosport magazine. "So, all in all, relatively conclusive results - even though it is a small comparison test."

• New this month from Central West Publishing in Australia: "Phase Change Materials," edited by Vikas Mittal, an associate professor of chemical engineering at the Petroleum Institute in Abu Dhabi.

• The International Conference on Innovative Applied Energy in the United Kingdom earlier this month featured a number of experiments with phase change materials, including Auburn University's development of micro-encapsulated phase change materials that can be combined with many different media. Other PCM research included a bio-composite made with hemp lime concrete and a novel utilization of fly ash to encapsulate phase change materials.

James Joule• The 200th anniversary of the birth of physicist James Prescott Joule will be commemorated with the unveiling of a plaque in Sale, United Kingdom, in April. The English physicist and mathematician, who gave his name to the unit of energy, was born on Dec. 24, 1818, in Salford. He died in Sale in 1889.

• The deadline for submitting manuscripts for "Phase Change Materials of Buildings," a special issue of the journal Buildings, is Sunday, March 31. Dr. Morshed Alam of Australia's Swinburne University of Technology is the guest editor.